Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Perfect

In the second model (Fig. 2.16) the continuous well-stirred model, feed and product takeoff are continuous, and the reactor contents are assumed to he perfectly mixed. This leads to uniform composition and temperature throughout. Because of the perfect mixing, a fluid element can leave at the instant it enters the reactor or stay for an extended period. The residence time of individual fluid elements in the reactor varies. [Pg.29]

Hydrorefining can substitute for extraction processes such as furfural where it integrates perfectly into the conventional process scheme. [Pg.396]

The Fuzzy-ARTMAP network reaehes the best learning rate of the training data set. This is recognised perfectly with 100% correctness. The exact results are presented in the next table ... [Pg.466]

The function h(t) to be restored is the impulse response of the medium x(t) is the transmitted pulse measured by reflection on a perfect plane reflector, for example the interface between air and water and y(t) is the observed signal. [Pg.746]

It seems almost perfect. Established methods, established acceptance criteria, established procedures and personnel qualification schemes. Almost perfect. Because the reason of this presentation is, to show that things could be improved. [Pg.946]

F.H. Dijkstra, J.A. de Raad and T. Bouma, TOFD Acceptance Criteria a Perfect Team. 14" World Conference on Non-Destructive Testing, New Delhi, India, December 1996... [Pg.951]

You will need to know addresses (http //www.) of the major Internet search engines. But search engines are still not perfected and the results may contain certain amount of noise, i. e, irrelevant information. Some companies use tricky things to get your attention we found many NDT related words like TOFD hidden as meta keywords in every page of some websites. If a search engine leads you to this site you will find no actual information provided, not even a single visible instance of the word TOFD. [Pg.976]

Systems involving an interface are often metastable, that is, essentially in equilibrium in some aspects although in principle evolving slowly to a final state of global equilibrium. The solid-vapor interface is a good example of this. We can have adsorption equilibrium and calculate various thermodynamic quantities for the adsorption process yet the particles of a solid are unstable toward a drift to the final equilibrium condition of a single, perfect crystal. Much of Chapters IX and XVII are thus thermodynamic in content. [Pg.2]

In the converse situation free of gravity, a drop assumes a perfectly spherical shape. At one point, the U.S. Space program tested this idea with the solidification of ball bearings from molten metal drops in microgravity conditions. [Pg.32]

It might be noted that only for particles smaller than about 1 /ig or of surface area greater than a few square meters per gram does the surface energy become significant. Only for very small particles does the edge energy become important, at least with the assumption of perfect cubes. [Pg.271]

The discovery of perfect geodesic dome closed structures of carbon, such as C o has led to numerous studies of so-called Buckminster fullerene. Dislocations are important features of the structures of nested fullerenes also called onion skin, multilayered or Russian doll fullerenes. A recent theoretical study [118] shows that these defects serve to relieve large inherent strains in thick-walled nested fullerenes such that they can show faceted shapes. [Pg.278]

Qualitative examples abound. Perfect crystals of sodium carbonate, sulfate, or phosphate may be kept for years without efflorescing, although if scratched, they begin to do so immediately. Too strongly heated or burned lime or plaster of Paris takes up the first traces of water only with difficulty. Reactions of this type tend to be autocat-alytic. The initial rate is slow, due to the absence of the necessary linear interface, but the rate accelerates as more and more product is formed. See Refs. 147-153 for other examples. Ruckenstein [154] has discussed a kinetic model based on nucleation theory. There is certainly evidence that patches of product may be present, as in the oxidation of Mo(lOO) surfaces [155], and that surface defects are important [156]. There may be catalysis thus reaction VII-27 is catalyzed by water vapor [157]. A topotactic reaction is one where the product or products retain the external crystalline shape of the reactant crystal [158]. More often, however, there is a complicated morphology with pitting, cracking, and pore formation, as with calcium carbonate [159]. [Pg.282]

Bikerman [179] has argued that the Kelvin equation should not apply to crystals, that is, in terms of increased vapor pressure or solubility of small crystals. The reasoning is that perfect crystals of whatever size will consist of plane facets whose radius of curvature is therefore infinite. On a molecular scale, it is argued that local condensation-evaporation equilibrium on a crystal plane should not be affected by the extent of the plane, that is, the crystal size, since molecular forces are short range. This conclusion is contrary to that in Section VII-2C. Discuss the situation. The derivation of the Kelvin equation in Ref. 180 is helpful. [Pg.285]

