Sensoric properties

Stmctural and chemical modification of urethane containing polymer matri-ces with macrocycles - calixarenes having reactive hydrazide groups have been carried out and stmcture, physico chemical and sensor properties of polyure-thanesemicarbazides (PUS) synthesised have been studied. The polymers obtained (on the base of polypropylene glycol MM 1000 and polysiloxane diol MM 860, hexamethylene diisocyanate and calixarene dihydrazide) are identified by IR-spectroscopy, size exclusion chromatography (SEC), DSC, WAXS and SAXS methods. 

The dynamic Weissenberg number W can be calculated from data obtained by the strain frequency sweep measurement. It s the ratio of the elastic to the viscous shares in the measured gel and leads to an objective description of the sensoric properties, representing the basis for the standardization of pectins. 

The design of bioeompatible (blood compatible) potentiometric ion sensors was described in this chapter. Sensing membranes fabricated by crosslinked poly(dimethylsiloxane) (silicone rubber) and sol gel-derived materials are excellent for potentiometric ion sensors. Their sensor membrane properties are comparable to conventional plasticized-PVC membranes, and their thrombogenic properties are superior to the PVC-based membranes. Specifically, membranes modified chemically by neutral carriers and anion excluders are very promising, because the toxicity is alleviated drastically. The sensor properties are still excellent in spite of the chemical bonding of neutral carriers on membranes. 

Durability of Sensor Properties With Respect to the Sensor Application... 

Size-related problems may become important for all microsensors. Leakage of sensing materials from a small membrane may lead to rapid deterioration of sensor properties [104], While the lipophilicity of membrane components cannot be increased infinitely, immobilization of ionophore and ion exchanger in the polymer by covalent attachment or molecular imprinting along with utilization of plasticizer-free membranes could help solve the leakage problem. 

The properties of a pH electrode are characterized by parameters like linear response slope, response time, sensitivity, selectivity, reproducibility/accuracy, stability and biocompatibility. Most of these properties are related to each other, and an optimization process of sensor properties often leads to a compromised result. For the development of pH sensors for in-vivo measurements or implantable applications, both reproducibility and biocompatibility are crucial. Recommendations about using ion-selective electrodes for blood electrolyte analysis have been made by the International Federation of Clinical Chemistry and Laboratory Medicine (IFCC) [37], IUPAC working party on pH has published IUPAC s recommendations on the definition, standards, and procedures... 

A.D Amico, C.DiNatale. A contribution on some basic definitions of sensors properties. Sensors Journal, IEEE, vol. 1, Issue 3, Oct 2001 Page(s) 183 - 190... 

It is worth remarking that a gas sensor array is a mere mathematical construction where the sensor outputs are arranged as components of a vector. Arrays can also be utilized to investigate the properties of chemical sensors, or even better, the peculiar behaviour of a sensor as a component of an array. In this chapter, the more common sensor array methodologies are critically reviewed, including the most general steps of a multivariate data analysis. The application of such methods to the study of sensor properties is also illustrated through a practical example. 

Some attempts to exploit sensor dynamics for concentration prediction were carried out in the past. Davide et al. approached the problem using dynamic system theory, applying non-linear Volterra series to the modelling of Thickness Shear Mode Resonator (TSMR) sensors [4], This approach gave rise to non-linear models where the difficulty to discriminate the intrinsic sensor properties from those of the gas delivery systems limited the efficiency of the approach. 

As an example of the use of array methodology to study chemical sensor properties let us consider the thirteen molecular structures reported in Figure 5. To investigate the sensing properties of these molecules we studied the behaviour of the response of thickness shear mode resonators (TSMR) sensors, each coated with a molecular film, to different concentration of various volatile compounds (VOC). Analyte compounds were chosen in order to have different expected interaction mechanisms. 

The twofold definition given in Section 1.3 encompasses several properties a (bio)chemical sensor must have in order to fulfil the objectives demanded by the analytical quality level to be achieved. Some such properties are mandatory, whereas others are only desirable. Figure 1.15 shows advantageous and essential sensor properties arranged in fom groups that are discussed below. 

The first group of sensor properties in Fig. 1.15 is concerned with the quality of results obtained in analytical processes involving a (bio)chemical sensor. All of them are obvious targets of analytical tasks [3]. As shown in the following section, the accuracy of the analytical results relies on a high reproducibility or repeatability, a steep slope of the calibration curve (or a low detection or quantification limit) and the absence of physical, chemical and physico-chemical interferences from the sample matrix. Sensors should ideally meet these essential requisites. Otherwise, they should be discarded for routine analytical use however great their academic interest may be. 

Figure 1.15 — Essential and desirable (bio)chemical sensor properties.

Sensor Properties at Elevated Temperatures, Influence of Hydrogen... 

In addition to the principal constituents listed in Table 1.1, milk contains several hundred minor constituents, many of which, e.g. vitamins, metal ions and flavour compounds, have a major impact on the nutritional, technological and sensoric properties of milk and dairy products. Many of these effects will be discussed in subsequent chapters. 

The working of a chemical sensor is based on the interaction between free particles (e g. gas molecules) and the surface of a solid. This interaction might be a physical absorption and in that case the sensor can be used at low temperatures because the absorption forces will not be great. However, the absorption might also be chemical and then there is question of a strong chemical bond to the surface of the sensor. This can lead to very specific changes in the electrical sensor properties. 

Kimura used the cholesterol-substituted [15]crown-5 8 in ion sensing membranes. It was found that the addition of the crown ether affects the sensor properties, especially the ion specificity, and it was possible to obtain sensors with extremely high sensitivities [48]. The performance could be further increased by using perfluoroalkyl side chains instead of cholesterol [49]. 

Fig. 4.12 Dansyl-decorated oligo-lysine dendrimer (2nd generation) as dendritic antenna with sensor properties towards metal ions (according to Balzani, Vogtle et al)...

Measurement of circular dichroism can even permit elucidation of relatively small structural changes. CD spectroscopy is also suitable for the solution of specific application-relevant questions. Studies of the sensor properties of chiral dendrimers make use of the fact that complexation of chiral guest molecules induces changes in the CD bands of the host dendrimers. Thus guest-selective chiroptical effects observed in titration experiments with enantiomeric guest molecules give an indication of the potential of the chiral dendrimer to act as an enantioselective sensor [87]. 

Chapter 10 deals with composite films synthesized by the physical vapor deposition method. These films consist of dielectric matrix containing metal or semiconductor (M/SC) nanoparticles. The film structure is considered and discussed in relation to the mechanism of their formation. Some models of nucleation and growth of M/SC nanoparticles in dielectric matrix are presented. The properties of films including dark and photo-induced conductivity, conductometric sensor properties, dielectric characteristics, and catalytic activity as well as their dependence on film structure are discussed. There is special focus on the physical and chemical effects caused by the interaction of M/SC nanoparticles with the environment and charge transfer between nanoparticles in the matrix. 

Physical and chemical properties of PVD-produced composite films with M/SC nanoparticles including dark- and photo-induced conductivity, conductometric sensoring properties, dielectric characteristics, and catalytic activity. 

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