Phosphorus applications

Increases in phosphorus export from agricultural landscapes have been measured after the application of phosphorus. Phosphorus losses are influenced by the rate, time, and method of phosphorus application, form of fertilizer or manure applied, amount and time of rainfall after application, and land cover. These losses are often small from the standpoint of farmers (generally less than 200 kg P km-2) and represent a minor proportion of fertilizer or manure phosphorus applied (generally less than 5%). Thus, these losses are not of economic importance to farmers in terms of irreplaceable fertility. However, they can contribute to eutrophication of downstream aquatic ecosystems. 

Brandt, K.and Molgaard, J.P. 2001. Organic agriculture does it enhance or reduce the nutritional value of plant foods Journal of the Science of Food and Agriculture 81 924-931. Buerkert, A., Haake, G., Ruckwied, M. and Marschner, H. 1998. Phosphorus application affects the nutritional quality of millet grain in the Sahel. Field Crops Research 57 223-235. 

Buerkert, A. Bationo, A. and H.P. Piepho (2001) Efficient phosphorus application strategies for increased crop production in sub-Saharan West Africa.- Field Crops Research 72, 1-15. 

Following 270 days of phosphorus application at the Jacksonville site. Residual Pb is obtained from the fractionation procedure. 

Xu M.G., Sun B.H., Zhang Y.P. 1998. Diffusion of phosphate and its energetic characteristics in soils Influence of phosphorus application rate and its interaction with soil moisture or/and temperature. Acta Pedologica Sinica 35 (1) 55 4 (in Chinese). 

Studies of the Stavropol Scientific Research Institute of Agriculture [9] showed that in conditions of ordinary loamy chernozem annual fertilizer phosphorus application for crops of a six coarse rotation rate of N,2oP9oKj2o first rotation of crop rotation ensured positive phosphorus balance (the content of phosphorus was determined by the method of Machigin) 270 kg/ha (Table 20.2, Figure 20.5). 

Aside from involvements of phosphorus as phosphates in the biochemistry of living systems, perhaps a second approach is to consider vital uses of phosphates in hundreds of products used daily, throughout most societies on Earth. Toy and Walsh s exceptional book. Phosphorus Chemistry in Everyday Livings gives an interesting approach to all forms of phosphorus applications, including DTA, RNA, and ATR Their approach is directed more toward the usefulness of these compounds rather than their safety when in contact with live forms, but it is a simplified, excellent coverage that will not be repeated here. ... 

BARBER S.A. 1979. Soil phosphorus after 25 years of cropping with five rates of phosphorus application. Communications in Soil Science and Plant Analysis, 10, 1459-1468. 

The procedure is not usually applicable to aminosulphonic acids owing to the interaction between the amino group and the phosphorus pentachloride. If, however, the chlorosulphonic acid is prepared by diazotisation and treatment with a solution of cuprous chloride in hydrochloric acid, the crystalline chlorosulphonamide and chlorosulphonanilide may be obtained in the usual way. With some compounds, the amino group may be protected by acetylation. Sulphonic acids derived from a phenol or naphthol cannot be converted into the sulphonyl chlorides by the phosphorus pentachloride method. 

The Gabriel s synthesis is also applicable when a polysubstituted thiazole is required (381, 550). Thus 2,4,5-trisubstituted thiazoles are obtained by treating the corresponding a-acylaminoketones with phosphorus pentasulfide for a few minutes at 100°C (550) or at higher temperature for heavier substituents (381). (Table 11-31). 

Thionyl chloride and phosphorus tribromide are specialized reagents used to bring about particular functional group transformations For this reason we won t present the mechanisms by which they convert alcohols to alkyl halides but instead will limit our selves to those mechanisms that have broad applicability and enhance our knowledge of fundamental principles In those instances you will find that a mechanistic understand mg IS of great help m organizing the reaction types of organic chemistry... 

Although widely applied in functional group modification in a variety of heterocyclic systems, phosphorus ylides have only been employed sparingly in heterocyclic ring construction with two or more heteroatoms in the nucleus. Their potential is shown in the applications illustrated below. 

An interesting application of a phosphorus ylide in heterocyclic synthesis is in a ring annulation. The diazopyrazole (592) when treated with various phosphorus ylides gave the 3//-pyrazolo[5,l-c][l,2,4]triazole derivatives (593) with elimination of triphenylphosphine (79TL1567). 

