Random polyester

Table 2. Application of MI to critical compositions for LC phase formation in random polyesters...

The general structure of the random polyester amide BAK1095. The molecule shown contains two moieties from 1,4-butanediol, one moiety from 6-aminocaproic acid and one moiety from adipic acid. The arrows show enzymatic cleavage sites. The question mark indicates that cleavage of the amide bond was not clearly established (Weigand et al.) [19]. 

Flores A, Pietkiewicz D, Stribeck N, Roslaniec Z and Balta Calleja F J (2001) Structural features of random polyester-amide copolymers as revealed by X-ray scattering and microindeiitation hai dness. Macromolecules 34 8094-8100. 

A composite material for a car-repair kit consists of a random mixture of short glass fibres in a polyester matrix. Estimate the maximum toughness of the composite. You may assume that the volume fraction of glass is 30% the fibre diameter is 15 pm the fracture strength of the fibres is 1400 MPa and the shear strength of the matrix is 30 MPa. 

Random block copolymers of polyesters (hard segments) and amorphous glycol soft segments, alloys of ethylene interpolymers, and chlorinated polyolefins are among the evolving thermoplastic elastomers. 

Spray-up Popular system with reinforced plastic production. An air spray gun includes a roller cutter that chops usually glass fiber rovings to a controlled short length before being blown in a random pattern (manually or automatically) onto a surface of the mold simultaneously the gun sprays catalyzed TS polyester plastic. The chopped fibers are plastic coated as they exit the gun s nozzle. The resulting, rather fluffy, RP mass is consolidated with serrated rollers to squeeze out air and reduce or eliminate voids. A closed mold... 

Aromatic polyesters that do not contain any flexible structural units are often nonmeltable or extremely high melting polymers that cannot be processed. Copolymerization is a way to obtain processable wholly aromatic polyesters The Tm versus copolyester composition curve is a U-shaped curve exhibiting a minimum that is generally well below the Tm of corresponding homopolymers. Liquid crystalline aromatic polyesters, for instance, are usually copolymers.72 An example is Ticona s Vectra, a random copolyester containing 4-oxybenzoyl and 6-oxy-2-naphthoyl units in ca. 70 30 mol ratio. This copolymer melts at ca. 

TPEs associating both rigid and soft polyester blocks have also been described. They cannot be obtained by the melt polyesterification used for polyesterether TPEs, since interchange reactions would yield random—rather than block — copolyesters. The preferred method involves the reaction of OH-terminated aliphatic and aromatic-aliphatic polyesters with chain extenders such as diisocyanates and results in copoly(ester-ester-urethane)s. 

As already discussed (Section 2.2.1.3), interchange reactions are also implicated in the formation of random copolyesters exhibiting the most probable molar mass distribution when polyester blends are melt mixed. They are also involved in the randomization of block copolyesters taking place in the melt upon heating.2,m 211... 

Many random copolyesters and polyester-polycarbonates have also been prepared by ester interchange reactions in the molten state. Thus, poly(ethylene terephthalate-co -isophthalates) can be obtained by simple melt blending of PET and poly(ethylene isophthalate) (PEI) homopolyesters at 270°C. The copolymer changes gradually from a block type at the beginning of reaction to a random-type... 

Another important type of condensation polymer are the linear polyesters, such as poly (ethylene terephthalate) (PET) and poly (butylene terephthalate) (PBT). Copolymers of polyesters and PA have been studied in detail, and it has been shown that random copolyesteramides have a low structural order and a low melting temperature. This is even the case for structurally similar systems such as when the group between the ester unit is the same as that between the amide unit, as in caprolactam-caprolactone copolymers (Fig. 3.10).22 Esters and amide units have different cell structures and the structures are not therefore isomorphous. If block copolymers are formed of ester and amide segments, then two melting temperatures are present. 

More definitive evidence of enzymatic attack was obtained with 1 1 copolymers of e-caprolactone and 6-valerolactone crosslinked with varying amounts of a dilactone (98,99). The use of a 1 1 mixture of comonomers suppressed crystallization and, together with the crosslinks, resulted in a low-modulus elastomer. Under in vitro conditions, random hydrolytic chain cleavage, measured by the change in tensile properties, occurred throughout the bulk of the samples at a rate comparable to that experienced by the other polyesters no weight loss was observed. However, when these elastomers were implanted in rabbits, the bulk hydrolytic process was accompanied by very rapid surface erosion. Weight loss was continuous, confined to the... 

In the case of random degradation, the molecular mass drop due to chemical reaction with a contaminant (e.g., H20, alcohol, acid, for a polyester) can easily be calculated. Consider the example of hydrolysis of a step polymer. 

The factors which influence pre-gel intramolecular reaction in random polymerisations are shown to influence strongly the moduli of the networks formed at complete reaction. For the polyurethane and polyester networks studied, the moduli are always lower than those expected for no pre-gel intramolecular reaction, indicating the importance of such reaction in determining the number of elastically ineffective loops in the networks. In the limit of the ideal gel point, perfect networks are predicted to be formed. Perfect networks are not realised with bulk reaction systems. At a given extent of pre-gel intramolecular... 

The copolymerization of lactones took place through enzyme catalysis [92]. The copolymerization of e-CL with d-VL catalyzed by lipase PF affords the corresponding copolymer having a molecular weight of several thousand. From 13C NMR analysis, the copolymer was found to be of random structure having both units, suggesting the frequent occurrence of transesterifications between the polyesters. In the copolymerization of 8-OL with e-CL or DDL, random copolyesters were also formed [84], whereas the copolymer from e-CL and PDL was not statistically random [88]. 

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