Rates of deformation

It is rare to be able to observe elastic deformations (which occur for instance during earthquakes) since by definition an elastic deformation does not leave any record. However, many subsurface or surface features are related to the other two modes of deformation. The composition of the material, confining pressure, rate of deformation and temperature determine which type of deformation will be initiated. 

A constitutive equation is a relation between the extra stress (t) and the rate of deformation that a fluid experiences as it flows. Therefore, theoretically, the constitutive equation of a fluid characterises its macroscopic deformation behaviour under different flow conditions. It is reasonable to assume that the macroscopic behaviour of a fluid mainly depends on its microscopic structure. However, it is extremely difficult, if not impossible, to establish exact quantitative... 

Common experimental evidence shows that the viscosity of polymers varies as they flow. Under certain conditions however, elastic effects in a polymeric flow can be neglected. In these situations the extra stress is again expressed, explicitly, in terms of the rate of deformation as... 

Theoretically the apparent viscosity of generalized Newtonian fluids can be found using a simple shear flow (i.e. steady state, one-dimensional, constant shear stress). The rate of deformation tensor in a simple shear flow is given as... 

The rate of deformation tensor in a pure elongatioiial flow has the following form... 

The elongation viscosity defined by Equation (1.19) represents a uni-axial extension. Elongational flows based on biaxial extensions can also be considered. In an equi-biaxial extension the rate of deformation tensor is defined as... 

All of the described differential viscoelastic constitutive equations are implicit relations between the extra stress and the rate of deformation tensors. Therefore, unlike the generalized Newtonian flows, these equations cannot be used to eliminate the extra stress in the equation of motion and should be solved simultaneously with the governing flow equations. 

The practical and computational complications encountered in obtaining solutions for the described differential or integral viscoelastic equations sometimes justifies using a heuristic approach based on an equation proposed by Criminale, Ericksen and Filbey (1958) to model polymer flows. Similar to the generalized Newtonian approach, under steady-state viscometric flow conditions components of the extra stress in the (CEF) model are given a.s explicit relationships in terms of the components of the rate of deformation tensor. However, in the (CEF) model stress components are corrected to take into account the influence of normal stresses in non-Newtonian flow behaviour. For example, in a two-dimensional planar coordinate system the components of extra stress in the (CEF) model are written as... 

Incorporation of viscosity variations in non-elastic generalized Newtonian flow models is based on using empirical rheological relationships such as the power law or Carreau equation, described in Chapter 1. In these relationships fluid viscosity is given as a function of shear rate and material parameters. Therefore in the application of finite element schemes to non-Newtonian flow, shear rate at the elemental level should be calculated and used to update the fluid viscosity. The shear rale is defined as the second invariant of the rate of deformation tensor as (Bird et at.., 1977)... 

Ec[uation (4.91) is written using the components of the rate of deformation tensor D as ... 

Non-dimensionalization of the stress is achieved via the components of the rate of deformation tensor which depend on the defined non-dimensional velocity and length variables. The selected scaling for the pressure is such that the pressure gradient balances the viscous shear stre.ss. After substitution of the non-dimensional variables into the equation of continuity it can be divided through by ieLr U). Note that in the following for simplicity of writing the broken over bar on tire non-dimensional variables is dropped. 

C - INITIALIZE TEMPERATURE SECOND IWARIANT OF RATE OF DEFORMATION TENSOR... 

FINDS THE SECOND IWARIAI JT OF RATE OF DEFORMATION AT INTEGRATION POINTS... 

Another aspect of plasticity is the time dependent progressive deformation under constant load, known as creep. This process occurs when a fiber is loaded above the yield value and continues over several logarithmic decades of time. The extension under fixed load, or creep, is analogous to the relaxation of stress under fixed extension. Stress relaxation is the process whereby the stress that is generated as a result of a deformation is dissipated as a function of time. Both of these time dependent processes are reflections of plastic flow resulting from various molecular motions in the fiber. As a direct consequence of creep and stress relaxation, the shape of a stress—strain curve is in many cases strongly dependent on the rate of deformation, as is illustrated in Figure 6. 

For a Hquid under shear the rate of deformation or shear rate is a function of the shearing stress. The original exposition of this relationship is Newton s law, which states that the ratio of the stress to the shear rate is a constant, ie, the viscosity. Under Newton s law, viscosity is independent of shear rate. This is tme for ideal or Newtonian Hquids, but the viscosities of many Hquids, particularly a number of those of interest to industry, are not independent of shear rate. These non-Newtonian Hquids may be classified according to their viscosity behavior as a function of shear rate. Many exhibit shear thinning, whereas others give shear thickening. Some Hquids at rest appear to behave like soHds until the shear stress exceeds a certain value, called the yield stress, after which they flow readily. 

