Sedimentation principle

A recent trend in particle analysis has been the introduction of personal computer-based automation (3). Sophisticated software packages can be used to automate and speed up the analysis. In some cases these computers can even carry out continuous process control (qv) (see Computer technology). The latest machines also allow the measurements of smaller particles and can detect a wider range of sizes. Machines based on light-scattering principles are being more widely accepted by the industry because of speed. An average analysis takes from 1—2 min, whereas those based on sedimentation principles require from 10—120 min. 

In colloidal systems the sedimentation principle uses the fact that particles of different mass have different velocities in a fluid at rest when the inertial force acting on the particle is equal to the difference between its weight minus buoyancy and the drag force of the medium ... 

Analysis method that uses the sedimentation principle for determination of colloidal properties of sample. 

An interesting combination of the Lamella sedimentation principle with an up-flow deep bed filter is known as the Rozka filter shown schematically in Figure 5.6. This is in fact a filter-assisted clarifier sometimes used in water... 

At first glance, the contents of Chap. 9 read like a catchall for unrelated topics. In it we examine the intrinsic viscosity of polymer solutions, the diffusion coefficient, the sedimentation coefficient, sedimentation equilibrium, and gel permeation chromatography. While all of these techniques can be related in one way or another to the molecular weight of the polymer, the more fundamental unifying principle which connects these topics is their common dependence on the spatial extension of the molecules. The radius of gyration is the parameter of interest in this context, and the intrinsic viscosity in particular can be interpreted to give a value for this important quantity. The experimental techniques discussed in Chap. 9 have been used extensively in the study of biopolymers. 

Paprika oleoresin (EEC No. E 160c) is the combination of davor and color principles obtained by extracting paprika with any one or a combination of approved solvents acetone, ethyl alcohol, ethylene dichloride, hexane, isopropyl alcohol, methyl alcohol, methylene chloride, and trichloroethylene. Depending on their source, paprika oleoresins are brown—red, slightly viscous, homogeneous Hquids, pourable at room temperature, and containing 2—5% sediment. 

FIG. 18-138 Principl es of centrifugal separation and filtration (a) sedimentation in rotating imperforate bowl (h) Bltration in rotating perforate basket. 

Filters generally achieve a lower final moisture content than obtained by gravity sedimentation and are often fed from thickeners, as indicated in the schematic particulate process shown in Figure 9.2. In this chapter the principles of slurry filtration will be described and certain simplified filter design equations derived. For more complex derivations the reader is referred to specialist texts e.g. Coulson and Richardson (1991), Wakeman (1990a) and Purchas (1981). 

The principle of the solid bowl centrifuge is illustrated in Figure 4.19. It is essentially a device for enhancing the rate of sedimentation. The application of high G, however, creates stress in the machine and is equivalent to the application of pressure (cf. pressure filtration). There is therefore a balance to be struck between separating effect and stress. 

Some of the principles of free surface model proposed by Happel (H10, P7, P8) for studying the rate of sedimentation of solid particles may be adopted for studying heat and mass transfer in gas-liquid dispersions (R9). 

Xenobiotics exist not only in the free state but also in association with organic and mineral components of particles in the water mass, and the soil and sediment phases. This association is a central determinant of the persistence of xenobiotics in the environment, since the extent to which the reactions are reversible is generally unknown. Such residues may therefore be inaccessible to microbial attack and apparently persistent. This is a critical factor in determining the effectiveness of bioremediation (Harkness et al. 1993). Although the most persuasive evidence for the significance of reduced bioavailability comes from data on the persistence of agrochemicals in terrestrial systems (Calderbank 1989), the principles can be translated with modification to aquatic and sediment phases that contain organic matter that resembles structurally that of soils. 

Various techniques and equipment are available for the measurement of particle size, shape, and volume. These include for microscopy, sieve analysis, sedimentation methods, photon correlation spectroscopy, and the Coulter counter or other electrical sensing devices. The specific surface area of original drug powders can also be assessed using gas adsorption or gas permeability techniques. It should be noted that most particle size measurements are not truly direct. Because the type of equipment used yields different equivalent spherical diameter, which are based on totally different principles, the particle size obtained from one method may or may not be compared with those obtained from other methods. 

The movement of a charged particle with respect to an adjacent liquid phase is the basic principle underlying four electrokinetic phenomena electrophoresis, electroosmosis, sedimentation potential, and streaming potential. 

Sedimentation of particles follows the principle outlined above [Eq. (1)] in which particles in the Stokes regime of flow have attained terminal settling velocity. In the airways this phenomenon occurs under the influence of gravity. The angle of inclination, t /, of the tube of radius R, on which particles might impact, must be considered in any theoretical assessment of sedimentation [14,19]. Landahl s expression for the probability, S, of deposition by sedimentation took the form ... 

A further electrokinetic phenomenon is the inverse of the former according to the Le Chatelier-Brown principle if motion occurs under the influence of an electric field, then an electric field must be formed by motion (in the presence of an electrokinetic potential). During the motion of particles bearing an electrical double layer in an electrolyte solution (e.g. as a result of a gravitational or centrifugal field), a potential difference is formed between the top and the bottom of the solution, called the sedimentation potential. 

These three numerical experiments show how the waters of an evaporating lagoon respond differently to the different seasonal perturbations that might affect them. Some record of these perturbations might, in principle, be preserved in the carbonate sediments precipitated in the lagoon. All three perturbations—productivity, temperature, and evaporation rate— cause seasonal fluctuations in the saturation state of the water and in the rate of carbonate precipitation. Temperature oscillations have little effect on the carbon isotopes. Although seasonally varying evaporation rates affect 14C, they have little effect on 13C. Productivity fluctuations affect both of the carbon isotopes. 

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