Plastics, weatherability

Xenon fluorides, 77 323-325 binary, 77 335-336 Xenon-gold cations, 77 332 Xenon halides, 77 323-325 Xenon hexafluoride, 7 7 325, 329 uses for, 7 7 336 Xenon ion lasers, 74 685 Xenon isotopes, in fission reactors, 77 375 Xenon oxide difiuoride, 77 326 Xenon oxide fluorides, 7 7 326 Xenon oxides, 77 325-326 Xenon oxide tetrafluoride, 77 326 Xenon testing, in plastics weathering, 79 584-585... 

There are other minor nonequivalencies of ISO test procedures compared to ASTM standards, but for color difference the ISO Test Procedure No. 105 is unique. Those who use Colour Measurement Committee (CMC) procedures—particularly CMC 2 1 Lightness to Color ratio—claim that it facilitates a uniform description for acceptability decisions that is better than any other system in existence. These equations permit the use of a single number tolerance, DEcmc, in a nearly uniform color space. The CMC formula is a modification to the perceptibility CIELAB formula. It is fully described elsewhere in this book, but it deserves some brief notice here because, after all, it is an ISO procedure. The CMC developed the basic British Standard No. 6923, Calculation of Small Color Differences. Soon afterward, in 1989, the American Association of Textile Chemists and Colorists (AATCC) adopted AATCC Test Method 173, CMC Calculation of Small Color Differences for Acceptability. Ford Motor Company indicated a preference for using CMC 2 1 ratio color difference for plastics weathering data for plastics interior trim materials. 

A polyethylene plastic weather balloon contains 65 L of helium, which is at 20.0°C and 94.0 kPa. How many moles of helium are in the balloon ... 

Isopropyl lanolate Isocetyl salicylate PPG-2 lanolin alcohol ether PPG-5 lanolin alcohol ether PPG-20 lanolin alcohol ether Propylene glycol myristate plasticizer, weather-stripping Dinonyl phthalate plasticizer, welding rod coatings Algin Alginic acid plasticizer, wire coatings Dioctyl terephthalate plasticizer, wire insulation Trimellitic anhydride plastics... 

Figure 4.3 The influence of various processing methods on plastics weathering resistance Left ABS[583]... 

Outdoor weathering for photodegradable plastics Weathering of transparent plastics... 

M. Tahan, Weathering of Plastics and Rubber, International Symposium of the Institute of Electrical Engineers, Eondon, June 1976, Chamelon Press, Ltd., London, 1976, p. A2.1. 

Polymer compositions containing pentaerythritol are also used as secondary heat-, light-, and weather-resistant stabilizers with calcium, zinc, or barium salts, usually as the stearate, as the prime stabilizer. The polymers may be in plastic or fiber form (87—89). 

FWWMR Finish. The abbreviation for fire, water, weather, and mildew resistance, FWWMR, has been used to describe treatment with a chlorinated organic metal oxide. Plasticizers, coloring pigments, fiUers, stabilizers, or fungicides usuaUy are added. However, hand, drape, flexibUity, and color of the fabric are more affected by this type of finish than by other flame retardants. Add-ons of up to 60% are required in many cases to obtain... 

Uses. Neopentyl glycol is used extensively as a chemical intermediate in the manufacture of polyester resins (see Alkyd resins), polyurethane polyols (see Urethane polymers), synthetic lubricants, polymeric plasticizers (qv), and other polymers. It imparts a combination of desirable properties to properly formulated esterification products, including low color, good weathering and chemical resistance, and improved thermal and hydrolytic stabiUty. 

The above-mentioned codes contain requirements for accelerated durabiUty tests. In addition, interlayer manufacturers and laminators expose test samples for several years under extreme weather conditions, eg, the Florida coast and Arizona desert. The laminated products weather extremely well, with no change in the plastic interlayer. Occasionally, clouding is noted around the edges when exposed to high humidity for long periods, but this is reversible. Colored areas of PVB laminates may fade while subjected to extensive uv/solar irradiation, which could cause an appearance issue. This has not, however, been shown to alter the laminate s other performance properties. 

Electrical Properties. Poly(methyl methacrylate) has specific electrical properties that make it unique (Table 4). The surface resistivity of poly(methyl methacrylate) is higher than that of most plastic materials. Weathering and moisture affect poly(methyl methacrylate) only to a minor degree. High resistance and nontracking characteristics have resulted in its use in high voltage appHcations, and its excellent weather resistance has promoted the use of poly(methyl methacrylates) for outdoor electrical appHcations (22). 

Environmental Impact of Ambient Ozone. Ozone can be toxic to plants, animals, and fish. The lethal dose, LD q, for albino mice is 3.8 ppmv for a 4-h exposure (156) the 96-h LC q for striped bass, channel catfish, and rainbow trout is 80, 30, and 9.3 ppb, respectively. Small, natural, and anthropogenic atmospheric ozone concentrations can increase the weathering and aging of materials such as plastics, paint, textiles, and mbber. For example, mbber is degraded by reaction of ozone with carbon—carbon double bonds of the mbber polymer, requiring the addition of aromatic amines as ozone scavengers (see Antioxidants Antiozonants). An ozone decomposing polymer (noXon) has been developed that destroys ozone in air or water (157). 

An important property of a pigment is its ability to maintain its color when exposed to light, weather, heat, and chemicals. This property is seldom measured for pigments alone. Rather it is determined for the dispersion of a pigment in a desired medium, eg, paints or plastics, and in many cases it is compared to the performance of a standard pigment. The observed changes are the result of complex pigment and media reactions and their possible interactions. In aH evaluations, time of exposure plays a role. 

MSTM D1435, Recommended Practicefor Outdoor Weathering of Plastics, Vol. 8.01, ASTM, Philadelphia, Pa., 1985. 

Goal Tar. In roofing, coal tar is used as mopping bitumen in between 15 and 20% of the BUR roofs installed. Coal-tar pitch and asphalt are considered incompatible and should not be mixed. If mixed, an oily exudate is formed that plasticizes the bitumen, and the mixture remains soft and does not weather well. For this reason, if coal tar is used in BUR systems the felts must be coal-tar saturated. There has been some success using asphalt-coated fiber-glass mat felts with coal-tar pitch. However, this has only been done for a limited number of years so the actual compatibiHty is not fully known. 

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