Fluid phase equilibria

Selected References for Calculation of Multicomponent Fluid-Phase Equilibria... 

Prausnitz, J. M., "Molecular Thermodynamics of Fluid-Phase Equilibria," Prentice-Hall, Englewood Cliffs, N.J. (1969)... 

PRAUSNITZ J.M. MOLECULAR THERMODYNAMICS OF FLUID PHASE EQUILIBRIA, PRENTICE-HALL. ENGLEWOOD CLIFFS. N.J.I19691. 

Figure A2.5.26. Molar heat capacity C y of a van der Waals fluid as a fimction of temperature from mean-field theory (dotted line) from crossover theory (frill curve). Reproduced from [29] Kostrowicka Wyczalkowska A, Anisimov M A and Sengers J V 1999 Global crossover equation of state of a van der Waals fluid Fluid Phase Equilibria 158-160 532, figure 4, by pennission of Elsevier Science.

Levelt Sengers J M H 1999 Mean-field theories, their weaknesses and strength Fluid Phase Equilibria 158-160 3-17... 

Kostrowicka Wyczalkowska A, Anisimov M A and Sengers J V 1999 Global crossover equation of state of a van der Waals fluid Fluid Phase Equilibria 158-160 523-35... 

Panagiotopoulos A Z 1992 Direot determination of fluid phase equilibria by simulation in the Gibbs ensemble a review Mol. SImul. 9 1 -23... 

Panagiotopoulos A Z 1989 Exaot oaloulations of fluid-phase equilibria by Monte Carlo simulation in a new statistioal ensemble Int. J. Thermophys. 10 447-57... 

K. A. Bartscherer, H. Renon, andM. Minier, Fluid-Phase Equilibria, 107, 93 (1995). 

This information allows prediction of X T.E at 323.15 K and at the higher temperatures, 372.8, 397.7, and 422.6 K, for which measured X T.E values are given by Wilsak, et al. (Fluid Phase Equilibria, 28, pp. 13-37 [1986]). Values of In yX and hence of the Margules parameters at the higher temperatures are given by Eq. (4-325) with Cf = 0. The pure-species vapor pressures in all cases are the measured values reported with the data sets. Res lilts of these calculations are displayed in Table 4-1, where the parentheses enclose values from the gamma/ phi approach as reported in the papers cited. 

A comprehensive treatment of LLE is given by Sorensen, et al. Fluid Phase Equilibria, 2, pp. 297-309 [1979] 3, pp. 47-82 [1979] 4, pp. 151-163 [1980]). Data for LLE are collected in a three-part set compiled by Sorensen and Arlt Liquid-Liquid Equilibrium Data Collection, Chemistry Data Series, vol. V, parts 1-3, DECHEMA, Frankfurt am Main, 1979-1980). 

FIG. 22-20 Six classes of binary liquid-fluid phase diagrams (Frausnitz et at. Molecular Thermodynamics of Fluid-Phase Equilibria, 1986. Reptinted hy peimission ofFrentice-Hall, Inc.). 

Prausnitz, J.M., Lichtenthaler, R.N. and Gomes de Azevedo, E., Molecular Thermodynamics of Fluid-Phase Equilibria. Prentice Hall, Upper Sadie River, NJ, 1999. 

Brignole, E. A., Botdni, S., and Gani, R, (1986). A strategy for the design and selection of solvents for separation processes. Fluid Phase Equilibria, 29, 125-132. 

Odele, O., and Macchietto, S. (1993). Computer aided molecular design A novel method for optimal solvent selection. Fluid Phase Equilibria, 82,47-54. 

THERMODYNAMICS OF FLUID-PHASE EQUILIBRIA AT HIGH PRESSURES... 

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