Physical properties water permeability

Fluorine-containing polymers exhibit unique chemical and physical properties and high performance that are not observed with other organic polymers. They possess high thermal stability, high chemical stability, a low coefficient of friction, low adhesion, water and oil repellency, low refractive index, and outstanding electric insulation. In addition, there have recently been new expectations of selective permeability, piezoelectricity, and biocompatibility. 

Two principal types of fabric are adaptable to filter use woven fabrics, which are used in shaker and reverse-flow filters and felts, which are used in reverse-pulse filters. The felts made from synthetic fibers are needle felts (i.e., felted on a needle loom) and are normally reinforced with a woven insert. The physical properties and air permeabilities of some typical woven and felt filter fabrics are presented in Tables 17-6 and 17-7. The air permeability of a filter fabric is defined as the flow rate of air in cubic feet per minute (at 70°F, 1 atm) that will pass through 1 ft2 of clean fabric under an applied differential pressure of Vt in water. The resistance coefficient KF of the clean fabric is defined by the equation in Table 17-6, which may be used to calculate the value of KF from the air permeability. If Ap, is taken as 0.5 in water, t as 0.0181 cP (the viscosity of air at 70°F and 1 atm), and Vj as the air permeability, then //, = 27.8/air permeability. 

Tarvainen et al. (2002) studied the film-forming ability of starch acetate (DS 2.8) and the effect of commotfly used plasticizers on the physical properties of starch acetate films. The properties were compared with ethylcellulose films. Mechanical studies, water vapor and drug permeability tests, and thermal analysis by differential scarming calorimetry (DSC) were used to characterize the film-forming ability of starch acetate and efficiency of tested plasticizers. Starch acetate films were foimd to be tougher and stronger than ethylcellulose films at the same plasticizer concentration. Also, in most cases, the water vapor permeability of starch acetate... 

It is difficult to explain why toxic hydrocarbons can be made selective to carrots by the addition of a nontoxic oil but not by the addition of water. Green (7) found some correlation between the toxicity of oils and their ability to emulsify. It is commonly found that high aromatic oils are easier to emulsify than are oils with low aromatic content. It is possible that some action between the aromatic hydrocarbons and the emulsifying agent results in increased toxicity. There is some evidence that the permeability of the protoplasmic membrane is the key to carrot resistance. If this is true, the presence of the emul er or the physical properties of the emulsion might increase the cell penetration of the hydrocarbons. Work is being continued along these lines and on the fundamental reasons for differential plant resistance to oils. 

Central to the osmosis phenomenon is the semipermeable membrane (SPM), whose physical properties and species-selectivity directly govern the kinetics and thermodynamics of osmotic flow. Naturally occurring biomembranes of high selectivity, permeable to water but not to other solutes, are ubiquitous, for example, in macroscopic stomach linings and blood vessels, as well as in the microscopic cell membranes that encapsulate all known cell types. Some common synthetic membranes, such as Gore-Tex and cellophane, also exhibit selective permeability and osmotic activity. 

An obvious hypothesis is that this unusual membrane lipid composition is related directly to membrane function in some way. Within the restricted area of lipid bilayers, lipid composition is known to be an important determinant of physical properties. There are several prominent examples. First, the temperature at which the hydrocarbon chains melt when assembled in bilayers (the gel-to-liquid-crystalline transition temperature, marks an abrupt change in many of the physical properties of such bilayer systems for example, water permeability through such bilayers increases by several orders of magnitude above the transition. Second, the presence of cholesterol within bilayers composed of amphipathic lipids has a profound effect on lipid motion, mechanical properties (such as resistance to shear), and permeability to water. 

PHYSICAL PROPERTIES UPID BILAYERS AS PERMEABILITY BARRIERS Ion Transport Water Channels... 

Guo, J.-H. Robertson, R.E. Amidon, G.L. Influence of physical aging on mechanical properties of polymer free films the prediction of long-term aging effects on the water permeability and dissolution rate of polymer film-coated tablets. Pharm. Res. 1991, 8 (12), 1500-1504. 

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