1.2.3- Triazine with organometallic compounds

The chemistry of fluorinated 1,3,5-triazines is not as well studied as the chemistry of their chloro derivatives. In case of fluorotriazines the reactions directed on the ring nitrogen atoms, displacement of fluorine atoms and reactions on carbon atoms on the ring with retention of the fluorine atoms appear to be the most characteristic ones. In this section the N-alkylation and N-acylation reactions, as well as replacement of fluorine atoms by a variety of nucleophiles will be considered. Metallation of fluorotriazines and synthesis on the basis of organometallic compounds, as well as the cross-coupling reactions were described. Also several examples of photochemical reactions and transformations are presented. 

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