Polymer coatings adhesion

Uses. Intermediate in production of polymers, coatings, adhesives, textiles, and paper finishes... 

Much attention has been paid to the synthesis of fluorine-containing condensation polymers because of their unique properties (43) and different classes of polymers including polyethers, polyesters, polycarbonates, polyamides, polyurethanes, polyimides, polybenzimidazoles, and epoxy prepolymers containing pendent or backbone-incorporated bis-trifluoromethyl groups have been developed. These polymers exhibit promise as film formers, gas separation membranes, seals, soluble polymers, coatings, adhesives, and in other high temperature applications (103,104). Such polymers show increased solubility, glass-transition temperature, flame resistance, thermal stability, oxidation and environmental stability, decreased color, crystallinity, dielectric constant, and water absorption. 

A series of four chapters emphasize the past, present and future aspects of natural oils. Polymerized vernonia, linseed and tung oils are described as replacements for synthetic polymers. Coatings, adhesive and bulk applications are discussed. 

To an experienced operator trained in the handling of industrial chemicals, the dimers present Httle cause for concern in handling or storage. The finished polymer coating presents even less of a health problem contact with the reactive monomer is unlikely. In the ancillary operations, such as cleaning or adhesion promotion, the operator must observe suitable precautions. Before using the process chemicals, operators must read and understand the current Material Safety Data Sheets, which are available from the manufacturers. 

Aromatic Isocyanates. In North America, aromatic isocyanates ate heavily used as monomers for addition and condensation polymers. The principal appflcafions include both flexible and rigid polyurethane foam and nonceUulat appflcations, such as coatings, adhesives, elastomers, and fibers. 

Suspension Polymerization. At very low levels of stabilizer, eg, 0.1 wt %, the polymer does not form a creamy dispersion that stays indefinitely suspended in the aqueous phase but forms small beads that setde and may be easily separated by filtration (qv) (69). This suspension or pearl polymerization process has been used to prepare polymers for adhesive and coating appHcations and for conversion to poly(vinyl alcohol). Products in bead form are available from several commercial suppHers of PVAc resins. Suspension polymerizations are carried out with monomer-soluble initiators predominantly, with low levels of stabilizers. Suspension copolymerization processes for the production of vinyl acetate—ethylene bead products have been described and the properties of the copolymers determined (70). Continuous tubular polymerization of vinyl acetate in suspension (71,72) yields stable dispersions of beads with narrow particle size distributions at high yields. 

Trichloroethane and other chlorinated solvents are used for vapor degreasing (84—90). Other uses include cold metal cleaning, printed ckcuit board cleaning, and as a solvent for inks, coatings, adhesives, and aerosols. 1,1,1-Trichloroethane is an excellent solvent for development of photoresist polymers used in printed ckcuit board manufacture (see Integrated circuits Photoconductivepolymers). 

High adhesion and sensitivity to UV irradiation of these polymer coatings allow one to use them as a base for the preparation of polymer resistance of a negative type. 

Adhesion of polymer coatings (thickness 60-70 fik) formed on the glass surface is obtained by lattice notch" method. 

Manuelli, A. Knobloch, A. Bernds, A. Clemens, W. 2002. Applicability of coating techniques for the production of organic field effect transistors. 2nd International IEEE Conference on Polymers and Adhesives in Microelectronics and Photonics, POLYTRONIC 2002. pp. 201-204. 

Classifying polymers in their crosslinked state according to end-use properties, polymer networks include vulcanized rubbers, crosslinked thermosetting materials, protective coatings, adhesives, polymeric sorbents, microelectronics materials, soft gels, etc. Polymer networks in contrast to uncrosslinked polymers,... 

Uses Manufacture of triethylenemelamine and other amines fuel oil and lubricant refining ion exchange protective coatings adhesives pharmaceuticals polymer stabilizers surfactants. 

The extent of coating adhesion failure was found to be dependent upon the resistance of the polymer in the coating to hydrolysis by corrosion generated hydroxide. In this study, similar trends have been observed for adhesives. Table I shows the results of salt spray corrosion on a series of bonds between cold rolled steel adherends and adhesives of varying chemistry. The results show that there is a direct correlation between the chemistry of the adhesive polymer and the durability of the series of adhesive bonds studied. The locus of adhesion failure also appears to be related to the type of adhesive chemistry. In this study, adhesives based on polymers having a wide range of hydrolysis resistance were examined. 

Polymers are very important chemicals derived from the top 50, and they play important roles in our everyday lives, giving us products made of plastics, fibers, elastomers, paints, coatings, adhesives, and many other materials. Representative top-selling commercial polymers are given in Table 1.16. These materials and products will be discussed in detail in Chapters 14-19. 

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