Nickel steel specifications

Nickel Steel Low-carbon 9 percent nickel steel is a ferritic alloy developed for use in cryogenic equipment operating as low as —I95°C (—320°F). ASTM specifications A 300 and A 353 cover low-carbon 9 percent nickel steel (A 300 is the basic specification for low-temperature ferritic steels). Refinements in welding and (ASME code-approved) ehmination of postweld thermal treatments make 9 percent steel competitive with many low-cost materials used at low temperatures. 

Low-carbon and chromium-nickel steels, certain copper, nickel and aluminium alloys (which are all widely used in marine and offshore engineering) are liable to exhibit stress-corrosion cracking whilst in service in specific environments, where combinations of perhaps relatively modest stress levels in material exposed to environments which are wet, damp or humid, and in the presence of certain gases or ions such as oxygen, chlorides, nitrates, hydroxides, chromates, nitrates, sulphides, sulphates, etc. 

A large fraction of the iron and steel produced today is recycled scrap. Since scrap does not require reduction, it can be melted down directly in an electric arc furnace, in which the charge is heated through its own electrical resistance to arcs struck from graphite electrodes above it. The main problem with this process is the presence of tramps (i.e., copper from electrical wiring, chromium, nickel, and various other metals) that accompany scrap steel such as crushed automobile bodies and that lead to brittleness in the product. Tin in combination with sulfur is the most troublesome tramp. Only the highest quality recycled steel—specifically, steel with no more than 0.13% tramps—can be used for new automobile bodies, and usually reprocessed scrap has to be mixed with new steel to meet these requirements. 

The main features of these concepts are freestanding inner tank and bottom in 9% nickel steel and aluminium suspended deck, with all penetrations from the tank roof. Pump wells are either supported from the tank base (as for type a+b) or from the roof (type c). The insulation material is usually perlite. Further specific features ... 

The significance of the pop-ins in the nickel steel COD and i -curves is the subject of some debate. Pop-ins represent rapid crack extensions followed by arrest. These arrests may be related to material toughness characteristics, but may also be the result of a drop-off in applied load due to the stiffness of the testing machine. The fracture toughness results developed in this work are intended to supplement the designer s basic understanding of the materials and aid in the selection of a particular material for a specific application. These tests show that the performance of a structure fabricated with the nickel steels will be dependent on the HAZ behavior. This information must be blended with additional design, fabrication, and economic factors before final material selection. 

SA-264 Specification for. stainless chromium Nickel steel-clad plate... 

Corrosion sodium chloride solution is aroimd 0.23 V (SCE), which compares with 0.38 V for type 304 stainless steel. This puts titanium-nickel on the noble or protected side of steiinless steel in the galvanic series. A passive oxide/nitride surface film is the basis of the corrosion resistance of titanium-nickel alloys, similar to stainless steels. Specific environments can cause the passive film to break down, thus subjecting the base material to attack. A summary of titanium-nickel reactions in various environments follows (Ref 28). 

Many types of stainless steels are available. The type most widely used in the dairy industry is 18—8 (18% chromium, 8% nickel plus iron). Small amounts of siHcon, molybdenum, manganese, carbon, sulfur, and phosphoms maybe included to obtain characteristics desired for specific appHcations. 

Corrective action should be initiated when value is > — 0.23 V against the standard hydrogen electrode (SHE). Plant-specific values should be estabUshed for protection of stainless steels and nickel-based critical components. 

Liquids. Approximately 170,000 railroad tank cars are used in the United States. The interior surfaces of these cars are tailored to carry a wide variety of products and are constmcted of steel which is either unlined or lined with materials to enhance the chemical compatibiUty with a specific product these lining materials include synthetic mbber, phenoHc or modified epoxy resins, or corrosion-resistant materials such as aluminum, nickel-bearing steel, or stainless steel. 

GoldJilloys, Wrought Type. Two types of wrought gold alloys were formerly recognized by the ADA specification no. 7 for the fabrication of orthodontic and prosthetic dental appHances, ie, type I, high-precious-metal alloys, and type II, low-precious-metal alloys (gold color). Alloys of this type are seldom used in the United States they have been replaced by stainless steels and nickel—titanium alloys. 

Sa.lt Spray Tests. One of the older accelerated corrosion tests is the salt spray test (40). Several modifications of this imperfect test have been proposed, some of which are even specified for particular appHcations. The neutral salt spray test persists, however, especially for coatings that are anodic to the substrate and for coatings that are dissolved or attacked by neutral salt fog. For cathodic coatings, such as nickel on steel, the test becomes a porosity test, because nickel is not attacked by neutral salt fog. Production specifications that call for 1000 hours salt spray resistance are not practical for quahty acceptance tests. In these cases, the neutral salt spray does not qualify as an accelerated test, and faster results from different test methods should be sought. 

Materials of Construction for Bulk Transport Because of the more severe service, construction materials for transportation usually are more restricted than for storage. Most large pipe lines are constructed of steel conforming to API Specification 5L or 5LX. Most tanks (cars, etc.) are built or pressure-vessel steels or AAR specification steels, with a few of aluminum or stainless steel. Carbon steel tanks may be hned with rubber, plastic, nickel, glass, or other materials. In many cases this is practic and cheaper than using a stainless-steel tank. Other materials for tank construction may be proposed and used if approved by the appropriate authorities (AAR and DOT). 

Manufacturing tolerances for steel, stainless-steel, and nickel-alloy tubes are such that the tubing is produced to either average or minimum wall thickness. Seamless carbon steel tube of minimum wall thickness may vaiy from 0 to 20 percent above the nominal wall thickness. Average-wall seamless tubing has an allowable variation of plus or minus 10 percent. Welded carbon steel tube is produced to closer tolerances (0 to plus 18 percent on minimum wall plus or minus 9 percent on average wall). Tubing of aluminum, copper, and their alloys can be drawn easily and usually is made to minimum wall specifications. 

Corrosion of industrial alloys in alkaline waters is not as common or as severe as attack associated with acidic conditions. Caustic solutions produce little corrosion on steel, stainless steel, cast iron, nickel, and nickel alloys under most cooling water conditions. Ammonia produces wastage and cracking mainly on copper and copper alloys. Most other alloys are not attacked at cooling water temperatures. This is at least in part explained by inherent alloy corrosion behavior and the interaction of specific ions on the metal surface. Further, many dissolved minerals have normal pH solubility and thus deposit at faster rates when pH increases. Precipitated minerals such as phosphates, carbonates, and silicates, for example, tend to reduce corrosion on many alloys. 

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