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Organometallic compounds coupling with alcohols

The direct substitution of hydroxyl groups can also be extended towards propargylic alcohols. In the presence of FeCl3, a plethora of O-, N- or S-nudeophiles are able to react with substituted propargylic alcohols [17]. Amongst the variety of nucleophiles, allylsilanes occupy an important position since this example resembles a cross-coupling reaction between an organometallic compound and an alcohol (Scheme 7.12) [17]. [Pg.203]

In some cases, it is possible to couple an alcohol with an organometallic compound. Allylic alcohols are coupled with alkylmagnesium bromides in the presence of Ti(OiPr)4, for example. Allylic alcohols can be coupled with arylboronic acids in ionic liquid solvent and a rhodium catalyst. The palladium-catalyzed... [Pg.614]

See other pages where Organometallic compounds coupling with alcohols is mentioned: [Pg.1272]    [Pg.159]    [Pg.288]    [Pg.1694]    [Pg.86]    [Pg.27]    [Pg.98]    [Pg.260]    [Pg.1693]    [Pg.266]    [Pg.5049]    [Pg.36]    [Pg.145]    [Pg.274]    [Pg.32]    [Pg.65]    [Pg.371]    [Pg.89]    [Pg.13]    [Pg.128]    [Pg.50]    [Pg.198]    [Pg.184]    [Pg.3]    [Pg.3]    [Pg.8]    [Pg.840]    [Pg.301]    [Pg.36]    [Pg.198]    [Pg.100]    [Pg.826]    [Pg.86]    [Pg.133]    [Pg.105]    [Pg.3]    [Pg.292]   
See also in sourсe #XX -- [ Pg.614 ]



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Alcohols compounds

Alcohols coupling

Coupling compounds

Coupling with organometallics

Coupling, organometallic organometallics

Organometallic compounds with

Organometallic couplings

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