Precipitation particle size distribution

Small solid particles, present in dust and grit emissions, have very low settling velocities (Table 4.4) The collection efficiencies of simple cyclones are tlierefore, as shown in Figure 17.3, relatively low. Fabric filters, electrostatic precipitators or wet scrubbers may be required to remove particles <5 pm in size with an acceptable efficiency. Therefore the cost of pollution control inevitably increases when dealing with particle size distributions skewed towards the lower end. 

Figure 6.12 Particle size distributions for agglomerative precipitation, (a) Theory according to equation 4.25, (h) Experimental results CaC03, o BaS04 Hostom.sky and Jones, 1993a,h)...

Figure 8.21 Particle size distribution of precipitated calcium carbonate (Wachi and Jones, 1991b)...

The significance of this novel attempt lies in the inclusion of both the additional particle co-ordinate and in a mechanism of particle disruption by primary particle attrition in the population balance. This formulation permits prediction of secondary particle characteristics, e.g. specific surface area expressed as surface area per unit volume or mass of crystal solid (i.e. m /m or m /kg). It can also account for the formation of bimodal particle size distributions, as are observed in many precipitation processes, for which special forms of size-dependent aggregation kernels have been proposed previously. 

Figure 8.24 Predicted transient particle size distribution during the hatch precipitation of calcium carbonate crystals (Wachi and Jones, 1992)...

Chen, J., Zheng, C. and Chen, G., 1996. Interaction of macro- and micromixing on particle size distribution in reactive precipitation. Chemical Engineering Science, 51, 1957-1966. 

Manuo, L., Manna, L., Chiampo, F., Sicardi, S. and Bersano, G., 1996. Influence of mixing on the particle size distribution of an organic precipitate. Journal of Crystal Growth, 166, 1027-1034. 

Petanate, A.M. and Glatz, C.E., 1983. Isoelectric precipitation of soy protein. I. Factors affecting particle size distributions. II. Kinetics of protein aggregate growth and breakage. Biotechnology and Bioengineering, 25, 3049. 

Tosuii, G., 1988. All experimental study of the effect of mixing on the particle size distribution in BaS04 precipitation reaction. 6th European Conference on Mixing, Pavia, pp. 161-170. 

Wachi, S. and Jones, A.G., 1992. Dynamic modelling of particle size distribution and degree of agglomeration during precipitation. Chemical Engineering Science, 47, 3145-3148. 

Brown et al. [494] developed a method for the production of hydrated niobium or tantalum pentoxide from fluoride-containing solutions. The essence of the method is that the fluorotantalic or oxyfluoroniobic acid solution is mixed in stages with aqueous ammonia at controlled pH, temperature, and precipitation time. The above conditions enable to produce tantalum or niobium hydroxides with a narrow particle size distribution. The precipitated hydroxides are calcinated at temperatures above 790°C, yielding tantalum oxide powder that is characterized by a pack density of approximately 3 g/cm3. Niobium oxide is obtained by thermal treatment of niobium hydroxide at temperatures above 650°C. The product obtained has a pack density of approximately 1.8 g/cm3. The specific surface area of tantalum oxide and niobium oxide is nominally about 3 or 2 m2/g, respectively. 

While the model was in general agreement with the limited experimental data published on bulk PVC particle size distribution, there is still no generally applicable theory describing particle growth and flocculation in the presences of mechanical agitation for precipitation polymerizations. 

The separation of solids from liquids forms an important part of almost all front-end and back-end operations in hydrometallurgy. This is due to several reasons, including removal of the gangue or unleached fraction from the leached liquor the need for clarified liquors for ion exchange, solvent extraction, precipitation or other appropriate processing and the post-precipitation or post-crystallization recovery of valuable solids. Solid-liquid separation is influenced by many factors such as the concentration of the suspended solids the particle size distribution the composition the strength and clarity of the leach liquor and the methods of precipitation used. Some important points of the common methods of solid-liquid separation have been dealt with in Chapter 2. 

In 1994, we reported the dispersion polymerization of MM A in supercritical C02 [103]. This work represents the first successful dispersion polymerization of a lipophilic monomer in a supercritical fluid continuous phase. In these experiments, we took advantage of the amphiphilic nature of the homopolymer PFOA to effect the polymerization of MMA to high conversions (>90%) and high degrees of polymerization (> 3000) in supercritical C02. These polymerizations were conducted in C02 at 65 °C and 207 bar, and AIBN or a fluorinated derivative of AIBN were employed as the initiators. The results from the AIBN initiated polymerizations are shown in Table 3. The spherical polymer particles which resulted from these dispersion polymerizations were isolated by simply venting the C02 from the reaction mixture. Scanning electron microscopy showed that the product consisted of spheres in the pm size range with a narrow particle size distribution (see Fig. 7). In contrast, reactions which were performed in the absence of PFOA resulted in relatively low conversion and molar masses. Moreover, the polymer which resulted from these precipitation... 

The counterparts of dissolving particles are the processes of precipitation and crystallization the description and simulation of which involve several additional aspects however. First of all, the interest in commercial operations often relates to the average particle size and the particle size distribution at the completion of the (batch) operation. In precipitation reactors, particle sizes strongly depend on the (variations in the) local concentrations of the reactants, this dependence being quite complicated because of the nonlinear interactions of fluctuations in velocities, reactant concentrations, and temperature. 

A major obstacle in making precise structures with metal colloids has been the control of aggregation and particle size distribution. The use of micelles has allotted some success in this regard with the formation of different metal colloid geometries [30]. It is known that the nanoparticles must be stabilized by organic molecules attached to their surface [31] and in general must be embedded in a solid matrix [32], This is done to prevent agglomeration and precipitation as... 

Structured products, such as cosmetics, detergents, surfactant foams, inks, paints, drugs, foods and agrochemicals, combine several functions and properties in a single product. Design of these structured products involve the creation and the control of the particle size distribution in operations such as crystallization, precipitation, generation of aerosols, and nanoparticles as well as... 

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