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Reducing environments composition

Elimination. Recall that the critical factors governing galvanic corrosion of welds are the presence of substantial compositional differences within the weld metal and the exposure of such a weld to a sufficiently aggressive environment. If the aggressiveness of the environment cannot be sufficiently reduced, significant compositional differences within the weld metal must be avoided. This requires following proper... [Pg.330]

H3ASO30 is the dominant dissolved arsenic species in most hydrothermal fluids because the fluids originate in reducing environments and mostly have pH values of 0-8 (Ballantyne and Moore, 1988, 478 Pokrovski et al., 1996 Chapter 2). The concentrations and compositions of dissolved arsenic species in hydrothermal... [Pg.85]

In this paper we review three types of field studies where the method is used to determine very different aspects of sulfur chemistry in the marine environment. These studies include i) the measurement of the intracellular thiol composition of marine phytoplankton in response to light ii) the reduced sulfur composition of anaerobic sediments and iii) the metabolism of potentially toxic hydrogen sulfide by sediment dwelling bivalve molluscs housing endosymbiotic sulfur oxidizing bacteria. [Pg.247]

The depletion in FeO may be understood in at least two ways. First, the crystalline grains may be equilibrium condensates from a hot solar nebular composition gas with iron sequestered to metals or sulfides (see e.g. Chapter 4). In this case the condensed grains either had to condense slowly to form crystal domains, or had been reheated and thermally annealed at a later epoch. The second, alternative explanation is that ferromagnesian amorphous silicate grains were thermally annealed in a reducing environment, e.g. in the presence of carbon. Heating such precursors leads to the formation of metallic spheroids embedded between the forsterite crystals, as the initial FeO component is reduced (see e.g. Fig. 8.3 and Connolly et al. 1994 Jones Danielson 1997 Leroux et al. 2003 Davoisne et al. 2006). Because carbon is ubiquitously present in primitive Solar System materials, this pathway offers a natural explanation to the observed FeO-poor silicate crystals. It is yet to be determined whether low-temperature crystallization processes, discussed in Section 8.1.1, would also lead to FeO depletion. [Pg.241]

Campbell and Van Wyk hot-pressed their iron-palladium and iron-platinum composites at 1090°C (2000°F) and 50MPa. They prepared a variety of composites containing nickel in a similar manner, but none of these was successful. They used graphite dies, and considered that this helped to create a reducing environment during the hot-pressing, which prevented oxidation of the molybdenum disulphide. Hubbell... [Pg.228]

In this report we examine the aqueous solutions associated with reducing environments in relation to the composition and redox properties of sulfur species. [Pg.26]

Nethods of computer simulation. Our purpose is to calculate the evolution of the water composition in reducing environments. The sulfur system is assumed to be the result of a constant yield of sulfur at a given initial oxidation level included between -2 and 0, plus modifications brought about by possible oxidation. [Pg.42]

Introduction actinide solubilities in reference waters. In this section, the environmental chemistry of the actinides is examined in more detail by considering three different geochemical environments. Compositions of groundwater from these environments are described in Tables 5 and 6. These include (i) low-ionic-strength reducing waters from crystalline rocks at nuclear waste research sites in Sweden (ii) oxic water from the J-13 well at Yucca Mountain, Nevada, the site of a proposed repository for high-level nuclear waste in tuffaceous rocks and (iii) reference brines associated with the WIPP, a repository for TRU in... [Pg.4770]

The physical differences between inherent and extraneous ash are important not only to those interested in cleaning coal but also to those concerned with the fireside behavior of coal ash. Inherent material is so intimately mixed with coal that its thermal history is linked to the combustion of the coal particle in which it is contained. Therefore, it will most likely reach a temperature in excess of the gas in the immediate surroundings. The close proximity of each species with every other species permits chemical reaction and physical changes to occur so rapidly that the subsequent ash particles formed will behave as a single material whose composition is defined by the mixture of minerals contained within the coal particle. The atmosphere under which the individual transformations take place will, no doubt, approach a reducing environment. Figure 2 illustrates a model of the coal and mineral matter as fed to the combustor and the fate of the minerals after combustion [13]. [Pg.356]

The interconnect material s function is to connect the single cells to provide higher output. They are in contact with both the anode and the cathode. Therefore, they must be stable with both electrode materials and in oxidizing and reducing environments. To reduce the ohmic losses and increase efficiency, the interconnect material must also maintain a low electrical resistance. Basically, two materials are used as interconnect materials metallic and ceramic materials, in which chromium are present, such as CoCr204, YCrOj, and LaCrOj. Glass composite interconnects have also been considered. [Pg.108]

The effects on fiber properties of exposure to composite fabrication conditions can be simulated by a relatively short exposure of fibers to high temperatures in an inert or reducing environment. [Pg.43]


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