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Mixing models physical

As will be shown for the CD model, early mixing models used stochastic jump processes to describe turbulent scalar mixing. However, since the mixing model is supposed to mimic molecular diffusion, which is continuous in space and time, jumping in composition space is inherently unphysical. The flame-sheet example (Norris and Pope 1991 Norris and Pope 1995) provides the best illustration of what can go wrong with non-local mixing models. For this example, a one-step reaction is described in terms of a reaction-progress variable Y and the mixture fraction p, and the reaction rate is localized near the stoichiometric point. In Fig. 6.3, the reaction zone is the box below the flame-sheet lines in the upper left-hand corner. In physical space, the points with p = 0 are initially assumed to be separated from the points with p = 1 by a thin flame sheet centered at... [Pg.287]

Based on the above examples, we can conclude that while localness is a desirable property, it is not sufficient for ensuring physically realistic predictions. Indeed, a key ingredient that is missing in all mixing models described thus far (except the FP and EMST70 models) is a description of the conditional joint scalar dissipation rates (e ) and their dependence on the chemical source term. For example, from the theory of premixed turbulent flames, we can expect that (eY F, f) will be strongly dependent on the chemical... [Pg.289]

One of the simplest estimation techniques is to use a kernel function hw(x) (see, for example, (6.206), p. 301). However, care must be taken in choosing the form of the kernel function in order to ensure that desirable physical constraints are not violated. For example, with unit-weight particles, the requirement that the mixing model in (7.28)... [Pg.367]

With this exception we can see that the impact of the configuration mixing model on nucleophilic substitution reactions, which constitute the most widely studied organic reaction, is indeed extensive. The model readily rationalizes much available experimental data, relates the entire mechanistic spectrum within a single framework, challenges some fundamental precepts of physical organic chemistry and enables one to make reactivity predictions about reactions yet to be investigated. For such a simple, qualitative theory, this is no mean achievement. [Pg.161]

Every ozonation process where gaseous ozone is transferred into the liquid phase and where it subsequently reacts, involves physical and chemical processes which need to be considered in modeling. Physical processes include mass transfer and hydrodynamic properties of the reaction system, e. g. gas- and liquid-phase mixing. Chemical processes include, ideally, all direct and/or indirect reactions of ozone with water constituents. Of course these processes cannot be seen independently. For example, fast reactions can enhance mass transfer. [Pg.127]

Physical transport processes and mixing ratio. The concentration profile of a minor constituent in an atmosphere is often expressed as a mixing ratio by volume or a mole fraction rather than the concentration by atmospheric modelers. Physical transport processes involve vertical and horizontal mixing by turbulence and molecular diffusion. The molecular diffusion process can be ignored in the stratosphere since it is important only above about 40 km. [Pg.256]

Vilchis et al. [81] presented a new idea to achieve better control of the particle size distribution by the synthesis in situ of a water-soluble copolymer of acrylic acid-styrene as suspension stabilizer without additional inorganic phosphate. Publications describe increasing the particle formation by using a physical (population balance, Maxwell fluid, power law viscosity, compartment mixing) modeling approach [22,60,98,105]. [Pg.177]

Our present understanding of mixing and UVR effects has been limited by both the availability of physical measurements and the oversimplified representation of mixing processes in experiments and analyses. This is expected to change in the future as it becomes more practical to incorporate mixing measurements into field work, and as experimental exposures and mixing models become more sophisticated and allow a better approximation of actual water column conditions. [Pg.109]

Physical properties for all flows are inputted. The user must specify certain parameters such as mixing models, kinetic rates, turbulence, and others as required. The CFD model is generally full-scale with complete similitude. The governing differential equations that solve all aspects of mixing, heat transfer, chemistry, turbulence, fluid mechanics, species, and continuity are iterated across the entire model until a converged solution is obtained for all cells and boundary conditions. [Pg.520]

Although instrumentation capabilities are continually improving, the limitation of experimental modeling that dynamic similarity can not be obtained is absolute, imposed by the physics of the system. However, computational modeling is continually improving and is indeed the great hope for future comprehensive crystallizer mixing models. [Pg.194]

The coupling of photochemistry and physical mixing in a model is a challenging task for three reasons. First, the photochemical production and decomposition rates, as well as the dark decay rates of Interest, are often poor estimates. This Is both because of the lack of good laboratory kinetic measurements and because the light attenuation models Into which such measurements are Incorporated are subject to additional uncertainties. Second, the one-dlmenslonal mixing models make certain assumptions and... [Pg.264]

Virtual prototypes are defined as a computer-based simulation of a technical system or subsystem with a degree of functional behavior that is comparable to corresponding physical prototypes. The visualization of virtual prototypes calls for the processing of the data in dependence on the visualization techniques. Apart from purely realistic visualization, complexity-reducing models and symbohc visualization are used as well. Mixed models of both methods are widespread. [Pg.2501]


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