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Normal phase temperature

Lee W, Cho D, Chun BO, Chang T, Ree M. Characterisation of polystyrene and pol-yisoprene by normal-phase temperature gradient interaction chromatography. J Chromatogr A 2001 910 51. [Pg.124]

Below about 0.5 K, the interactions between He and He in the superfluid Hquid phase becomes very small, and in many ways the He component behaves as a mechanical vacuum to the diffusional motion of He atoms. If He is added to the normal phase or removed from the superfluid phase, equiHbrium is restored by the transfer of He from a concentrated phase to a dilute phase. The effective He density is thereby decreased producing a heat-absorbing expansion analogous to the evaporation of He. The He density in the superfluid phase, and hence its mass-transfer rate, is much greater than that in He vapor at these low temperatures. Thus, the pseudoevaporative cooling effect can be sustained at practical rates down to very low temperatures in heHum-dilution refrigerators (72). [Pg.9]

Sohd ammonium nitrate occurs in five different crystalline forms (19) (Table 6) detectable by time—temperature cooling curves. Because all phase changes involve either shrinkage or expansion of the crystals, there can be a considerable effect on the physical condition of the sohd material. This is particularly tme of the 32.3°C transition point which is so close to normal storage temperature during hot weather. [Pg.365]

Although 16 different crystalline modifications have been identified (24,25), the a-pentahydrate is the stable form below 48°C. Solutions of sodium thiosulfate in the absence of seed crystals can be easily supercooled below their normal crystallisation temperatures. The dotted line extension of the dihydrate phase in Figure 1 is an indication that, if supercooling takes place below this line, solutions normally giving the pentahydrate may form the dihydrate [36989-90-9] s1ste2id. [Pg.28]

Colloidal State. The principal outcome of many of the composition studies has been the delineation of the asphalt system as a colloidal system at ambient or normal service conditions. This particular concept was proposed in 1924 and described the system as an oil medium in which the asphaltene fraction was dispersed. The transition from a coUoid to a Newtonian Hquid is dependent on temperature, hardness, shear rate, chemical nature, etc. At normal service temperatures asphalt is viscoelastic, and viscous at higher temperatures. The disperse phase is a micelle composed of the molecular species that make up the asphaltenes and the higher molecular weight aromatic components of the petrolenes or the maltenes (ie, the nonasphaltene components). Complete peptization of the micelle seems probable if the system contains sufficient aromatic constituents, in relation to the concentration of asphaltenes, to allow the asphaltenes to remain in the dispersed phase. [Pg.367]

Traditionally, LC and GC are used as separate steps in the sample analysis sequence, with collection in between, and then followed by transfer. A major limitation of off-line LC-GC is that only a small aliquot of the LC fraction is injected into the GC p. (e.g. 1 - 2 p.1 from 1 ml). Therefore, increasing attention is now given to the on-line combination of LC and GC. This involves the transfer of large volumes of eluent into capillary GC. In order to achieve this, the so-called on-column interface (retention gap) or a programmed temperature vaporizor (PTV) in front of the GC column are used. Nearly all on-line LC-GC applications involve normal-phase (NP) LC, because the introduction of relatively large volumes of apolar, relatively volatile mobile phases into the GC unit is easier than for aqueous solvents. On-line LC-GC does not only increase the sensitivity but also saves time and improves precision. [Pg.273]

Fig. 2-9. Chromatograms of phensuximide in normal phase on vancomycin (A), teicoplanin (B), ristocetin A (C), vancomycin + teicoplanin (D), ristocetin A + vancomycin (E), ristocetin A + teicoplanin (F), and ristocetin A + vancomycin + teicoplanin (G). All columns were 100 x 4.6 mm. The numbers by the peaks refer to the retention time in minutes. The mobile phase was ethanol hexane (60/40 v/v) and the flow rate was 1.5 mL min at ambient temperature (23 °C). Fig. 2-9. Chromatograms of phensuximide in normal phase on vancomycin (A), teicoplanin (B), ristocetin A (C), vancomycin + teicoplanin (D), ristocetin A + vancomycin (E), ristocetin A + teicoplanin (F), and ristocetin A + vancomycin + teicoplanin (G). All columns were 100 x 4.6 mm. The numbers by the peaks refer to the retention time in minutes. The mobile phase was ethanol hexane (60/40 v/v) and the flow rate was 1.5 mL min at ambient temperature (23 °C).
Fig. 2-11. The effect of flow rate on the selectivity of a-methyl-a-phenyl succinimide on teicoplanin CSP (250 X 4.6 mm) in normal phase. The mobile phase was ethanol hexane (20/80 v/v) at ambient temperature (23 °C). Fig. 2-11. The effect of flow rate on the selectivity of a-methyl-a-phenyl succinimide on teicoplanin CSP (250 X 4.6 mm) in normal phase. The mobile phase was ethanol hexane (20/80 v/v) at ambient temperature (23 °C).
Fig. 2-18. Normal phase retention of the first eluted and seeond eluted enantiomer of mephenytoin on vaneomyein CSP (250 x 4.6 mm). The flow rate was 1.0 mL min at ambient temperature (23 °C). Fig. 2-18. Normal phase retention of the first eluted and seeond eluted enantiomer of mephenytoin on vaneomyein CSP (250 x 4.6 mm). The flow rate was 1.0 mL min at ambient temperature (23 °C).
Normal phase a. Type of polar solvent b. Coneentration of polar solvent e. Aeid and base as modifiers d. Temperature... [Pg.53]

