Selectivity, terminology

Fig. 4.2 Selected terminology from blown film production [44]...

A term that is nearly synonymous with complex numbers or functions is their phase. The rising preoccupation with the wave function phase in the last few decades is beyond doubt, to the extent that the importance of phases has of late become comparable to that of the moduli. (We use Dirac s terminology [7], which writes a wave function by a set of coefficients, the amplitudes, each expressible in terms of its absolute value, its modulus, and its phase. ) There is a related growth of literatm e on interference effects, associated with Aharonov-Bohm and Berry phases [8-14], In parallel, one has witnessed in recent years a trend to construct selectively and to manipulate wave functions. The necessary techifiques to achieve these are also anchored in the phases of the wave function components. This bend is manifest in such diverse areas as coherent or squeezed states [15,16], elecbon bansport in mesoscopic systems [17], sculpting of Rydberg-atom wavepackets [18,19], repeated and nondemolition quantum measurements [20], wavepacket collapse [21], and quantum computations [22,23], Experimentally, the determination of phases frequently utilizes measurement of Ramsey fringes [24] or similar" methods [25]. 

This chapter is in no way meant to impart a thorough understanding of the theoretical principles on which computational techniques are based. There are many texts available on these subjects, a selection of which are listed in the bibliography. This book assumes that the reader is a chemist and has already taken introductory courses outlining these fundamental principles. This chapter presents the notation and terminology that will be used in the rest of the book. It will also serve as a reminder of a few key points of the theory upon which computation chemistry is based. 

Before selecting or sizing a specific control device, a careful evaluation of all aspects of the process and contaminants must be made. Improper terminology can lead to poor design and/or operation of any type of device. A list of contaminant definitions in accordance with the USA Standards Institute includes the following. 

This chapter describes the basic principles and procedures for the evaluation of overpressure potential in plant equipment, and for the selection, design and specification of appropriate pressure relieving facilities. The design of closed safety valves and flare headers is included in this chapter, but blowdown drums and flares are covered separately. To properly discuss this subject, the reader should become familiar with the following terminology. 

In this chapter the results of detailed research on the realistic electronic structure of single-walled CNT (SWCNT) are summarised with explicit consideration of carbon-carbon bond-alternation patterns accompanied by the metal-insulator transition inherent in low-dimensional materials including CNT. Moreover, recent selective topics of electronic structures of CNT are also described. Throughout this chapter the terminology "CNT stands for SWCNT unless specially noted. 

Electric Motors, 615 Terminology, 615 Load Characteristics, 616 Basic Motor Types Synchronous and Induction, 616 Selection of Synchronous Motor Speeds, 619 Duty, 625 Types of Electrical Current, 625 Characteristics, 627 ... 

With regard to the common European market, the European Economic Community (EEC) has undertaken numerous activities concerned with materials and material information systems. In one demonstration program for material databases eleven such databases from various countries in the EEC are being cooperatively developed with joint standards for terminology, data presentation, database access, and the user interface of search commands, aids, and menus. For the materials class of plastics, Polymat was selected to participate in this cooperative work. Interesting developments occur from which the users of central material databases in the entire EEC area can benefit. 

It is the aim of this chapter to describe the nature, selectivity, and efficiency of initiation. Section 3.2 summarizes the various reactions associated with initiation and defines the terminology used in describing the process. Section 3.3 details the types of initiators, indicating the radicals generated, the byproducts formed (initiator efficiency), and any side reactions (e.g. transfer to initiator). Emphasis is placed on those initiators that see widespread usage. Section 3.4 examines the properties and reactions of the radicals generated, paying particular attention to the specificity of their interaction with monomers and other components of a polymerization system. Section 3.5 describes some of the techniques used in the study of initiation. 

In all these cases the support has a dramatic effect on the activity and selectivity of the active phase. In classical terminology all these are Schwab effects of the second kind where an oxide affects the properties of a metal. Schwab effects of the first kind , where a metal affects the catalytic properties of a catalytic oxide, are less common although in the case of the Au/Sn02 oxidation catalysts9,10 it appears that most of the catalytic action takes place at the metal-oxide-gas three phase boundaries. 

Others which, according to the Primas definition [13] are graceless. These graceless quantities are defined and selected with the scope of "understanding", i.e. in our terminology with the scope of giving an interpretation of the chemical phenomena. 

Many of the new insecticidal chemicals are complex organic materials with long and complicated names. There is need for simple common names. Without simplified terminology costly losses may result from relatively minor errors in nomenclature. Coined names must be protected if they are to remain available for general use, and must be defined with sufficient accuracy to assure that a standard product will be marketed. Selection of such names requires cooperative consideration by many agencies. Chemists can make important contributions to this undertaking. 

Before you reach for that alcohol-free product, stop and consider the features that you expect and desire in your cosmetics. The class of substances known to chemists as alcohols is commonly confused with the consumer interpretation of alcohol. Knowing the chemist s terminology will help you select the safest and most beneficial formulation. 

We will present mechanistic aspects of the Diels-Alder reaction, its selectivity and reactivity in order to explain solvent effects on the one hand, and the effects of Lewis acids on the other. Other catalytic systems like micelles will also be addressed. Some of the explanations may seem trivial or are well-known but, as we will use these in later sections, a clear terminology is desirable. 

On the other hand, selective, usually applied to a synthesis, means that of all the possible isomers only one isomer is obtained. However, if the reaction product was/is a mixture of isomers one could speak then of the "degree of selectivity". Since usually one of the isomers will be the predominant isomer, we may say that the reaction (or the synthesis) is selective with respect to this particular isomer. As in the case of "specificity", we may refer to "regioselectivity" or to "stereoselectivity" (either diastereoselectivity or enantioselectivity) and may say, for instance, that a synthesis is 80% diastereoselective. According to the most updated terminology "diastereomers" are all the "stereoisomers" that are not "enantiomers", so geometrical isomers are also included in such a definition. 

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