Pressure Swing Adsorption PSA

Relatively new methods for separating helium from natural gas use pressure swing adsorption (PSA) processes to recover helium at better than 99.99% purity. This type of process is probably less costiy for the production of gaseous helium but might be uneconomical for liquefied helium production. The PSA process is widely used to produce specification pure helium from 85+% cmde helium in conjunction with cryogenic enrichment of the ca 50% helium raffinate. 

As an alternative to scmbbing out the CO2 followed by methanation, the shifted gas can be purified by pressure-swing adsorption (PSA) when high purity hydrogen is desirable. 

Fig. 2. Hydrogen production flow sheet showing steam reforming, shift, and pressure swing adsorption (PSA). BFW = boiling feed water.

The impurities usually found in raw hydrogen are CO2, CO, N2, H2O, CH, and higher hydrocarbons. Removal of these impurities by shift catalysis, H2S and CO2 removal, and the pressure-swing adsorption (PSA) process have been described (vide supra). Traces of oxygen in electrolytic hydrogen are usually removed on a palladium or platinum catalyst at room temperature. 

Pressure Swing Adsorption. A number of processes based on Pressure Swing Adsorption (PSA) technology have been used in the production of carbon dioxide. In one version of the PSA process, CO2 is separated from CH using a multibed adsorption process (41). In this process both CH4 and CO2 are produced. The process requires the use of five adsorber vessels. Processes of this type can be used for producing CO2 from natural gas weUs, landfiU gas, or from oil weUs undergoing CO2 flooding for enhanced oil recovery (see Adsorption, gas separation). 

Adsorption Processes. More recendy, pressure swing adsorption (PSA) processes utilizing a high selectivity copper adsorbent have been utilized to effectively separate carbon monoxide from blast furnace gas and coke oven gas (97—101). 

The sulphur-free syngas has a high C02 concentration and an elevated pressure (2-7 MPa), thus making physical absorption highly recommended for C02 separation, although adsorption process such as pressure swing adsorption (PSA) is also utilised. 

A pressure-swing adsorption (PSA) process cycle is one in which desorption takes place at a pressure much lower than adsorption. Reduction of pressure is used to shift the adsorption equilibrium and affect regeneration of the adsorbent. Figure 16-39 depicts a simplified pressure-swing cycle. Feed fluid containing an adsorbate at a molar concentration of y i = pi /Pi is passed through an adsorbent at conditions... 

In most hydrogen plants, a pressure-swing adsorption (PSA) system is used for hydrogen purification. In these plants, a major portion of reformer fuel is PSA offgas with a hydrocarbon stream for makeup fuel. 

Besides absorption processes, adsorption processes, cryogenic separation or membrane separation can be applied. Adsorption processes are based on the physical attachment and bonding of components from the gas mixture on the surface of solid sorbents. As with absorption a distinction can be made between physical and chemical adsorption the first one is referred to as pressure-swing adsorption (PSA), where... 

The pressure at the outlet of the pressure-swing adsorption (PSA) plant is 1.5 MPa. The specific electricity requirement for the compression from 1.5 to 88 MPa at the compressed gaseous hydrogen (CGH2) filling station (required for 70 MPa on-board vehicle storage) amounts to about 0.077 MJei/MJ of CGH2. 

The age of pressure swing adsorption (PSA) began so far as air separation is concerned in the late 1950s. The first process patent was that of Skarstrom [12]. The scientists and engineers of the Linde Laboratories were very active in this field. It is worth mentioning that the discovery of synthetic zeolite molecular sieves was... 

Processes involving total-pressure reduction to remove the adsorbed species, called pressure-swing adsorption (PSA) or heatless adsorption, are mechanically complex, since they must include separate adsorption, depressurization, desorption, and repressurization steps. To accommodate a steady flow of feed and products, several beds - usually three or more in parallel -are used. A typical four-bed process flowsheet is shown in... 

Pressure swing adsorption (PSA) processes are widely applied industrially for gas separations. Applications are numerous and include hydrogen and helium recovery and purification, air drying, the production of oxygen from air, and the separation of normal paraffins from isoparaffins. 

The gas is then cooled to 30-50 °C and the carbon dioxide is removed by amine absorption or other processes. The remaining impurities - carbon monoxide, methane, nitrogen, argon - are removed in a final pressure-swing adsorption (PSA) step to yield >99.5% pure hydrogen. One of the main problems with this process is that the carbon dioxide is removed by the amine unit as a low-pressure gas. This gas must be compressed to 80 bar to be pipelined for sequestration. This compression step alone requires massive compressors and uses 4—5% of the total power output of the plant. The amine treatment step itself uses even more energy, so the total energy consumption is 15% of the power produced by the plant. 

After shift conversion, the gas is cooled by direct contact with circulating process condensate and then fed to a pressure swing adsorption (PSA) unit to remove excess nitrogen, CO2 and inerts. The C02 can be recovered from the pressure swing adsorption waste gas by using an aqueous solution of tertiary... 

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