Reactions metal oxide containing

Manganaies IV), manganites. Mixed-metal oxides containing Mn(IV). Prepared by solid state reactions. 

Ionic metal oxides contain the oxide ion, which is a very strong base. Therefore, the addition of a metal oxide to water will result in a basic solution as a result of the reaction... 

Metal oxides contain the oxide ion, O2-. The ionic equation for this reaction is therefore ... 

Metal oxides containing single metalhc elements (binary oxides) and more than two metallic elements (double oxides and salts of oxoacids) are commonly used as catalysts in a variety of chemical reactions. Oxide and metallic catalysts are two major groups of industrial catalysts. In practice, most catalysts are produced from mixtures of more than two phases the phase primarily responsible for the catalysis is called the active component. 

The first step in the reaction is the formation of the catalytically active species and then coordination with the hydroperoxide. This is followed by the ratedetermining oxygen-transfer step, for which two reaction pathways have been suggested. One of these is a mechanism involving a metal-oxide-containing active species, while the other involves an activated complex between the catalyst and the intact hydroperoxide molecule. The latter is confirmed by experiments with 0-enriched water and by the results of the steric effects. 

Metal oxides react with acids in exchange reactions. All acids contain hydrogen. Obviously all metal oxides contain oxygen. When a metal oxide is added to an acid, the hydrogen from the add swaps partners with the metal from the oxide and joins up with the oxygen to form water. 

Apply Scientists want to release the oxygen from its metal oxide using a decomposition reaction metal oxide —> metal -1- oxygen. To assess the viability of this idea, determine the amount of oxygen per kilogram contained in each of the oxides found in lunar soil. 

Transition metal oxide containing zeolites are used in selective oxidation reactions, ammoxidation, aromatization, photocatalysis and the selective catalytic reduction of NO. Often, isolated, zeolite-boimd oxidic species are identified as the most active sites in these reactions. Therefore, the preparation procedures are usually aimed at creating very small intrazeolitic oxide clusters or even isolated metal oxo-spedes. 

These redox reactions exhibit the two oxidation states of iridium oxide by which it is able to create an electrochemical potential as a pH sensor being similar to the conventional glass electrode. If there is any variation in the stoichiometry of the metal oxide then its pH response behavior will also be changed. If the metal oxide contains hydroxyl (OH ) groups at its surface the pH response will also be generated due to ion exchange ... 

Aluminum-containing propellants deflver less than the calculated impulse because of two-phase flow losses in the nozzle caused by aluminum oxide particles. Combustion of the aluminum must occur in the residence time in the chamber to meet impulse expectations. As the residence time increases, the unbumed metal decreases, and the specific impulse increases. The soHd reaction products also show a velocity lag during nozzle expansion, and may fail to attain thermal equiUbrium with the gas exhaust. An overall efficiency loss of 5 to 8% from theoretical may result from these phenomena. However, these losses are more than offset by the increase in energy produced by metal oxidation (85—87). 

DMF can also be manufactured from carbon dioxide, hydrogen, and dimethylamine ia the presence of halogen-containing transition-metal compounds (18). The reaction has also been performed with metal oxides and salts of alkaU metals as promoters (19). 

Waterborne contact adhesives contain an elastomer in latex form, usually an acryflc or neoprene-based latex, and a heat-reactive, cross-linkable phenohc resin in the form of an aqueous dispersion. The phenoHc resin improves metal adhesion, green strength, and peel strength at elevated temperature. A typical formulation contains three parts latex and one part phenohc dispersion (dry weight bases). Although metal oxides may be added, reaction of the oxide with the phenohc resin does not occur readily. 

At high temperatures, aluminum reduces many oxygen-containing compounds, particularly metal oxides. These reactions, of the type shown in equation 6, are used in the manufacture of certain metals and alloys, as well as in the thermite welding process. ... 

Isopropyl alcohol can be oxidized by reaction of an a,P-unsaturated aldehyde or ketone at high temperature over metal oxide catalysts (28). In one Shell process for the manufacture of aHyl alcohol, a vapor mixture of isopropyl alcohol and acrolein, which contains two to three moles of alcohol per mole of aldehyde, is passed over a bed of uncalcined magnesium oxide [1309-48-4] and zinc oxide [1314-13-2] at 400°C. The process yields about 77% aHyl alcohol based on acrolein. 

Dithiophosphates. These compounds (13) are made by reaction of an alcohol with phosphoms pentasulfide, then neutralization of the dithiophosphoric acid with a metal oxide. Like xanthates, dithiophosphates contain no nitrogen and do not generate nitrosamines during vulcanization. Dithiophosphates find use as high temperature accelerators for the sulfur vulcanization of ethylene—propylene—diene (EPDM) terpolymers. 

Meta.1 Oxides. Halogen-containing elastomers such as polychloropreae and chlorosulfonated polyethylene are cross-linked by their reaction with metal oxides, typically ziac oxide. The metal oxide reacts with halogen groups ia the polymer to produce an active iatermediate which then reacts further to produce carbon—carbon cross-links. Ziac chloride is Hberated as a by-product and it serves as an autocatalyst for this reaction. Magnesium oxide is typically used with ZnCl to control the cure rate and minimize premature cross-linking (scorch). 

Beryllium carbide slowly hydroly2es to beryllium oxide and methane in the presence of atmospheric moisture although months may be requited to complete the reaction. Any carbon contained in beryllium metal is present as the carbide because the solubiUty of carbon in beryllium is extremely low. 

A number of metal chelates containing transition metals in their higher oxidation states are known to decompose by one electron transfer process to generate free radical species, which may initiate graft copolymerization reactions. Different transition metals, such as Zn, Fe, V, Co, Cr, Al, etc., have been used in the preparation of metal acetyl acetonates and other diketonates. Several studies demonstrated earlier that metal acetyl acetonates can be used as initiators for vinyl polymeriza-... 

Solid catalysts for the metathesis reaction are mainly transition metal oxides, carbonyls, or sulfides deposited on high surface area supports (oxides and phosphates). After activation, a wide variety of solid catalysts is effective, for the metathesis of alkenes. Table I (1, 34 38) gives a survey of the more efficient catalysts which have been reported to convert propene into ethene and linear butenes. The most active ones contain rhenium, molybdenum, or tungsten. An outstanding catalyst is rhenium oxide on alumina, which is active under very mild conditions, viz. room temperature and atmospheric pressure, yielding exclusively the primary metathesis products. 

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