The mechanism of crystal growth has been a topic of considerable interest. In the case of a perfect crystal, the starting of a new layer involves a kind of nucleation since the first few atoms added must occupy energy-rich positions. Becker and Doring [4],... [Pg.340]

D. Y. Kwok, F. Y. H. Lin, and A. W. Neumann, Contact Angle Studies on Perfect and Imperfect Solid Surfaces, in Proc. 30th Int. Adhesion Symp., Yokohama Japan, 1994. [Pg.386]

As might be expected, this simple picture does not hold perfectly. The coefficient of friction tends to increase with increasing velocity and also is smaller if the pavement is wet [14]. On a wet road, /x may be as small as 0.2, and, in fact, one of the principal reasons for patterning the tread and sides of the tire is to prevent the confinement of a water layer between the tire and the road surface. Similarly, the texture of the road surface is important to the wet friction behavior. Properly applied, however, measurements of skid length provide a conservative estimate of the speed of the vehicle when the brakes are first applied, and it has become a routine matter for data of this kind to be obtained at the scene of a serious accident. [Pg.438]

Finally, it is perfectly possible to choose a standard state for the surface phase. De Boer [14] makes a plea for taking that value of such that the average distance apart of the molecules is the same as in the gas phase at STP. This is a hypothetical standard state in that for an ideal two-dimensional gas with this molecular separation would be 0.338 dyn/cm at 0°C. The standard molecular area is then 4.08 x 10 T. The main advantage of this choice is that it simplifies the relationship between translational entropies of the two- and the three-dimensional standard states. [Pg.646]

On the other hand, as applied to the submonolayer region, the same comment can be made as for the localized model. That is, the two-dimensional non-ideal-gas equation of state is a perfectly acceptable concept, but one that, in practice, is remarkably difficult to distinguish from the localized adsorption picture. If there can be even a small amount of surface heterogeneity the distinction becomes virtually impossible (see Section XVll-14). Even the cases of phase change are susceptible to explanation on either basis. [Pg.653]

Since indistinguishability is a necessary property of exact wavefiinctions, it is reasonable to impose the same constraint on the approximate wavefiinctions ( ) fonned from products of single-particle solutions. Flowever, if two or more of the Xj the product are different, it is necessary to fonn linear combinations if the condition P. i = vj/ is to be met. An additional consequence of indistinguishability is that the h. operators corresponding to identical particles must also be identical and therefore have precisely the same eigenfiinctions. It should be noted that there is nothing mysterious about this perfectly reasonable restriction placed on the mathematical fonn of wavefiinctions. [Pg.26]

Issues associated with order occupy a large area of study for crystalline matter [1, 7, 8]. For nearly perfect crystals, one can have systems with defects such as point defects and extended defects such as dislocations and grain... [Pg.86]

Defining order in an amorphous solid is problematic at best. There are several qualitative concepts that can be used to describe disorder [7]. In figure Al.3.28 a perfect crystal is illustrated. A simple fonn of disorder involves crystals containing more than one type of atom. Suppose one considers an alloy consisting of two different atoms (A and B). In an ordered crystal one might consider each A surrounded by B and vice versa. [Pg.130]

The next step, therefore, is to address the question how is it possible to take advantage of the many additional available parameters pulse shaping, multiple pulse sequences, etc—m general an E(t) with arbitrary complexity—to maximize and perhaps obtain perfect selectivity Posing the problem mathematically, one seeks to maximize... [Pg.274]


See other pages where Perfect is mentioned: [Pg.28]    [Pg.9]    [Pg.108]    [Pg.239]    [Pg.241]    [Pg.317]    [Pg.393]    [Pg.393]    [Pg.231]    [Pg.332]    [Pg.375]    [Pg.479]    [Pg.528]    [Pg.686]    [Pg.780]    [Pg.90]    [Pg.272]    [Pg.273]    [Pg.276]    [Pg.347]    [Pg.437]    [Pg.574]    [Pg.575]    [Pg.652]    [Pg.86]    [Pg.87]    [Pg.130]    [Pg.271]    [Pg.286]   
See also in sourсe #XX -- [ Pg.170 ]




SEARCH



Perfecting

Perfection

Perfectly

© 2024 chempedia.info