Phenyl acetanilide

N-(Butoxymethyl)-2-chloro-N-(2,6-diethylphenyl)aoetamide. Acetamide, N-(butoxymethyl)-2-chloro-N-(2,6-diethyl-phenyl)- Acetanilide, 2-ch oro-2, 6 -diethyl-N-(butoxy-methyl)- Acetanilide, N-(butoxymethyl)-2-chloro-2, 6 -diethyl- Amichlor Bilchlor BRN 2873811 Butachlor Butaclor Butanex Caswell No, 119B 2-Chloro-2, 6 -diethyl-N-(butoxymethyl)acetanilide CP 53619 Del-ohlor Delchior 5G 2, 6 -Diethyl-N-butoxymethyl-2-chloroacetanilide 2,6 -Diethyl-N-butoxymethyl-a-chloro-acetanilide EINECS 245-477-8 EPA Pesticide Chemical Code 112301 Hiltachlor HSDB 6865 Mach-Mach Machete Machete (herbicide) Machetfe N-(Butoxymethyl)-2-chloro-N-(2,6-diethylphenyl)acetamide N-... 

Chloro-N-(l-isopropyl-4-piperidinyl)-2-phenyl-acetanilide monohydrochloride Benzeneacetamide, N-(4-chlorophenyl)-N-l-(l-methylethyl)-4-piperidinyl-, monohydrochloride Lorcainide Hydrochloride (Janssen Pharmaceutica, Belgium)... 

N-Acettfi N-diphenylacetamide, N-phenyl-acetanilide. C-gHigON. MW, 211. Cryst, from ligroin or EtgO. M.p. 103°. Sublimes. N-Bemzoyl see Diphenylbenzamide. 

Pyridine has been phenylated with the following free-radical sources benzenediazonium chloride with aluminum trichloride the Gomberg reaction " phenylhydrazine and metal oxides A -nitroso-acetanilide dibenzoyl peroxide phenylazotriphenylmethane di-phenyliodonium hydroxide and electrolysis of benzoic acid. ° Although 2-phenylpyridine usually accounts for over 50% of the total phenylated product, each of the three phenyl derivatives can be obtained from the reaction by fractional recrystallization of the... 

Some of the artificial musks of commerce are mixtures of two or more of the bodies above described, a fact which is easily demonstrated by fractionally crystallising the specimen, when the fractions will show altered melting-points. The principal adulterant of artificial musk is acetanilide. This can, of course, be easily detected by the phenyl-isocyanide reaction or by dissolving it out with hot water. 

Feng et al. [3] have studied the structural effect of acetanilide on the AAM polymerization either in water-for-mamide [3], water-acetonitrile [4], and water-DMF [26] mixed solution using Ce(IV) ion-acetanilide and its substituted derivatives as the initiator. The results showed that an electron donating substituent on the phenyl group would enhance the Rp, while an electron withdrawing group would decrease it, as shown in Table 1 [26]. 

Abietylamine, dehydro-, A tnfluoro- [Acetamide, 2,2,2-trifluoro-/V-[ [1,2,3,4,4a, 9,10,1 Oa-octahydro-l, 4a-dtmethyl-7-(l-methylethyl)-l -phenanthrenyl ] -methyl]-, [17 (la,4ad,10aa))-, 125 Acetamides, A-arylalkyl-, 7 Acetanilide, 2,2,2-tnfluoro- [Acetamide, 2,2,2-tnfluoroTV-phenyl-], 122 Acetic acid, cyano-, methyl ester, 63 Acetic acid, methoxy-, 70 Acetic acid, phenoxy-, 68 Acetic acid, phenyl- [Benzeneacetic acid],... 

De la Mare and Hassan254 obtained second-order rate coefficients (in parenthesis) for the following 4-methylacetanilide (1.53), 2-methylacetanilide (0.193), 2,6-dimethylacetanilide (0.0118), acetanilide (0.93), 4-acetamidodiphenyl (0.248) and 1,4-diacetamidobenzene (0.231) the results for the acetanilides demonstrated the effect of steric hindrance to coplanarity thereby inhibiting resonance of the nitrogen lone pair with the aromatic ring. The rate coefficients for chlorination of 3-chloroacetanilide (0.215), 4-chloroacetanilide (0.010) 3-nitroacetanilide (6.7 x 10 5) and phenyl benzoate (3.2 x 10-6) have also been measured258,261. 

