Sediment porosity

For the calculation of the fluxes the following parameters are needed porosity, sedimentation rate, diffusion coefficients, distribution constants, and the concentration gradients for each species dCildz)z=o- In assessing diffusion coefficients, coupling-effects due to electroneutrality between coions and counterions may have to be considered. Serious errors may be introduced by using wrong values of dQldz, because it is very difficult to collect undisturbed sediment. 

Hamilton, E.L. 1956. Low sound velocities in high porosity sediments. Journal (f the Acoustical Society... 

Compaction occurs when continuous sedimentation results in an increase of overburden which expels pore water from a sediment package. Pore space will be reduced and the grains will become packed more tightly together. Compaction is particularly severe in clays which have an extremely high porosity of some 80% when freshly deposited. 

Stratigraphic traps are formed by depositional and sedimentary factors. In such traps the depositional process and the follow-on cementing process, which changes the sediment bed into a rock, create porosity and permeability alterations in geometric forms that provide traps. 

Sedimentary deposits are usually carried to the region of deposition by water and are deposited in water. (In some cases deposits are carried by wind or ice.) It is within these water leposited sediments that hydrocarbons are likely generated from the plant and animal life that exists in these environments. Two principal properties of the sedimentary rocks that form from such deposits are porosity and permeability. 

Primary porosity—porosily formed at the time the sediment was deposited. Sedimentary rocks that typically exhibit primary porosity are the clastic (also called fragmental or detrital) rocks, which are composed of erosional fragments from older beds. These particles are classified by grain size. 

Secondary porosity— o ds formed after the sediment was deposited. The magnitude, shape, size, and interconnection of the voids bears little or no relation to the form of the original sedimentary particles. Secondary porosity is subdivided into three classes. 

The presence of particles in the fluid medium complicates diffusion in a sediment due to the effects of porosity, represented by n, and tortuosity. Since tortuosity of natural sediments is seldom known it is more convenient to use the term "formation factor" or "lithological factor," denoted L, which takes into account everything but porosity. Tick s diffusion constant D is replaced by the whole sediment diffusion constant Ds, where < D. 

For the upper part of the sediment, where the sea-sediment interaction is most predominant, steady-state compaction is a reasonable assumption, as porosity and compaction undergo a linear change during burial. 

Filter. A filter is used in some cases when coagulation and sedimentation do not completely separate the solids from the liquid waste in areas where sand and sandstone formations are susceptible to plugging. Filters with a series of metal screens coated with diatomaceous earth or cartridge filters are typically used.27 Where limestone formations with high solution porosity are used for injection, filtration is usually not required. 

Winters and Lee134 describe a physically based model for adsorption kinetics for hydrophobic organic chemicals to and from suspended sediment and soil particles. The model requires determination of a single effective dififusivity parameter, which is predictable from compound solution diffusivity, the octanol-water partition coefficient, and the adsorbent organic content, density, and porosity. 

In order to increase the flow rate without too much pressure, Experiment 4 was performed with a Fann filter press which has a wider cross sectional area. A constant air pressure of 100 psi was applied, the flow rate was 26 times that of Experiment 1 while the NaCl concentration was only slightly higher than that of Experiment 1. Although the flow rate was much increased in Experiment 4, the result was similar to Experiment 1. The water retained in the clay (Column 8) determined by drying was found to be close to the amount of anion-free water. The porosity of the sediment was 0.4 and the average pore diameter was 4466 X. It was concluded from this experiment, that the anion-free water was immobile even at 100 psi and 7.4 ft/day. The pore size distributionQof the sample showed 90% of the pores to have a diameter above 350 A and less than 3% of the pores to have a diameter below 100 X (Figure 4). 

A global sensitivity analysis was performed for the lead concentration in the arterial blood model (Fig. 7) over the simulation period for each parameter. Parameters considered for the sensitivity analysis are listed in Table 8 (Annex 1). The magnitude of sensitivity is shown by relative sensitivity index. It was observed that the most influential parameter is the porosity of the sediment of the river (phi sed)... 

To prepare for our calculation, we save these reactions and exchange coefficients in a dataset CaMgNaJx.dat . We take the sediment s cation exchange capacity to be 4 meq (100 g) 1, or 4 x 10-5 eq g 1. We further assume a porosity of 30%, so that per kg of pore fluid, there is about 2300 cm3 of sediment. 

The geology not only provides the chemical source for trace-element mobility but it also provides the physical framework for water-flow paths. The structural properties of the rocks, the porosity, permeable fractures, provide for water-mineral reaction and element mobility. The geomorphology contributes to water-table levels, aquifer permeability, surface-water travel times, and time periods for erosion and sediment transport. Examples of... 

Preferred fluid migration pathways are influenced by porosity and permeability, sedimentary sequences, facies architecture, and fractures. Porosity is a measure of pore space per unit volume of rock or sediment and can be divided into two types absolute porosity and effective porosity. Absolute porosity (n) is the total void space per unit volume and is defined as the percentage of the bulk volume that is not solid material. The equation for basic porosity is listed below ... 

Effective porosity (Ne) is of more importance and, along with permeabihty (the ability of a material to transmit fluids), determines the overall ability of the material to store and transmit fluids or vapors readily. Where porosity is a basic feature of sediments, permeability is dependent upon the effective porosity, the shape and size of the pores, pore interconnectiveness (throats), and properties of the fluid or vapor. Fluid properties include capillary force, viscosity, and pressure gradient. 

Porosity can be primary or secondary. Primary porosity develops as the sediment is deposited and includes inter- and intraparticle porosity (Figure 3.1). Secondary porosity develops after deposition or rock formation and is referred to as diagenesis (Figure 3.2). 

The final consolidation of the sediment is the slowest part of the process because the displaced fluid has to flow through the small spaces between the particles. As consolidation occurs, the rate falls off because the resistance to the flow of liquid progressively increases. The porosity of the sediment is smallest at the bottom because the compressive force due to the weight of particles is greatest and because the lower portion was formed at an earlier stage in the sedimentation process. The rate of sedimentation during this period is... 

It is important to differentiate between two terms that are widely used in the literature, namely chemical kinetics and kinetics . Chemical kinetics is defined as the investigation of chemical reaction rates and the molecular processes by which reactions occur where transport (e.g., in the solution phase, film diffusion, and particle diffusion) is not limiting. On the other hand, kinetics is the study of time-dependent processes. Because of the different particle sizes and porosities of soils and sediments, as well as the problem to reduce transport processes in these solid phase components, it is difficult to examine the chemical kinetics processes. Thus, when dealing with solid phase components, usually the kinetics of these reactions are studied. 

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