Pulse test procedure

When developing a liquid phase adsorptive separation process, a laboratory pulse test is typically used as a tool to search for a suitable adsorbent and desorbent combination for a particular separation. The properties of the suitable adsorbent, such as type of zeolite, exchange cation and adsorbent water content, are a critical part of the study. The desorbent, temperature and liquid flow circulation are also critical parameters that can be obtained from the pulse test. The pulse test is not only a critical tool for developing the equilibrium-selective adsorption process it is also an essential tool for other separation process developments such as rate-selective adsorption, shape-selective adsorption, ion exchange and reactive adsorption. 

A pulse test procedure [6] begins with an injection of a small pulse of the feed mixture to be separated into a desorbent stream flowing through a packed adsorbent column at a fixed flow rate and temperature. The on-line column effluent composition is then determined as a function of time or volume of desorbent passed by gas or liquid chromatography. Particularly important is the sequence and time when each of the feed components exit the packed adsorbent column because these characteristics describe the specific adsorbate and adsorbent interactions. By determining the interactions using the pulse test, the separation process can be optimized. 

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The breakthrough procedure is similar to the pulse test procedure except a large amount of high feed concentration is used. The breakthrough procedure can be described as follows ... 

Ultrasonics. The most widely used nondestmctive test method for explosion-welded composites is ultrasonic inspection. Pulse-echo procedures (ASTM A435) are appHcable for inspection of explosion-welded composites used in pressure appHcations. 

The bar impact test, which is a variation of the plate impact test, produces a one-dimensional compressive square stress pulse which neglects the effects of lateral inertia caused by Poisson s effect. This testing procedure was developed in the laboratory of the author and his colleague,30 and is described here in some detail. 

One way around this problem is to find a nondestructive test that would still give good indication of firing characteristics. This has been done, using the Rosenthal model (seen earlier) as the basis, with transient-pulse testing or electrothermal response. This procedure can be used on 100% of the units fabricated and find individual bad actors to be weeded out as well as to find systematic or lot to lot shifts at the same time. This procedure is based upon the same heat transfer and energy balance equation we saw earlier... 

Functional high-throughput multifunctional screening of chemosensitive properties of conductive polymers was described recently.44 The authors developed a minimal test procedure consisting of two concentration pulses of an analyte at the same concentration and a sequence of concentration pulses at increased concentrations. Automated analysis of the materials responses has given the following information ... 

The procedure for the scale-up of an expanded-bed-adsorption process is relatively straightforward and the principles are similar to those used for a packed-bed process. It is important that the length of the laboratory column be equal to the pilot-plant column. If the pilot-plant equipment is not specifically designed for expanded-bed-adsorption procedures, it should be modified as described in the previous section on laboratory equipment. To verify that the expanded-bed flow patterns are similar for the lab and pilot-plant columns, pulse tests using NaCl solution should be carried out. The adsorbent used, whole-broth-solvent ratio, bed height, and linear velocity, should not be changed on scale-up. The volumetric flow should be increased m proportion to the mcrease in the cross-sectional area of the two columns. Thus, the superficial velocity will be maintained and the adsorption and the fluidization properties will be constant. 

In dust collection, the laboratory test procedures are designed to support a particular theory. A more practical procedure, on the other hand, is described by Barlow and involves the construction of a pilot dust collector. The equipment houses four filter sleeves and is capable of operation in both reverse air and pulse cleaning... 

Standard procedures that are used for testing of construction materials are based on square pulse actions or their various combinations. For example, small cyclic loads are used for forecast of durability and failure of materials. It is possible to apply analytical description of various types of loads as IN actions in time and frequency domains and use them as analytical deterministic models. Noise N(t) action as a rule is represented by stochastic model. 

To determine the optimal parameters, traditional methods, such as conjugate gradient and simplex are often not adequate, because they tend to get trapped in local minima. To overcome this difficulty, higher-order methods, such as the genetic algorithm (GA) can be employed [31,32]. The GA is a general purpose functional minimization procedure that requires as input an evaluation, or test function to express how well a particular laser pulse achieves the target. Tests have shown that several thousand evaluations of the test function may be required to determine the parameters of the optimal fields [17]. This presents no difficulty in the simple, pure-state model discussed above. 

Rote et al. (1993, 1994) used a carotid thrombosis model in dogs. A calibrated electromagnetic flow meter was placed on each common carotid artery proximal to both the point of insertion of an intravascular electrode and a mechanical constrictor. The external constrictor was adjusted with a screw until the pulsatile flow pattern decreased by 25 % without altering the mean blood flow. Electrolytic injury to the intimal surface was accomplished with the use of an intravascular electrode composed of a Teflon-insulated silver-coated copper wire connected to the positive pole of a 9-V nickel-cadmium battery in series with a 250000 ohm variable resistor. The cathode was connected to a subcutaneous site. Injury was initiated in the right carotid artery by application of a 150 xA continuous pulse anodal direct current to the intimal surface of the vessel for a maximum duration of 3 h or for 30 min beyond the time of complete vessel occlusion as determined by the blood flow recording. Upon completion of the study on the right carotid, the procedure for induction of vessel wall injury was repeated on the left carotid artery after administration of the test drug. 

Resilient Modulus. The Schmidt test device (22) was used to measure the resilient modulus of all samples at 68°F. A load pulse time of 0.1 sec and a rest time between pulses of 2.9 sec was used in this procedure. The results of these tests are presented in Table III. 

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