Pressure adsorption

In these processes, a carbon monoxide containing gas is fed to an adsorber bed containing copper, typically dispersed on a high surface area support such as alumina or carbon. The copper is present predominately as Cu", which selectively adsorbs carbon monoxide. The remainder of the gas stream passes through the adsorbent bed. The carbon monoxide is then removed from the adsorbent by lowering the pressure. Figure 6 shows a typical process for a CO-PSA process. Process conditions are typically adsorption pressures of 0.68—204 MPa (6.8—20.4 atm) and temperatures of 313—373 K. Regeneration occurs at reduced pressure or by vacuum. 

MOF name Type of functional C02 uptake Enthalpy of adsorption Pressure Temperature Surface area Ret. 

The feed gas is introduced at the high adsorption pressure in the adsorption step, impurities are adsorbed on the internal surfaces of the adsorbent leaving high-purity hydrogen product gas in the void spaces of the vessel, and high-purity hydrogen is withdrawn continuously as product from the top of the vessel under pressure. The gas flow is normally... 

The actual adsorption of vapor molecules takes place mainly on the surface of internal passages within the adsorbent particles, since that is where most of the available surface exists. The adsorption process may be either physical or chemical in nature. Physical adsorption is a readily reversible process that occurs as a result of the physical attraction between the gas molecules and the molecules of the solid surface. If the gas-solid intermolecular attraction is greater than the intermolecular attractions in the gas phase, the gas will condense on the solid surface, even though its pressure is lower than its vapor pressure at the prevailing temperature. For example, the equilibrium adsorption pressure of acetone on activated carbon may, under some conditions, be as little as 150 to 1,100 of the equilibrium vapor pressure at... 

Desorption Displacement desorption Gas separation adsorption Liquid separation adsorption Pressure swing adsorption Thermal swing adsorption asbestos fibers, 3 304 for bioremediation, 3 782 capillary condensation, 1 585, 591 dessicants and, 3 375-377 detergency and, 3 428 129 in dispersions, 3 707 filler measurement via, 22 571 general separation heuristics for,... 

The earlier PSA units typically utilized 2,3, or 4 adsorber beds in a cyclic sequence in which one of the beds was always on an adsorption step while the other bed or beds were being regenerated. However, these systems were inherently inefficient for two reasons. First, the blowdown from adsorption pressure to the low waste pressure caused large losses of the desired product gas which was stored in the bed at high pressure. Second, some pure product gas was cycled to waste since it was used to purge a regenerating bed. 

In order to determine the PSD of the micropores, Horvath-Kawazoe (H-K) method has been generally used. In 1983, Horvath and Kawazoe" developed a model for calculating the effective PSD of slit-shaped pores in molecular-sieve carbon from the adsorption isotherms. It is assumed that the micropores are either full or empty according to whether the adsorption pressure of the gas is greater or less than the characteristic value for particular micropore size. In H-K model, it is also assumed that the adsorbed phase thermodynamically behaves as a two-dimensional ideal gas. 

Pressurization Adsorption Pressure Blowdown Desorption Pressure... 

The specific surface excess amount is what is typically measured in practical adsorption studies (see Section 6.4). This parameter is almost equal to the amount adsorbed, a, and is dependent on the equilibrium adsorption pressure, P, at constant adsorbent temperature, T. Accordingly, gas adsorption data is, in practice, expressed by the adsorption isotherm ... 

P0 is the vapor pressure of the adsorptive at the temperature, T, of the adsorption experiment P is the equilibrium adsorption pressure P is a parameter called the characteristic energy of adsorption... 

Several methods are used to calculate the amount of adsorbate corresponding to monolayer coverage. Extrapolation of the nearly linear high pressure portion of the adsorption isotherm back to zero pressure, and calculation of the amount of gas adsorbed at zero pressure is the most usual procedure. One reason for chosing this method is that it minimizes errors due to weak adsorption on the support since at low pressures this is directly proportional to the adsorption pressure. An alternative means of determining the monolayer coverage is to measure the quantity of gas adsorbed at a fixed reference pressure (e.g., about 25 kPa). 

Figure 9 presents the effluent concentrations of the separator. Due to the pressure resistance of the separator only adsorption pressures up to 120 bar can be realised. So an isobaric regeneration of the carbon dioxide was not possible. Results for 110 bar and 70 °C... 

He) was introduced into the column, and the column pressure reached the adsorption pressure Pa. This process took about 5 seconds. Valve V-2 was then opened, and adsorption in the column from the inlet gas took place (adsorption step). During this period, the flow rate and concentration of CO, Gu and C/ were measured. (2) Valves V-1 and V-2 were closed, V-4 was opened, and the column was evacuated (desorption step). At the end of the desorption step, the pressure was below 13 Pa after 600 seconds. (3) As V-3 was also opened under evacuation, helium was supplied as a countercurrent puige to remove CO thoroughly (countercurrent purge step). (4) With V-3 closed and V-4 still open, the column was re-pressurized to the adsorption pressure with helium. The measurement conditions are summarized in Table 1, and the samples that were screened are listed in Table 2. The adsorption temperature was one parameter examined in this study, and a sequence controller was programmed for each set of conditions, so that steps (1) ( 4) were repeated over more than 4 hours. The total amount of desorbed gas was determined from the gas collected at the exit of the rotary flowm er. 

The breakthrough experiments were performed through the adsorption pressure of 5 to 9 atm, and feed flow rate of 4.5 to 9.1 LSTP/min. And the desorption experiments were performed through 2 to 4 LSTP/min at constant pressure of 1.5 atm. 

Adsorption pressure in the first step / Pa Desorption temperature / K ... 

Figure 3 AES of Si-oxide thin film as a function of O2 adsorption pressure (A) no background O2, (B) 1 x 10 Torr, and (C) 4x 10 Torr. (From Ref. 66.)...

Prox. See oxidation, preferential PSA. See adsorption, pressure swing PSU-SARS. See adsorption, selective sulfur purging, 415, 419, 421, 424 pyrolysis, 15, 106, 156... 

SERP. See adsorption, pressure swing SE-SMR. See sorption-enhanced steam methane reforming process Shanxi New Style Fuel and Stove Company, 520... 

TPD experiments were performed using an NEVA NAG 110 mass spectrometer with a glass-made vacuum system. Prior to every TPD measurement the sample was heated up at 1173K for Ih under vacuum (10 torr) to remove the adsorbed impurities. The typical water vapor adsorption pressure was around 20 torr and the heating rate was 10 l min. The temperature programmer used in our experiments was Chino, model KP. 

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