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Model compound analysis

LOV MOLECULAR WEIGHT MODEL COMPOUNDS. The mechanisms of radiation effects on polymers are frequently investigated by studies of low molecular weight model compounds. Analysis of the chemical reactions is much easier than with high molecular weight polymers. Thus, N-acetyl amino acids can be studied as model compounds for poly(amino acid)s and hence for proteins. [Pg.10]

What both the Chevron study and the SOHIO study indicate is that complete heteroatom removal from whole shale oil will require between 1,800 and 2,000 SCF of hydrogen per barrel of feedstock (13.55 kmol/m3 to 15.06 kmol/m3). What model compound analysis indicates is that hydrotreating of raw shale oil is rather selective, in that only about one-third of the hydrogen consumed is for olefin saturation, saturation of non-hetero aromatics, and hydrocracking. [Pg.294]

X-ray analysis of 2-phenylmethylaraino-5-phenyl-A-2-thiazoline-4-one (176), which exists in the keto form in the solid state (420), and of 4,4 -diacetoxy-5,5 -dimethy]-2,2 bithiazolyl (177) (419) are available as model compounds for theoretical calculations (Scheme 92). [Pg.422]

Polyanilines. Initial preparations of polyaniline (PANI) led to insoluble materials that were difficult to characterize. Use of model compounds and polymers (124,125) allowed for definitive stmctural analysis. Poly( phenylene amineimine) (PPAI) was synthesized directiy to demonstrate that PANI is purely para-linked (126). The synthesis was designed so as to allow linkage through the nitrogen atoms only (eq. 9). Comparison of the properties of PPAI and PANI showed PPAI to be an excellent model both stmcturaHy and electronically. [Pg.38]

Thermogravimetric analysis and other studies made on low-molecular weight model compounds such as 1,3, 5,-trichlorohexane [7,8] corresponding to the idealized head-to-tail structure of PVC show these structures to be considerably more stable than the polymer. This abnormal instability of the polymer is attributed to structural irregularities or defects in the polymer chain, which serve as initiation sites for degradation. [Pg.318]

It seems appropriate to utilize model compounds of relatively low molecular weight, in order for X-ray analysis to provide the highly accurate information on the spatial... [Pg.92]

The model compound 9 was treated with Me3Al under conditions simulating a polymerization experiment (for details see Sect. n.F.l.) and the product was examined by H1 NMR spectroscopy. According to the H1 NMR analysis of spectra obtained before (Fig. 7) and after (Fig. 12) Me l treatment at -50° and 22°, 7 did not change after contact with Me Al. [Pg.22]

The inequality indicates that if a concerted mechanism (where b4 and b2 change simultaneously) gives a Ag which is much lower than our stepwise estimate, we will have smaller Ag< age. This possibility, however, is not supported by detailed calculations (Ref. 6). Direct information about Ag age can be obtained from studies of model compounds where the general acid is covalently linked to the R-O-R molecules. However, the analysis of such experiments is complicated due to the competing catalysis by HaO+ and steric constraints in the model compound. Thus, it is recommended to use the rough estimate of Fig. 6.8. If a better estimate is needed, one should simulate the reaction in different model compounds and adjust the a parameters until the observed rates are reproduced. [Pg.164]

Solid-surface room-temperature phosphorescence (RTF) is a relatively new technique which has been used for organic trace analysis in several fields. However, the fundamental interactions needed for RTF are only partly understood. To clarify some of the interactions required for strong RTF, organic compounds adsorbed on several surfaces are being studied. Fluorescence quantum yield values, phosphorescence quantum yield values, and phosphorescence lifetime values were obtained for model compounds adsorbed on sodiiun acetate-sodium chloride mixtures and on a-cyclodextrin-sodium chloride mixtures. With the data obtained, the triplet formation efficiency and some of the rate constants related to the luminescence processes were calculated. This information clarified several of the interactions responsible for RTF from organic compounds adsorbed on sodium acetate-sodium chloride and a-cyclodextrin-sodium chloride mixtures. Work with silica gel chromatoplates has involved studying the effects of moisture, gases, and various solvents on the fluorescence and phosphorescence intensities. The net result of the study has been to improve the experimental conditions for enhanced sensitivity and selectivity in solid-surface luminescence analysis. [Pg.155]