The objectives of this study were to (a) determine the mobilities of the herbicides, alachlor (2-chloro-2, 6 -diethyl-N-(me-thoxymethyl)acetanilide), butylate (S-ethyl diisobutylthiocarba-mate), and metolachlor (2-chloro-N-(2-ethyl-6-methyl phenyl)-N-(2-methoxy-l-methyl ethyl) acetamide in the laboratory using soil leaching columns and soil thin-layer vapor diffusion techniques,... 

The conversion of hydrazobenzene into the isomeric benzidine— discovered by the Russian chemist Zinin in the year 1846—is started catalyticaUy by mineral acids and results from the tendency of the molecule to pass into a form possessing less energy, i.e. into a more saturated condition. The reaction is suitably classified with those of which the chief characteristic is that a substituent united to nitrogen exchanges its point of attachment with an H-atom of the nucleus— usually an H-atom in the p-position. To this class belong the conversion of phenylsulphaminic acid into sulphanilic acid (p. 198), of phenyl-hydroxylamine into p-aminophenol (p. 176), and also of acetanilide into p-aminoacetophenone and of N-chloroacetanilide into p-chloro-acetanilide ... 

Table 6 Hyperfine Coupling Constants of the Acyl Radicals Detected in the Photolysis of Phenyl Acetate, Phenyl Benzoate and Acetanilide...

Upon excitation to the singlet state [87], acetanilide (100) reacts to 2-amino-acetophenone (101), 4-aminoacetophenone (102), and aniline (Scheme 31). The quantum yield of product formation is considerably lower than that of phenyl... 

Other studies on the PFR in the presence of cyclodextrins include substrates with different acyl moieties (phenyl propionate and phenyl valerate) [261] 1-naphthyl acetate [262,263], 1-naphthyl benzoate [263], sulfonate esters, [264,265], benzenesulfonylanilides [266], acetanilide [259,267], and benzanilide [259,268]. 

Acetal formation from pentaerythritol and benzaldehyde, 38, 65 Acetamide, 31, 17 Acetamide, N-bromo, 31,17 a-PHENYL-, 32, 92 Acetanilide, cz-benzoyl-, 37, 2 a -ben zoyl-2-mcth oxy-4-ni tro, 37, 4 Acetic acid, benzoyl-, ethyl ester, 37, 3, 32... 

When acetophenone oxime (1) is thermically treated with acidic solids in "dry media" under soft experimental conditions, two main products are obtained the rearrangement one acetanilide (N-phenyl acetamide) (2) obtained by Beckmann rearrangement with migration of the phenyl group, and the hydrolysis one acetophenone (3), obtained by the hydrolysis of the imino group (C=N) (eqn.2). 

Preparation 274.—Acetanilide [Phenyl-amide of ethan add], CH3C0NHC6H6. C8H8ON. 135. 

Water Dimethoate, metramitron Triazines, phenyl-urea herbicides, acetanilides... 

The photochemistry of diphenyl- and bis(4-methylphenyl)iodonium salts has been investigated481,482. Diphenyliodonium halides (140, X = Cl, Br, I) exist as tight ion pairs in acetonitrile. Their photolysis gives almost exclusively iodobenzene by a homolytic cleavage from a charge-transfer excited state. In aqueous acetonitrile, however, the ion pairs are solvent-separated and substantial amounts of 2-, 3- and 4-iodobiphenyls (141) are formed in addition to iodobenzene (142), benzene (143), acetanilide (144) and biphenyl (145) (equation 126). In this medium the photodecomposition occurs via initial heterolysis of the molecule in its excited state, leading to iodobenzene and phenyl cation. 

As outlined above, the orientation of substitution in bicyclic benzazines frequently occurs preferentially at the 5- and/ or 8-positions. However, when the heterocyclic ring contains a carbonyl group, the orientation of substitution in a fused benzene ring frequently occurs in the 6-position, for example for 2-quinolone 618 (Z = NH) (nitration, H2SO4HNO3, 20 C) and for coumarin 618 (Z = 0) [nitration (H2S04HN03) and sulfonation (H2S04)], and this can be compared with the /wra-substitution of acetanilide and phenyl acetate, respectively. 

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