Gaz qui demeure gazeux dans la rocbe reservoir, quelle que soit la pression, mais qui dans les conditions normales de temperature et de pression donne naissance k une phase condensee liquide. [Pg.45]

Figure 4.4 Heat capacity of N as a function of temperature. A solid phase transition occurs at 35.62 K, the melting temperature is 63.15 K, and the normal boiling temperature is 77.33 K. Figure 4.4 Heat capacity of N as a function of temperature. A solid phase transition occurs at 35.62 K, the melting temperature is 63.15 K, and the normal boiling temperature is 77.33 K.
Figure 4.7 Heat capacity and phase transitions in phosphine. The same entropy at point (a) is obtained by going the stable (lower) route or by going the metastable (upper) route. Point (b) is the normal boiling temperature. Figure 4.7 Heat capacity and phase transitions in phosphine. The same entropy at point (a) is obtained by going the stable (lower) route or by going the metastable (upper) route. Point (b) is the normal boiling temperature.
Liquid and vapor are in equilibrium when the pressure of the vapor phase is the vapor pressure. When the (vapor + liquid) equilibrium mixture is exposed to the atmosphere, the mixture will boil at a temperature where the vapor pressure equals the external (atmospheric) pressure. This temperature is known as the boiling temperature. At the normal boiling temperature, the substance has a vapor pressure of exactly one atmosphere (0.101325 MPa) and hence, boils at this external pressure. [Pg.232]

The equilibrium pressure when (solid + vapor) equilibrium occurs is known as the sublimation pressure, (The sublimation temperature is the temperature at which the vapor pressure of the solid equals the pressure of the atmosphere.) A norma) sublimation temperature is the temperature at which the sublimation pressure equals one atmosphere (0.101325 MPa). Two solid phases can be in equilibrium at a transition temperature (solid + solid) equilibrium, and (liquid + liquid) equilibrium occurs when two liquids are mixed that are not miscible and separate into two phases. Again, "normal" refers to the condition of one atmosphere (0.101325 MPa) pressure. Thus, the normal transition temperature is the transition temperature when the pressure is one atmosphere (0.101325 MPa) and at the normal (liquid + liquid) solubility condition, the composition of the liquid phases are those that are in equilibrium at an external pressure of one atmosphere (0.101325 MPa). [Pg.232]

Use the phase diagram for compound X below to answer these questions (a) Is X a solid, liquid, or gas at normal room temperatures (b) What is the normal melting point ol X ... [Pg.471]

Phase changes are characteristic of all substances. The normal phases displayed by the halogens appear in Section II-L where we also show that a gas liquefies or a liquid freezes at low enough temperatures. Vapor pressure, which results from molecules escaping from a condensed phase into the gas phase, is one of the liquid properties described in Section II-I. Phase changes depends on temperature, pressure, and the magnitudes of intermolecular forces. [Pg.803]

A third category of syn eliminations involves pyrolytic decomposition of esters with elimination of a carboxylic acid. The pyrolysis of acetate esters normally requires temperatures above 400° C and is usually a vapor phase reaction. In the laboratory this is done by using a glass tube in the heating zone of a small furnace. The vapors of the reactant are swept through the hot chamber by an inert gas and into a cold trap. Similar reactions occur with esters derived from long-chain acids. If the boiling point of the ester is above the decomposition temperature, the reaction can be carried out in the liquid phase, with distillation of the pyrolysis product. [Pg.600]

Table 18-2 Enthalpies of Phase Change (at Normal Phase Change Temperatures)... Table 18-2 Enthalpies of Phase Change (at Normal Phase Change Temperatures)...
In a plant for the continuous nitration of chlorobenzene, maloperation during startup caused the addition of substantial amounts of reactants into the reactor before effective agitation and mixing had been established. The normal reaction temperature of 60°C was rapidly exceeded by at least 60° and an explosion occurred. Subsequent investigation showed that at 80° C an explosive atmosphere was formed above the reaction mixture, and that the adiabatic vapour-phase nitration would attain a temperature of 700° C and ignite the explosive atmosphere in the reactor. See l,3-Bis(trifluoromethyl)benzene, above... [Pg.1576]


See other pages where Normal phase temperature is mentioned: [Pg.61]    [Pg.62]    [Pg.41]    [Pg.8]    [Pg.464]    [Pg.213]    [Pg.141]    [Pg.163]    [Pg.163]    [Pg.305]    [Pg.306]    [Pg.324]    [Pg.40]    [Pg.53]    [Pg.1310]    [Pg.571]    [Pg.228]    [Pg.410]    [Pg.398]    [Pg.155]    [Pg.20]    [Pg.94]    [Pg.210]    [Pg.244]    [Pg.372]    [Pg.54]    [Pg.67]    [Pg.109]   
See also in sourсe #XX -- [ Pg.70 ]




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