Rotation extrusion

The pressure exerted by the rotating extrusion heads on the screen as product is being pushed out in an A-R screw extruder (25) is shown in Figure 10. Each spike in the profile represents one revolution of the extrusion head while the frequency represents screw speed. Based on the shear stress developed during extrusion, wet mixtures of MCC-lactose had a lower yield stress in the radial screw extruder (130kN/m ) than in the ram... 

The counter-rotating extrusion die for LCPhas been used with a conventional vacuum tank, tube puller, and cutter to make high-quality LCP tube. Tubing from 2 mm OD to 50 mm OD has been extruded with wall thickness ranging from 0.25 mm to 6 mm. 

Thiirane 1,1-dioxides extrude sulfur dioxide readily (70S393) at temperatures usually in the range 50-100 °C, although some, such as c/s-2,3-diphenylthiirane 1,1-dioxide or 2-p-nitrophenylthiirane 1,1-dioxide, lose sulfur dioxide at room temperature. The extrusion is usually stereospeciflc (Scheme 10) and a concerted, non-linear chelotropic expulsion of sulfur dioxide or a singlet diradical mechanism in which loss of sulfur dioxide occurs faster than bond rotation may be involved. The latter mechanism is likely for episulfones with substituents which can stabilize the intermediate diradical. The Ramberg-Backlund reaction (B-77MI50600) in which a-halosulfones are converted to alkenes in the presence of base, involves formation of an episulfone from which sulfur dioxide is removed either thermally or by base (Scheme 11). A similar conversion of a,a -dihalosulfones to alkenes is effected by triphenylphosphine. Thermolysis of a-thiolactone (5) results in loss of carbon monoxide rather than sulfur (Scheme 12). 

P Injection, blow, extrusion and rotational Pipe, pipe fittings, surgical implants, coatings, wire and cable insulation... 

F-G F Thermoforming, injection, blow, rotational and extrusion molds Business machine and camera housings, blowers, bearings, gears, pump impellers... 

Polyvinyl Chloride (PVC) 1940 M-H VG G G G Extrusion, injection, rotational, slush, transfer, compression, blow mold Pipe conduit and fittings, cable insulation, downspouts, bottles, film... 

Injection Molding Extrusion Blow Molding Thermoforming Reaction Injection Molding Rotational Molding Compression and Transfer Molding Matched Mold Spray-up... 

Many product designs are inherently limited by the economics of the process that must be used to make them. For example, to date TSs are not blow molded, and they have limited extrusion possibilities. Many hollow products, particularly very large ones, may be produced more economically by the rotational process than by blow molding. The need for a low quantity of products may eliminate certain molding processes and indicate the use of casting or others. 

Process used provides different control capabilities. As an example closed molding (injection, compression, etc.) provides fine detail on all surfaces. Open molding (blow molding, thermoforming, spray-up, etc.) provides detail only on the one side in contact with the mold, leaving the second side free-formed. Continuous production (extrusion and pultrusion) yields products of continuous length. Hollow (rotational or blow) produces hollow products. These processes can be used creatively to make different types of products. For example, two molded or thermo-formed components can be bonded together to form a hollow product, or they can be blow molded. 

Part Design Blow Molding Casting Compression Extrusion Filament Winding Injection Matched Die Molding Rotational Thermo- forming Transfer Compression Wet lay-up (Contact Molding)... 

Material Family Injection Compression Hansfer Casting Cold Molding Coating Structural Foam Extrusion Laminating Sheet Forming RP Molding FRP Filament Dip and Slush Blow Rotational... 

Important are behaviors associated and interrelated with plastic materials (thermoplastics, thermosets, elastomers, reinforced plastics, etc.) and fabricating processes (extrusion, injection molding, blow molding, forming, foaming, rotational molding, etc.). They are presented so that the technical or non-technical reader can readily understand the interrelationships. 

Most of the compounds were extrusion compounded in a conical, partially intermeshing, counter rotating twin screw extruder (Haake Reomix TW-lOO). The extruder speed was set at 50 rpm and the barrel temperature profile was set to produce a melt temperature of 260°C at the die. Samples were injection molded in a 31.8 MT Battenfeld press with a 59 cc shot size. Where noted, samples were compounded in a 60 cc Brabender internal mixer and compression molded. 

Thermolysis of 16e,f in either solution or gas phase (150-350 °C) gave deuteriated ethylenes (i.e. 40e from 16e and 41f from 16f) with about 95% retention of stereochemis-try ". Similarly, pyrolysis of the stereoisomeric 2,3-diphenylthiirane oxides 16g,h proceeded smoothly to yield stilbenes and sulfur monoxide in more than 70% yield . The extrusion of SO from the trans-isomer proceeds almost stereospecifically, while that from the cis-isomer occurs with complete loss of stereochemistry. This indicates the intervention of a stepwise mechanism, and not a symmetry-allowed nonlinear chelatropic reaction . Based on the fact that all attempts to trap the intermediate with 1,3-dipolarophiles were in vain, whereas a 1 1 adduct was obtained in good yield (about 60%) with the carbon radical scavenger di-p-anisyl thioketone, a mechanistic scheme as depicted in equation 10 has been proposed . Although the radical intermediates are capable of internal rotation about the carbon-carbon bond, for the 2,3-diphenyl case (i.e. 16g,h), the rotation would be... 

The flow toward the surface is caused by the pressure under the indenter. It is analogous to the upward flow around a sphere dropped into a liquid. It is also analogous to inverse extrusion. A model of the flow has been proposed by Brown (2007) in terms of rotational slip. This model reproduces some of the observed behavior, but it is a continuum model and does not define the mechanism of rotational slip. 

Cross-file patent searches, 18 243-244 CrossFire Beilstein, 6 19 Cross-flow filtration, 11 383 15 827, 829 in porous pipes, 11 387-388 with rotating elements, 11 383-387 Cross flow model, 21 706 Cross-flow packed scrubber, 26 687-688 Crossflow plates, 6 762-763 Cross-flow screens, 22 282 Cross-flow velocity, 15 725 Crosshead mandrel, in VDC film extrusion, 25 732-733 Cross-lapping, 17 501 Cross-linkable epoxy thermoplastic system (CET), 10 436... 

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