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Proper liquids

An ideal gas has by definition no intermolecular structure. Also, real gases at ordinary pressure conditions have little to do with intermolecular interactions. In the gaseous state, molecules are to a good approximation isolated entities traveling in space at high speed with sparse and near elastic collisions. At the other extreme, a perfect crystal has a periodic and symmetric intermolecular structure, as shown in Section 5.1. The structure is dictated by intermolecular forces, and molecules can only perform small oscillations around their equilibrium positions. As discussed in Chapter 13, in between these two extremes matter has many more ways of aggregation the present chapter deals with proper liquids, defined here as bodies whose molecules are in permanent but dynamic contact, with extensive freedom of conformational rearrangement and of rotational and translational diffusion. This relatively unrestricted molecular motion has a macroscopic counterpart in viscous flow, a typical property of liquids. Molecular diffusion in liquids occurs approximately on the timescale of nanoseconds (10 to 10 s), to be compared with the timescale of molecular or lattice vibrations, to 10 s. [Pg.230]


The following are several examples TEMA K-type shells, whieh allow for proper liquid disengagement for reboilers TEMA J-type shells, whieh aecommodate high vapor flows by allowing for divided flow in the shellside Two-pass TEMA F-type shells, whieh ean be used for applieations when a temperature eross exists (below) TEMA D-type front head designs, whieh are often the answer for high-pressure tubeside applieations. [Pg.35]

Proper liquid level, seal fluid contaminants, foam, vessel corrosion, distributor pluggage, functioning instrumentation... [Pg.151]

Passive, but must have system to verify proper liquid level, and composition if pool liquid is used as a neutralizing or kill liquid. [Pg.86]

Let us look at some of the information available to answer the above questions, although we would like to point out that we are not now attempting to develop a pattern by which one would choose the proper liquid substrate as this is discussed in Chapter 3. [Pg.88]

As discussed previously, proper liquid distribution on the rotor is critical to performance, but it is also important to prevent rotor imbalance. Rotor imbalance... [Pg.61]

The plant operator opened the nitrogen valves that were both upstream and downstream of the plants nitrogen pressure regulator to pad the truck. The truck manifold that was in front the right rear wheels contained a pressure gauge that read the expected 20 psig (1.36 bar). The operator opened the proper liquid delivery valves, started the unloading pump, and left to handle other chores. The driver stayed with the truck, as was the normal procedure. [Pg.25]

The aspirator is not a very fast pump (1-2 gallons/minute), nor does it create a powerful vacuum ( 10 mm Hg) (with proper liquid nitrogen trapping, aspirators can achieve vacuums as great as 10 2 torr). 1 It is ideally suited for emptying large containers of liquids down a sink or for supplying the vacuum necessary for a filter flask. [Pg.342]

At this purpose N,V,T MD simulations of 10 ns each, were performed at 300 and 293 K, constraining Mb-CO in the center of the simulation box, filled with water molecules, at the proper liquid density. The rototranslational constraint [27] was used to keep the Mb-CO rototranslationally fixed at the center of the simulation box. [Pg.206]

Sample preparation techniques involve the chemical separation of the specific chemical forms of a radionuclide, and the preparation of the counting sample by mixing the separated nuclides with the proper liquid scintillator. [Pg.189]

Instrumentation on the unit consists of a magnetic flowmeter to measure feed rate and a level controller to maintain proper liquid height in the flotation cells. [Pg.381]

The immersion of the system in a proper liquid ensures a good coupling between transmitter/sample/receiver and promotes the temperature control of the system. When a wave is incident normally to the boundary between two media both transmission and reflection occur. The reflection coefficient is high for... [Pg.109]

Rotation speeds to 40 r/min are possible with cakes typically 3 to 6 mm (0.12 to 0.24 in) thick. Filter sizes range from 930 cm to 19 m (1 to 207 fF) with 93 percent of the area active. The slurry is fed into a conical feed tank designed to prevent solids from settling without the use of mechanical agitators. The proper liquid level is maintained by overflow, and submergence ranges from 5 to 70 percent of the drum circumference. [Pg.1720]

Two basic requirements for superconductivity are the pairing of electrons and phase coherence. Both of these can be satisfied in highly anisotropic arrays of loosely associated double bonds which are not directly chemically bonded as further association due to extra electrons would then be impossible. These criteria seem to be fulfilled by proper liquid crystalline state of matter. [Pg.464]

The liquid was transferred to the test chamber through a closed system. The storage dewar was pressurized from 2 to 6 psi to transfer the liquid. It was possible to maintain the proper liquid level during an experiment (about 3 in. above the test specimen) by controlling the dewar pressure. [Pg.212]

Selection of the proper liquid must satisfy all of the following requirements ... [Pg.6]

The absorption of SO2 (and traces SO3) is gas-phase controlled. The HTU (Height of a Transfer Unit) for gas-phase controlled absorption is about 0.3m, assuming 1.0 Raschig Rings and proper wetting of the packing material (correct liquid circulation rate and proper liquid distribution over the bed cross-sectional area). The required bed height can be calculated from the simple absorption equation. [Pg.176]

Fluid phase equilibria and mixing properties are of primary interest for theoretical purposes (mathematical model design, parameter estimatioii, etc.), and for the development of a general proper liquid theory. In chemical irrdrrstiial processes irrvolving liquid mixtures, the optimization and adequate design of separation... [Pg.165]


See other pages where Proper liquids is mentioned: [Pg.92]    [Pg.86]    [Pg.147]    [Pg.488]    [Pg.433]    [Pg.1348]    [Pg.331]    [Pg.2041]    [Pg.2594]    [Pg.106]    [Pg.831]    [Pg.265]    [Pg.2029]    [Pg.2574]    [Pg.223]    [Pg.18]    [Pg.9]    [Pg.173]    [Pg.1276]    [Pg.85]    [Pg.32]    [Pg.433]    [Pg.889]    [Pg.230]    [Pg.241]   


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