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Sampling methods advantages

A successful application of GA to conformation sampling is, for example, as a part of flexible docking [12-14], It should be noted, however, that none of the three sampling methods discussed above, MD, MC, and GA, was shown to outperform the other two in any general way. In fact, a comparison of the three methods in the context of flexible docking showed similar efficiency for all three [12], although specific advantages are likely to exist for particular apphcations. [Pg.74]

X-ray fluorescence spectrometry was the first non-destructive technique for analysing surfaces and produced some remarkable results. The Water Research Association, UK, has been investigating the application of X-ray fluorescence spectroscopy to solid samples. Some advantages of nondestructive methods are no risk of loss of elements during sample handling operations, the absence of contamination from reagents, etc. and the avoidance of capital outlay on expensive instruments and highly trained staff. [Pg.451]

III.C.3) and the use of special sampling methods to gain the rapid-convergence advantage of point-successive iteration without inducing asymmetry (Section III.C.2). [Pg.109]

Method Sample introduction Advantages Limitations Mass range (daltons)... [Pg.707]

The density and thermal neutron cross-section values in Table 6 pertain to the thermal neutron attenuation gauging process. In this method, advantage is taken of the large thermal neutron scattering cross-section of hydrogen as compared to most other elements. In its simplest form, when a beam of thermal neutrons of intensity IQ traverses a sample of thickness x, the intensity 1 of neutrons measured by a thermal neutron detector will be... [Pg.107]

The decision on the proper sampling technique will be influenced by each of these factors, and the selection process may go through several field trials until the most appropriate sampling option is established. To assist the reader in the selection of the proper sampling method, Example 3.2 addresses their advantages and limitations. [Pg.122]

An estimation of the amounts of weak acid was made from direct titration on the samples (method D). Most oil samples have TAN of 1 to 2 units (mg KOH g 1 oil) however, samples 8 and 9 have an acidity index of around 4.5 units. Heat of neutralization of acidic products ranges from -3.7 to -20.4 kJ mol"1 and indicates the presence of weak acids in engine oil samples. The precision of calorimetric titration is comparable with conductometric and potentiometric methods. The advantages of calorimetric and conductometric techniques are rapidity, good reproducibility and avoidance of poisoning of detectors by organic substances. [Pg.248]

Methods are not presented in detail, space considerations alone would not permit this. Instead, the chemist is presented with details of methods available for a variety of types of water samples. Methods are described in broad outline, giving enough information for the chemist to decide whether he or she wishes to refer to the original paper. To this end information is provided on applicability of methods, advantages and disadvantages of one method compared to another, interferences, sensitivity, detection limits and data relevant to accuracy and precision. [Pg.458]

Except for extraction, no separation methods have been used in the NMR sample preparations in the interlaboratory comparison tests (7 15). Thus, the chemicals of interest, impurities, and background present in the original sample and in the extract were all present in the NMR sample. The advantage of this... [Pg.326]

It should be emphasized that the objective of combining high-resolution spectroscopic detection with chromatographic separations is to minimize the chromatographic resolution required to achieve identification and quantitation of individual components in complex samples. The advantage of optical over mass spectrometry for this purpose lies in the ability of optical spectroscopic techniques to distinguish readily between isomeric compounds. The combination of separation with spectroscopic analytical techniques, termed "hyphenated methods" by Hirschfeld (31)f is a field of intense activity at the present time it.is our belief that matrix isolation sampling adds an extra analytical dimension to the already powerful techniques achieved in this manner. [Pg.260]

Another excellent demonstration of the wide application range of CEC has been the microanalytical determination of the molecular mass distribution of celluloses in the investigation of cellulose-based objects of cultural and historical value [168]. Stol et al. employed a column packed with bare silica particles of 5 pm diameter with a nominal pore size of 300 A to achieve the separation of 2-kDa to 500-kDa celluloses by size exclusion (SE) CEC. The higher speed and smaller sample size advantages of SE CEC compared to SE HPLC distinguished CEC as the method of choice for the study of cellulose-based objects of archeological importance. [Pg.417]

The variety of sampling methods available in spectrofluorimetry makes it a very versatile technique. The most frequent mode of sample presentation is as a dilute solution, although gases, suspensions, and solid surfaces can also be examined. Combinations of spectrofluorimetry with thin-layer chromatography and high pressure liquid chromatography are particularly advantageous for sensitive and selective detection offluorophores. [Pg.233]


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Sample methods

Sampling methods

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