Extensional Viscosity. In addition to the shear viscosity Tj, two other rheological constants can be defined for fluids the bulk viscosity, iC, and the extensional or elongational viscosity, Tj (34,49,100—107). The bulk viscosity relates the hydrostatic pressure to the rate of deformation of volume, whereas the extensional viscosity relates the tensile stress to the rate of extensional deformation of the fluid. Extensional viscosity is important in a number of industrial processes and problems (34,100,108—110). Shear properties alone are insufficient for the characterization of many fluids, particularly polymer melts (101,107,111,112). 

Fluids without any sohdlike elastic behavior do not undergo any reverse deformation when shear stress is removed, and are called purely viscous fluids. The shear stress depends only on the rate of deformation, and not on the extent of derormation (strain). Those which exhibit both viscous and elastic properties are called viscoelastic fluids. 

Purely viscous fluids are further classified into time-independent and time-dependent fluids. For time-independent fluids, the shear stress depends only on the instantaneous shear rate. The shear stress for time-dependent fluids depends on the past history of the rate of deformation, as a result of structure or orientation buildup or breakdown during deformation. 

Velocity The term kinematics refers to the quantitative description of fluid motion or deformation. The rate of deformation depends on the distribution of velocity within the fluid. Fluid velocity v is a vector quantity, with three cartesian components i , and v.. The velocity vector is a function of spatial position and time. A steady flow is one in which the velocity is independent of time, while in unsteady flow v varies with time. 

Rate of Deformation Tensor For general three-dimensional flows, where all three velocity components may be important and may vaiy in all three coordinate directions, the concept of deformation previously introduced must be generahzed. The rate of deformation tensor Dy has nine components. In Cartesian coordinates. 

Vorticity The relative motion between two points in a fluid can be decomposed into three components rotation, dilatation, and deformation. The rate of deformation tensor has been defined. Dilatation refers to the volumetric expansion or compression of the fluid, and vanishes for incompressible flow. Rotation is described bv a tensor (Oy = dvj/dxj — dvj/dxi. The vector of vorticity given by one-half the... 

It is evident from their definitions that /, and hence d and w depend on the instantaneous rate of deformation of the current configuration. On the other hand, F and hence U and R relate the current configuration to the reference configuration. In order to find relations for d and w in terms of material derivatives of U and R, the material derivative of (A. 13) may be inserted into (A. 10)... 

We also want to point out the difference between simple rate-dependent phenomena and path-dependent effects. Simple rate dependence means that the internal micromechanical state (as possibly represented by some meso-scale variables) depends only on the current deformation and current rate of deformation the material has no memory of the past. In terms of dislocation dynamics and (7.1), a simple rate-dependent constitutive description would be one in which... 

In this case the shear stress (in the plastic deformation region) depends on how much plastic strain y that has accumulated and the current rate of deformation y. For example, in shock compression the shear stress t behind the shock front (where y is nominally zero) is a function of y only, as given by the implicit relationship... 

Here t has no memory of the rate of deformation in getting to the final plastic strain y. This differs from a path-dependent law, in which the strength (for example) depends in detail on the path followed in getting to the current macroscale state. 

Unloading experiment.. At least, for opening cracks, or unloading, experiments, it is necessary to differentiate between the rates of deformation experienced in the bulk and in the vicinity of the crack tip. Greenwood and Johnson [109] have shown that... 

Creep deformation can be split into three separate parts. The first, transient creep, is a short lived phenomenon which gives a high initial rate of deformation but decays according to the expression ... 

MFI of the composition to that of the matrix, as a function of the filler concentration. It can be seen that, as the concentration of a particular filler increases, the index increases too for one matrix but decreases for another, and varies by a curve with an extremum for a third one. Even for one and the same polymerfiller system and a fixed concentration of filler, the stress-strain characteristics, such as ultimate stress, may, depending on the testing conditions (temperature, rate of deformation, etc.) be either higher or lower than in the reference polymer sample [36],... 

For all high-filled polymers, whatever the nature of the matrix and filler, it has been found [297,298] that the Bagley pressure loss at extruder inlet increases sharply in a certain range of temperatures and rates of deformation. What distinguishes composites with PMF is that for them the pressure loss at the inlet begins at lower deformation rates. 

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