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Products, permanganate

The most common situation studied is that of a film reacting with some species in solution in the substrate, such as in the case of the hydrolysis of ester monolayers and of the oxidation of an unsaturated long-chain acid by aqueous permanganate. As a result of the reaction, the film species may be altered to the extent that its area per molecule is different or may be fragmented so that the products are soluble. One may thus follow the change in area at constant film pressure or the change in film pressure at constant area (much as with homogeneous gas reactions) in either case concomitant measurements may be made of the surface potential. [Pg.151]

Reactions in which a product remains in the him (as above) are complicated by the fact that the areas of reactant and product are not additive, that is, a nonideal mixed him is formed. Thus Gilby and Alexander [310], in some further studies of the oxidation of unsaturated acids on permanganate substrates, found that mixed hlms of unsaturated acid and dihydroxy acid (the immediate oxidation product) were indeed far from ideal. They were, however, able to ht their data for oleic and erucic acids fairly well by taking into account the separately determined departures from ideality in the mixed hlms. [Pg.155]

Outline how you would determine the concentration of permanganate ions in the product (practical details are not required). [Pg.423]

Out first example is 2-hydroxy-2-methyl-3-octanone. 3-Octanone can be purchased, but it would be difficult to differentiate the two activated methylene groups in alkylation and oxidation reactions. Usual syntheses of acyloins are based upon addition of terminal alkynes to ketones (disconnection 1 see p. 52). For syntheses of unsymmetrical 1,2-difunctional compounds it is often advisable to look also for reactive starting materials, which do already contain the right substitution pattern. In the present case it turns out that 3-hydroxy-3-methyl-2-butanone is an inexpensive commercial product. This molecule dictates disconnection 3. Another practical synthesis starts with acetone cyanohydrin and pentylmagnesium bromide (disconnection 2). Many 1,2-difunctional compounds are accessible via oxidation of C—C multiple bonds. In this case the target molecule may be obtained by simple permanganate oxidation of 2-methyl-2-octene, which may be synthesized by Wittig reaction (disconnection 1). [Pg.201]

A compound was obtained from a natural product and had the molecular formula C14H20O3 It contained three methoxy (—OCH3) groups and a —CH2CH=C(CH3)2 substituent Oxidation with either chromic acid or potassium permanganate gave 2 3 5 trimethoxybenzoic acid What is the structure of the compound" ... [Pg.469]

Secondary alcohols (C q—for surfactant iatermediates are produced by hydrolysis of secondary alkyl borate or boroxiae esters formed when paraffin hydrocarbons are air-oxidized ia the presence of boric acid [10043-35-3] (19,20). Union Carbide Corporation operated a plant ia the United States from 1964 until 1977. A plant built by Nippon Shokubai (Japan Catalytic Chemical) ia 1972 ia Kawasaki, Japan was expanded to 30,000 t/yr capacity ia 1980 (20). The process has been operated iadustriaHy ia the USSR siace 1959 (21). Also, predominantiy primary alcohols are produced ia large volumes ia the USSR by reduction of fatty acids, or their methyl esters, from permanganate-catalyzed air oxidation of paraffin hydrocarbons (22). The paraffin oxidation is carried out ia the temperature range 150—180°C at a paraffin conversion generally below 20% to a mixture of trialkyl borate, (RO)2B, and trialkyl boroxiae, (ROBO). Unconverted paraffin is separated from the product mixture by flash distillation. After hydrolysis of residual borate esters, the boric acid is recovered for recycle and the alcohols are purified by washing and distillation (19,20). [Pg.460]

The fermentation-derived food-grade product is sold in 50, 80, and 88% concentrations the other grades are available in 50 and 88% concentrations. The food-grade product meets the Vood Chemicals Codex III and the pharmaceutical grade meets the FCC and the United States Pharmacopoeia XK specifications (7). Other lactic acid derivatives such as salts and esters are also available in weU-estabhshed product specifications. Standard analytical methods such as titration and Hquid chromatography can be used to determine lactic acid, and other gravimetric and specific tests are used to detect impurities for the product specifications. A standard titration method neutralizes the acid with sodium hydroxide and then back-titrates the acid. An older standard quantitative method for determination of lactic acid was based on oxidation by potassium permanganate to acetaldehyde, which is absorbed in sodium bisulfite and titrated iodometricaHy. [Pg.515]

