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Poly applications with

The important features of rigidity and transparency make the material competitive with polystyrene, cellulose acetate and poly(methyl methacrylate) for a number of applications. In general the copolymer is cheaper than poly(methyl methacrylate) and cellulose acetate, tougher than poly(methyl methacrylate) and polystyrene and superior in chemical and most physical properties to polystyrene and cellulose acetate. It does not have such a high transparency or such food weathering properties as poly(methyl methacrylate). As a result of these considerations the styrene-acrylonitrile copolymers have found applications for dials, knobs and covers for domestic appliances, electrical equipment and car equipment, for picnic ware and housewares, and a number of other industrial and domestic applications with requirements somewhat more stringent than can be met by polystyrene. [Pg.441]

Bao, Z. Dodabalapur, A. Lovinger, A. 1996. Soluble and processable regioregular poly (3-hexylthiophene) for thin film field-effect transistor applications with high mobility. Appl. Phys. Lett. 69 4108 1110. [Pg.401]

Conductive polymers have attracted increasing attention because they have wide applications. Recently, very stable poly(thiophenes) with polyfluorinated side chains have been electrochemically synthesized and characterized [81]. Furthermore, notably novel conductive materials have been prepared by cathodic electropolymerization of perfluoro cvclobutene and cyclopentene [82]. [Pg.45]

Poly(alkylene oxide)-based (PEO-PPO-PEO) triblock and diblock copolymers are commercially successful, linear non-ionic surfactants which are manufactured by BASF and ICI. Over the last four decades, these block copolymers have been used as stabilisers, emulsifiers and dispersants in a wide range of applications. With the development of ATRP, it is now possible to synthesise semi-branched analogues of these polymeric surfactants. In this approach, the hydro-phobic PPO block remains linear and the terminal hydroxyl group(s) are esteri-fied using an excess of 2-bromoisobutyryl bromide to produce either a monofunctional or a bifunctional macro-initiator. These macro-initiators are then used to polymerise OEGMA, which acts as the branched analogue of the PEO block (see Figures 2 and 3). [Pg.24]

BAMO is perhaps the most prominent among the azido oxetanes class in terms of the number of polymers and copolymers reported so far. Due to its symmetrical azido groups, it assumes special significance as a hard block repeating unit in a thermoplastic elastomer. However, the homopolymer is solid and cannot be used directly for binder applications because of its crystal-tine nature. Also, poly(BAMO) shows relatively poor mechanical properties as a binder for solid rocket propellants [153]. Many copolymers of BAMO with non-energetic co-monomers tike tetrahydrofuran (THF) have been reported. The BAMO-THF copolymer is an excellent candidate for binder applications with its energetic BAMO content coupled with the THF block which affords... [Pg.263]

Amino acid ester side groups are not the only units that sensitize the system to hydrolysis. The imidazolyl group has an even greater effect.197-198-219 For example, polymer 3.86, prepared by the reaction of poly(dichlorophosphazene) with imidazole, is so unstable hydrolytically that it decomposes in moist air to imidazole, phosphate, and ammonia. This is too high a sensitivity for most biomedical applications. Hence, an emphasis has been placed on the study of polymers such as 3.87 in which a hydrophobic cosubstituent group, such as aryloxy, is present to reduce the rate of erosion. [Pg.128]

With the application of protein microarrays in mind, Spencer and coworkers immobilized poly(lysine) with grafted PEG side chains on various metal or semiconductor oxide surfaces via electrostatic adsorption [200], Part of the PEG side chain was functionalized with biotin at the distal end. Streptavidin was bound to the surface-tethered biotin in a subsequent step, and the remaining unoccupied binding pockets of streptavidin were then used to immobilize biotinylated capture antibodies. As an example of an immunoassay, biotinylated goat anti-rabbit IgG was immobilized, which then specifically bound rabbit IgG. [Pg.28]

Lactic acid, initially produced in 1880, was the first organic acid made industrially by fermentation of a carbohydrate. Nowadays it is made both by fermentation and by chemical synthesis. About 85% of the use of lactic acid is in food and food-related applications, with some use in the making of emulsifying agents and poly(lactic acid). [Pg.8]

The control of the Eu redox stability is certainly a key issue for an eventual MRI contrast agent application. With the exception of cryptate complexes of Eu such as Eu (2.2.2) + and Eu (2.2.1) +, the complexation with poly(amino carboxylates) diminishes the redox stability of the Eu state, as compared to the aqua ion (some representative redox potentials are -0.63 V (Eu(H20) ) -0.21 V (Eu(2.2.2)2+) -0.82 V (EuODDA) -1.00 V (EuTETA -) -1.18 V (EuDO-TA ) -1.35 V (EuDTPA )) [111, 112]. Macrocyclic ligands that match in size with the larger Eu ion have a stabilizing effect of the reduced state, whereas carboxylate coordinating groups seem to be unfavorable in this respect. [Pg.94]

In the present study, we have investigated the synthesis of OVE from CO2 and GVE in view of the characteristics of phase transfer catalysts and reaction mechanism as well as its application with acylonitrile(AN) to the synthesis of corresponding copolymer. We have tested monomer reaetivity ratio and thermal properties of the copolymer. The blends of poly(OVE-co-AN) and SAN were prepared, and the degree of miscibility was examined by... [Pg.403]

Poly(imides) contain the group -C(0)-NH-C(0)- in their structure. Many poly(imides) with practical applications have a more complicated formula and contain oxygen atoms and aromatic rings in the backbone [1]. One example is poly(pyromellitic dianhydride-a/f-4,4 -oxydianiline) or PMDA-ODA, CAS 25038-81-7, which is obtained from pyromellitic anhydride and oxybis(benzenamine) by water elimination as follows ... [Pg.617]


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See also in sourсe #XX -- [ Pg.148 ]




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