Shaft Furnaces The oldest and most important application of the shaft furnace is the blast furnace used for the production of pig iron. Another use is in the manufac ture of phosphorus from phosphate rock. Formerly hme was calcined exclusively in this type of furnace. Shaft furnaces are widely used also as gas producers. Chemicals are manufac tured in shaft furnaces from briquetted mixtures of the reacting components. 

For medium- to high-impact applications a wide range of low-alloy steels are produced containing some chromium, molybdenum, phosphorus, and silicon. Economy of manufacture is a benefit for selec tion of these steels. 

A recent review of research on phosphorus input to surface waters from agriculture highlights the variability of particulate and dissolved phosphorus contributions to catchments. The input varies with rainfall, fertilizer application rates, the history of the application of the fertilizer, land use, soil type, and between surface and sub-surface water. The balance struck between export of nutrients from the catchment and recipient-water productivity is the primary factor which controls its quality. 

The synthetic procedure described is based on that reported earlier for the synthesis on a smaller scale of anthracene, benz[a]anthracene, chrysene, dibenz[a,c]anthracene, and phenanthrene in excellent yields from the corresponding quinones. Although reduction of quinones with HI and phosphorus was described in the older literature, relatively drastic conditions were employed and mixtures of polyhydrogenated derivatives were the principal products. The relatively milder experimental procedure employed herein appears generally applicable to the reduction of both ortho- and para-quinones directly to the fully aromatic polycyclic arenes. The method is apparently inapplicable to quinones having an olefinic bond, such as o-naphthoquinone, since an analogous reaction of the latter provides a product of undetermined structure (unpublished result). As shown previously, phenols and hydro-quinones, implicated as intermediates in the reduction of quinones by HI, can also be smoothly deoxygenated to fully aromatic polycyclic arenes under conditions similar to those described herein. 

Although the majority of NAA applications have been in the area of bulk analysis, some specialized uses need to be mentioned. One such unique application is the measurement of phosphorus in thin films (about 5000 A) of phosphosilicate (PSG) or borophosphosilicate (BPSG) glasses used in VLSI device fabrication. In this case,... 

Enolates of aldehydes, ketones, and esters and the carbanions of nitriles and nitro compounds, as well as phosphorus- and sulfur-stabilized carbanions and ylides, undergo the reaction. The synthetic applications of this group of reactions will be discussed in detail in Chapter 2 of Part B. In this section, we will discuss the fundamental mechanistic aspects of the reaction of ketone enolates with aldehydes md ketones. 

Aluminum based chemicals have been used for many years in wastewater treatment applications for suspended solids removal. These include dry and liquid alum, with sodium aluminate used in activated sludge plants for phosphorus removal. 

The application of biosolids also increases the nutritional value of blue grama. Tissue levels of nitrogen, phosphorus, potassium, and crude protein increased to recommended tissue concentrations with biosolids treatments. Trace metals in blue grama grass did not increase during the study, thereby eliminating concerns that toxic amounts of these elements could be transferred to grazing animals. 

Covalent fluondes of group 3 and group 5 elements (boron, tin, phosphorus, antimony, etc ) are widely used m organic synthesis as strong Lewis acids Boron trifluoride etherate is one of the most common reagents used to catalyze many organic reactions. A representative example is its recent application as a catalyst in the cycloadditions of 2-aza-l,3-dienes with different dienophiles [14] Boron trifluoride etherate and other fluonnated Lewis acids are effective activators of the... 

All the approaches for deblocking protective groups described earlier in this book have found application in the removal of protective groups from phosphorus derivatives. Because phosphate protection and deprotection are commonly associated with compounds that contain acid-sensitive sites (e.g., glycosidic linkages and DMTr-O- groups of nucleotides), the most widely used protective groups on phosphorus are those that are deblocked by base. 

Because of the great importance of phosphorus and its compounds in the chemical industry, several books and reviews on their preparation and uses are available.Some of these applications reflect the fact that P is a vital element for the growth and development of all plants and animals and is therefore an important constituent in many fertilizers. Phosphorus compounds are involved in energy transfer... 

Proceedings of the First International Congress on Phosphorus Compounds and their Non-fertilizer Applications, 17-21 October 1977 Rabat, Morocco, IMPHOS (Institut Mondial du Phosphat), Rabat, 1978, 767 pp. 

---