The potassium permanganate crystals are dried at atmospheric pressure below 150°C, cooled, and packaged. Care is taken to prevent heating the product above 200°C during drying to avoid autocatalytic exothermic decomposition of the product. [Pg.520]

Principal uses of KOH include chemicals, particularly the production of potassium carbonate and potassium permanganate, pesticides (qv), fertilizers (qv), and other agricultural products soaps and detergents scmbbing and cleaning operations, eg, industrial gases dyes and colorants and mbber chemicals (qv) (10,34). [Pg.534]

Various methods can be used to analy2e succinic acid and succinic anhydride, depending on the characteristics of the material. Methods generally used to control specifications of pure products include acidimetric titration for total acidity or purity comparison with Pt—Co standard calibrated solutions for color oxidation with potassium permanganate for unsaturated compounds subtracting from the total acidity the anhydride content measured by titration with morpholine for content of free acid in the anhydride atomic absorption or plasma spectroscopy for metals titration with AgNO or BaCl2 for chlorides and sulfates, respectively and comparison of the color of the sulfide solution of the metals with that of a solution with a known Pb content for heavy metals. [Pg.538]

Oxidation. Benzene can be oxidized to a number of different products. Strong oxidizing agents such as permanganate or dichromate oxidize benzene to carbon dioxide and water under rigorous conditions. Benzene can be selectively oxidized in the vapor phase to maleic anhydride. The reaction occurs in the presence of air with a promoted vanadium pentoxide catalyst (11). Prior to 1986, this process provided most of the world s maleic anhydride [108-31 -6] C4H2O2. Currendy maleic anhydride is manufactured from the air oxidation of / -butane also employing a vanadium pentoxide catalyst. [Pg.39]

Oxidation. Citric acid is easily oxidized by a variety of oxidizing agents such as peroxides, hypochlorite, persulfate, permanganate, periodate, hypobromite, chromate, manganese dioxide, and nitric acid. The products of oxidation are usually acetonedicarboxyhc acid (5), oxaUc acid (6), carbon dioxide, and water, depending on the conditions used (5). [Pg.180]

Production of potassium permanganate in the CIS is beheved to be from potassium manganate. Electrolysis of potassium manganate in a continuous-flow electrolytic cell with turbulent electrolyte flow and continuous crystallization has been reported (72). [Pg.78]

This material is contaminated with -10% of 3-methylcyclohexenone. Material of greater purity can be obtained by extending the time of irradiation, by carrying out an efficient distillation of product, or by decomposing starting material with potassium permanganate prior to distillation. [Pg.120]

The progress of the reaction may be followed by analytical thin-layer chromatography on alumina. The submitters used polygram pre-coated plastic sheets (Alox N/UV254) purchased from Macherey-Nagel, Inc. The plates were developed with 1 1 hexane-ether and stained with basic permanganate. The Rf of the product is 0.56. [Pg.204]


See other pages where Products, permanganate is mentioned: [Pg.355]    [Pg.118]    [Pg.804]    [Pg.67]    [Pg.67]    [Pg.93]    [Pg.204]    [Pg.473]    [Pg.308]    [Pg.278]    [Pg.287]    [Pg.512]    [Pg.141]    [Pg.511]    [Pg.515]    [Pg.518]    [Pg.520]    [Pg.522]    [Pg.522]    [Pg.522]    [Pg.522]    [Pg.522]    [Pg.200]    [Pg.447]    [Pg.338]    [Pg.61]    [Pg.426]    [Pg.62]    [Pg.128]    [Pg.78]    [Pg.250]    [Pg.304]    [Pg.304]    [Pg.749]    [Pg.157]   


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Permanganate reaction products

Potassium permanganate production

Products, permanganate oxidations

Solid permanganate production

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