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Poisoned growth

The basis of the Cossee-Arlman theory is the concept of a chloride vacancy on the catalyst surface. This idea was first suggested by Boor in a private communication (Arlman, 1964). At the vacancy, monomer is adsorbed on the surface. According to the theory, not all titanium ions are active because most of them are fully coordinated in the octahedral interstices of the crystal. The active sites are found only on certain surfaces of a titanium trichloride crystal where vacancies exist. These arise because in order to have electrical neutrality some titanium ions must be coordinated to fewer than six chloride ions. The above interpretation is consistent with microscopic observations that poisoner growth occurs at boundaries defined by edges or steps of platelets (Hargitay et al., 1959 Rodriguez and Gabant, 1963). [Pg.259]

Figure 2.18 Atomic force microscopy images of an area 3.5 pm x 3.5 pm of poisoned growth of calcite." ... Figure 2.18 Atomic force microscopy images of an area 3.5 pm x 3.5 pm of poisoned growth of calcite." ...
Wrought or extmded lead—teUurium (0.035—0.10 wt %) aUoys produce extremely fine grains. The binary aUoy is, however, susceptible to recrysta11i2ation. The addition of copper or sUver reduces grain growth and retains the fine grain si2e. Because teUurium is a poison for sealed lead—acid batteries, the teUurium content of lead and lead aUoys used for such purposes is usuaUy restricted to less than 1 ppm. [Pg.61]

This can be a dangerous procedure due to the potential growth of food poisoning bacteria such as Staphylococcus aureus (31). This method of inoculation requites a very strict condition to assure the absence of not only bacteria associated with a health hazard but also those associated with product failure (proteolytic, greening, and gas-forming microorganisms). [Pg.33]

Toxicity The relative degree of being poisonous or toxic. A condition which may exist in wastes and will inhibit or destroy the growth or function of certain organisms. [Pg.627]

Biological growth can present a potentially hazardous fouling, since it can provide a stickier surface with which to bond other fouling sources. In many cases, however, treatment of the fluid can reduce the amount of biological growth. The use of germicides or poisons to kill bacteria can help. [Pg.399]

There have been few satisfactory demonstrations that decompositions of hydrides, carbides and nitrides proceed by interface reactions, i.e. either nucleation and growth or contracting volume mechanisms. Kinetic studies have not usually been supplemented by microscopic observations and this approach is not easily applied to carbides, where the product is not volatile. The existence of a sigmoid a—time relation is not, by itself, a proof of the occurrence of a nucleation and growth process since an initial slow, or very slow, process may represent the generation of an active surface, e.g. poison removal, or the production of an equilibrium concentration of adsorbed intermediate. The reactions included below are, therefore, tentative classifications based on kinetic indications of interface-type processes, though in most instances this mechanistic interpretation would benefit from more direct experimental support. [Pg.155]

Zinc and cadmium have an oxidation number of +2 in all their compounds. Zinc is an essential element for human health. It is present in many enzymes and plays a role in the expression of DNA and in growth. Zinc is toxic only in very-high amounts. However, cadmium is a deadly poison that disrupts metabolism by-substituting for other essential metals in the body such as zinc and calcium, leading to soft bones and to kidney and lung disorders. [Pg.787]

Bacteria not only attack teeth but can also make people extremely sick. Therefore, canned food must be specially prepared to prevent the growth of bacteria. This is usually done by boiling or steaming. People who can their own food at home, however, do not have the sophisticated machines that food-canning manufacturers have. Even so, there are other methods that home canners can use to preserve their own food and keep their families safe. For example, high heat can be used to kill the bacteria Clostridium botulinum, which causes one deadly form of food poisoning called botulism. Acidic conditions will also kill C. botulinum. Because the bacteria cannot survive at a pH below 4.5, very acidic foods such as tomatoes, pears, and peaches are safe for home canning. [Pg.93]

At the same time, the public s faith in science and technology was eroding. Radioactive fallout from atomic bomb tests was poisoning cows milk, and the thalidomide antinausea medicine prescribed to pregnant women in Europe had caused severe birth defects in 8000 children. Above all, the enormous growth of the chemical industry and pollution after World War II put public pressure on Congress to clean up the nation s air and water. [Pg.166]


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See also in sourсe #XX -- [ Pg.44 ]




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