Radiator coatings

Some polymers like PE and NR get cross-linked on exposure to radiation while others like those based on vinylidene polymers, e.g., polymethylmethacrylate (PMMA), polyisobutylene, degrade. Certain other types of polymer stmctures (high aromatic content or thermoset) resist degradation by high-energy radiation. Coating polymers usually contain acrylic, methacryUc, or fumaric vinyl unsaturation along or attached to the backbone. 

Photoinitiators are perhaps the most important component in uv cured radiation coatings. The photoinitiator is an ingredient that absorbs light and is responsible for the production of free radicals in a free radical polymerized system or cations in a cationic photoinitiated system. The photoinitiators are usually added to the reactive coating formulations in concentration ranges from less than 1 to 20 percent by weight based on the total formulation. The absorption bands of the photoinitiators should overlap the emission spectra of the various commercial light sources. 

Equation 12.2 reflects a base case of 9 mg/mile with a 0.29 m2 surface area, ratio of airflow to vehicle speed at 40%, and conversion of base case to 80% from the UAM. The deactivation factor (DF) is DF = (aged ozone conversion/ fresh ozone conversion). To determine the deactivation factor, on-road aging of radiators coated with catalyst was run for 150,000 miles and DFs at that point were determined. Freshly coated radiators were exposed to an accelerated aging test and DFs were calculated and compared for accuracy. Figure 12.4 shows the calculation of deactivation factors for two different radiators with different core geometries. 

Gush, D. P. and Ketley, A. D., Chemical Coatings Conference II, Radiation Coatings, National Paint and Coatings Association, Washington, D. C., May 10,1978. 

Given flow times of 20-40 s (DIN 4 cup), an application rate of 20-100 g/m is used. The drying time at room temperature is approx, six hours. After flash-off of the solvent (4-5 min at 50 C), the coating can be cured in approx. 10 min at 80 C in a circulating air oven, in 1 -2 min under IR radiation or at a rate of. for example. 3 m/min under UV radiation. Coatings applied in this way have outstanding properties such as good scratch resistance, adhesion and resistance to household chemicals. 

Uses Pigment for aq., nonaq. and LIV-curing systems, inks, coatings, food pkg., childrens toys, security documents, lottery tickets, temperature indicators, radiator coatings... 

The importance of polymer composites arises largely from the fact that such low density materials can have unusually high elastic modulus and tensile strength. Polymers have extensive applications in various fields of industry and agriculture. They are used as constructional materials or protective coatings. Exploitation of polymers is of special importance for products that may be exposed to the radiation or temperature, since the use of polymers make it possible to decrease the consumption of expensive (and, sometimes, deficient) metals and alloys, and to extent the lifetime of the whole product. 

Specimens used in tests were sections of cables with PVC outer coating. PVC was plasticized with DOF softener. The materials considered were exposed to the radiation and thermal aging. The samples have been irradiated at room temperature by hard gamma rays with 10 rad/sec dose power. A number of samples had been heated for long different times at 90°C. Besides a special specimens were cut out from outer coating for test on tensile machine like "Instron". The total doses of irradiation, times of heating and elongations at break obtained with "Instron" are listed in Table 1. 

When considering how the evolution of life could have come about, the seeding of terrestrial life by extraterrestrial bacterial spores traveling through space (panspermia) deserves mention. Much is said about the possibility of some form of life on other planets, including Mars or more distant celestial bodies. Is it possible for some remnants of bacterial life, enclosed in a protective coat of rock dust, to have traveled enormous distances, staying dormant at the extremely low temperature of space and even surviving deadly radiation The spore may be neither alive nor completely dead, and even after billions of years it could have an infinitesimal chance to reach a planet where liquid water could restart its life. Is this science fiction or a real possibility We don t know. Around the turn of the twentieth century Svante Arrhenius (Nobel Prize in chemistry 1903) developed this theory in more detail. There was much recent excitement about claimed fossil bacterial remains in a Martian meteorite recovered from Antarctica (not since... 

Better detection limits are obtained using fluorescence, particularly when using a laser as an excitation source. When using fluorescence detection, a small portion of the capillary s protective coating is removed and the laser beam is focused on the inner portion of the capillary tubing. Emission is measured at an angle of 90° to the laser. Because the laser provides an intense source of radiation that can be focused to a narrow spot, detection limits are as low as 10 M. 

The aluminium absorbs the radiation, heats up and transfers the heat to xenon gas contained in the cell. As the temperature of the gas varies the curvature of a flexible mirror of antimony-coated collodion, forming a part of the cell, changes. Reflection of a light beam from this mirror, which is on the outside of the Golay cell, indicates its curvature and therefore the intensity of radiation absorbed by the cell. 

One of the mirrors forming the laser cavity is as close to 100% reflecting as possible (99.5%) the other is coated to allow 1% of the radiation to emerge as the laser beam. 

Fig. 1. The hthographic process. A substrate is coated with a photosensitive polymer film called a resist. A mask with transparent and opaque areas directs radiation to preselected regions of the resist film. Depending on resist characteristics, exposed or unexposed portions of the film are removed using a developer solvent. The resulting pattern is then transferred to the substrate surface and the resist is stripped.

Higher alkyl acrylates and alkyl-functional esters are important in copolymer products, in conventional emulsion appHcations for coatings and adhesives, and as reactants in radiation-cured coatings and inks. In general, they are produced in direct or transesterification batch processes (17,101,102) because of their relatively low volume. 

Solution polymers are the second most important use for acryflc monomers, accounting for about 12% of the monomer consumption. The major end use for these polymers is in coatings, primarily industrial finishes. Other uses of acryflc monomers include graft copolymers, suspension polymers, and radiation curable inks and coatings. 

The Curing of Coatings with UItra-Uiolet Radiation, D8667 G.D., Tioxide of Canada, Sorel, P.Q., Canada. 

Polyimide. Polyimide is a biaxiaHy oriented high performance film that is tough, flexible, and temperature- and combustion-resistant. Its room temperature properties compare to poly(ethylene terephthalate), but it retains these good characteristics at temperatures above 400°C. Its electrical resistance is good and it is dimensionally stable. The principal detriment is fairly high moisture absorbance. The main uses are for electrical insulation, particularly where high temperatures are prevalent or ionizing radiation is a problem. The films may be coated to reduce water absorption and enhance... 

Requirements for space suits are more complex and frequently involve garments that can circulate water and/or air through the fibrous assembly. Laminated and/or coated garments with specific requirements to pressure, radiation, temperature, and humidity are more stmcturaHy complex as a textile product relative to the types of fibers used in this aerospace fabrication. 

---