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Pores forced flow through

Effect of Pressure Drop in Reactor Forced Flow Through Catalyst Pores)... [Pg.292]

We note that under Knudsen flow conditions (small pores, moderate pressures) the forced flow through pores due to reactor pressure drop cannot ever be important. This is because the available Knudsen diffusion gradient due to reaction is of the order of 1000 times larger than the very small concentration gradient caused by reactor pressure drop, and the Knudsen diffusion coefficient is identical with the Knudsen forced flow coefficient. [Pg.294]

In low RH conditions, the cathode MPL can force flow through the membrane into the anode by capillary pressure forces, reducing dryout and increasing performance. The backflow of water would occur primarily through the hydrophilic pore network in the catalyst layer, since complete pore saturation in the catalyst layer would result in nearly total performance loss, and high saturation in the hydrophobic pores of the CL would likely... [Pg.322]

Intraparticle convection can also occur in packed beds when the adsorbent particles have very large and well-connected pores. Although, in general, bulk flow through the pores of the adsorbent particles is only a small frac tion of the total flow, intraparticle convection can affec t the transport of veiy slowly diffusing species such as macromolecules. The driving force for convec tion, in this case, is the... [Pg.1510]

The mechanism of separation is the same for Zorbax PSM columns as it is for other types of SEC columns. As the mobile phase flows through the column, large molecules are forced down the column at faster rates than small molecules because the large molecules have less access to the column volume inside the pores. Consequently, molecules that are too large to permeate any of the pore... [Pg.77]

The small particles are reported to be very harmful for human health [98]. To remove particulate emissions from diesel engines, diesel particulate filters (DPF) are used. Filter systems can be metallic and ceramic with a large number of parallel channels. In applications to passenger cars, only ceramic filters are used. The channels in the filter are alternatively open and closed. Consequently, the exhaust gas is forced to flow through the porous walls of the honeycomb structure. The solid particles are deposited in the pores. Depending on the porosity of the filter material, these filters can attain filtration efficiencies up to 97%. The soot deposits in the particulate filter induce a steady rise in flow resistance. For this reason, the particulate filter must be regenerated at certain intervals, which can be achieved in the passive or active process [46]. [Pg.155]

Flow properties of macroemulsions are different from those of non-emulsified phases 19,44). When water droplets are dispersed in a non-wetting oil phase, the relative permeability of the formation to the non-wetting phase decreases. Viscous energy must be expended to deform the emulsified water droplets so that they will pass through pore throats. If viscous forces are insufficient to overcome the capillary forces which hold the water droplet within the pore body, flow channels will become blocked with persistent, non-draining water droplets. As a result, the flow of oil to the wellbore will also be blocked. [Pg.584]

By definition, the anion-free water is free of salt. When pressure is applied to a clay-brine slurry to force out water (as that described in the experimental section), the solution that flows out of the cell should maintain the same chloride concentration as the brine s if the anion-free water is immobile. Otherwise, the concentration of the chloride decreases. Pressure forces water to flow through the pores with a certain velocity meanwhile, the pore size... [Pg.600]

Water flow through unsaturated soil is controlled by the same forces as capillary action and water retention (i.e., adhesion, gravity, and surface tension). Flow can occur only when the water phase is continuous from pore to pore. If gravity is the controlling force, downward flow will occur according to Darcy s law in direct proportion to the percentage of water-filled, connected pores. For example, if only half the pores in a cross section are water filled, the flow through that section will be half of that predicted by Q- K1A. [Pg.83]

This method in principle can also be used to estimate the average pore size of the membrane when there are no defects in the membrane. First, gas flows through the membrane in the dry state. Typically, the gas flow rate is a linear function of the applied pressure difference. Then the membrane is saturated with the test liquid and the gas is forced to flow through the wet... [Pg.81]

Gibbs adsorption equation is an expression of the natural phenomenon that surface forces can give rise to concentration gradients at Interfaces. Such concentration gradient at a membrane-solution Interface constitutes preferential sorption of one of the constituents of the solution at the interface. By letting the preferentially sorbed Interfacial fluid under the Influence of surface forces, flow out under pressure through suitably created pores in an appropriate membrane material, a new and versatile physicochemical separation process unfolds itself. That was how "reverse osmosis" was conceived in 1956. [Pg.57]

Further, it is known that real-world capillaries or pores are not always circular shaped. In fact, in oil reservoirs, the pores are more triangular shaped or square shaped than circular. In this case, the rise in capillaries of other shapes, such as rectangular or triangular (Birdi et al 1988 Birdi, 1997, 2002) can be measured. These studies have much significance in oil recovery or water treatment systems. In any system in which the fluid flows through porous material, it would be expected that capillary forces would be one of the most dominant factors. [Pg.20]

In many processes (such as oil recovery, blood flow, underground water), one encounters liquid flow through thin (micrometer diameter), noncircular-shaped tubes, or pores. In the literature, one finds studies that address these latter systems. In another context of liquid drop formation, for example, in an inkjet nozzle, this technique falls under a class of scientifically challenging technology. The inkjet printer demands such quality that this branch of drop-on-demand technology is much in the realm of industrial research. All combustion engines are controlled by oil drop formation and evaporation characteristics. The important role of capillary forces is obvious in such systems. [Pg.23]


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See also in sourсe #XX -- [ Pg.267 , Pg.268 , Pg.269 , Pg.272 , Pg.273 , Pg.274 , Pg.279 , Pg.289 , Pg.292 , Pg.293 ]




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