Vibrational spectroscopy has played a very important role in the development of potential functions for molecular mechanics studies of proteins. Force constants which appear in the energy expressions are heavily parameterized from infrared and Raman studies of small model compounds. One approach to the interpretation of vibrational spectra for biopolymers has been a harmonic analysis whereby spectra are fit by geometry and/or force constant changes. There are a number of reasons for developing other approaches. The consistent force field (CFF) type potentials used in computer simulations are meant to model the motions of the atoms over a large ranee of conformations and, implicitly temperatures, without reparameterization. It is also desirable to develop a formalism for interpreting vibrational spectra which takes into account the variation in the conformations of the chromophore and surroundings which occur due to thermal motions. [Pg.92]

We have developed a compact photocatalytic reactor [1], which enables efficient decomposition of organic carbons in a gas or a liquid phase, incorporating a flexible and light-dispersive wire-net coated with titanium dioxide. Ethylene was selected as a model compound which would rot plants in sealed space when emitted. Effects of the titanium dioxide loading, the ethylene concentration, and the humidity were examined in batches. Kinetic analysis elucidated that the surface reaction of adsorbed ethylene could be regarded as a controlling step under the experimental conditions studied, assuming the competitive adsorption of ethylene and water molecules on the same active site. [Pg.241]

The surface analyses of the Co/MgO catalyst for the steam reforming of naphthalene as a model compound of biomass tar were performed by TEM-EDS and XPS measurements. From TEM-EDS analysis, it was found that Co was supported on MgO not as particles but covering its surface in the case of 12 wt.% Co/MgO calcined at 873 K followed by reduction. XPS analysis results showed the existence of cobalt oxide on reduced catalyst, indicating that the reduction of Co/MgO by H2 was incomplete. In the steam reforming of naphthalene, film-like carbon and pyrolytic carbon were found to be deposited on the surface of catalyst by means of TPO and TEM-EDS analyses. [Pg.517]

And finally, we may mention that a statistical analysis of the sulfur d orbital problem has been carried out with dimethyl sulfoxide as a model compound . The results provide a clear answer to the sulfur d orbital problem, since no simultaneous reproduction of experimental geometry and an adequate approximation to the variationally optimum total energy have been possible without including d polarization functions on sulfur . [Pg.493]

We shall return to the discussion of the orientation and electronic structure of the dioxygen ligand during the next section which is primarily concerned with recent advances in the synthesis and physical characterization (particularly X-ray analysis) of oxygencarrying metal porphyrin model compounds. [Pg.36]

Local surface structure and coordination numbers of neighbouring atoms can be extracted from the analysis of extended X-ray absorption fine structures (EXAFS). The essential feature of the method22 is the excitation of a core-hole by monoenergetic photons modulation of the absorption cross-section with energy above the excitation threshold provides information on the distances between neighbouring atoms. A more surface-sensitive version (SEXAFS) monitors the photoemitted or Auger electrons, where the electron escape depth is small ( 1 nm) and discriminates in favour of surface atoms over those within the bulk solid. Model compounds, where bond distances and atomic environments are known, are required as standards. [Pg.18]

For samples that meet the solubility requirements of the SEC approach, analyses were also reported for additives in polymers such as PVC and PS [28,29]. Direct SEC analysis of PVC additives such as plasticisers and thermal stabilisers in dissolution mode has been described [28,30,31 ]. In the analysis of a dissolved PS sample using a SEC column of narrow pore size, the group of additives was separated on a normal-phase column after elution of the polymer peak [21]. Column-loading capacity of HPSEC for the analysis of additives, their degradation products and any other low-MW compounds present in plastics has been evaluated for PS/HMBT, PVC/TNPP and PVC/TETO (glyceryl tri[l-14C] epoxyoleate) [31]. It was shown that HPSEC can be used to separate low-MW compounds from relatively large amounts of polymers without serious loss of resolution of the additives the technique has also been used for the group analysis of chlorohydrin transformation products of the TETO model compound [32]. [Pg.694]

The NMR and infrared spectra of the derivatized model compounds are useful In establishing the structures and the D.F. of the modified polymers. Careful assignment of all peaks in the 13C-NMR spectra for each of structures 7-13 confirms the regioselectivity of the substitution on the oxyphenyl unit and inertness of the phenyl sulfone units. The chemical shifts of the key carbons for the analysis, those of the oxyphenyl rings, are summarized in Table I. [Pg.14]


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See also in sourсe #XX -- [ Pg.284 ]




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