Physical mixing

Smelt/Smelting. Any metallurgical operation in which metal is separated by fusion from those impurities with which it may be chemically combined or physically mixed, such as in ores. 

Internal surfactant antistats ate physically mixed with the plastic resin prior to processing. When the resin is melted, the antistat distributes evenly in the polymer matrix. The antistat usually has some degree of solubiUty in the molten polymer. However, when the polymer is processed (extmded, molded, etc) into its final form and allowed to cool, the antistat migrates to the surface of the finished article due to its limited solubiUty in the solidified resin. The molecule of a surface-active agent is composed of a polar hydrophilic portion and a nonpolar hydrophobic portion. The hydrophilic portion of the surfactant at the surface attracts moisture from the atmosphere it is the moisture that has the static dissipative effect. 

Two or more soHd catalyst components can be mixed to produce a composite that functions as a supported catalyst. The ingredients may be mixed as wet or dry powders and pressed into tablets, roUed into spheres, or pelletized, and then activated. The promoted potassium ferrite catalysts used to dehydrogenate ethylbenzene in the manufacture of styrene or to dehydrogenate butanes in the manufacture of butenes are examples of catalysts manufactured by pelletization and calcination of physically mixed soHd components. In this case a potassium salt, iron oxide, and other ingredients are mixed, extmded, and calcined to produce the iron oxide-supported potassium ferrite catalyst. 

Blends with PVC. Nitrile mbber may be blended with poly(vinyl chloride) (PVC) by the polymer producer by two different techniques (1) blending of NBR latex with PVC latex followed by co-coagulation and drying, or (2) physically mixing the soHd NBR and PVC powder in mixing equipment such as an internal mixer. NBR—PVC polymer blends are well known for the good ozone resistance that is imparted by the PVC. 

B.S. Uphade, M. Okumura, S. Tsubota, and M. Haruta, Effect of physical mixing of CsCl with Au/Ti-MCM-41 on the gas-phase epoxidation of propene using H2 and02 Drastic depression of H2 consumption, Appl. Catal. A 190, 43-50 (2000). 

Another widely used concept is that of a planetary boundary layer (PBL) in contact with the surface of the Earth above which lies the "free atmosphere." This PBL is to some degree a physically mixed layer due to the effects of shear-induced turbulence and convective overturning near the Earth s surface. 

Fig. 2. UV-VISdiffiise reflectance sp>ectra of (a) TiO2-400°C, (b) CdS-IPA-800 C, (c) CdS-Ti02, (d) CdS-Ti02 physically mixed (PM).

The Ni based anode catalysts were prepared by a physical mixing method. NiO (99.99%, Sigma-Aldrich Co.), YSZ (TZ-8Y, TOSOH Co.), MgO (98%, Nakarai Chemical Co.) and Ce02 (99.9%, Sigma-Aldrich Co.) were used as raw materials. The physically mixed catalyst... 

The synthesis of bimetallic nanoparticles is mainly divided into two methods, i.e., chemical and physical method, or bottom-up and top-down method. The chemical method involves (1) simultaneous or co-reduction, (2) successive or two-stepped reduction of two kinds of metal ions, and (3) self-organization of bimetallic nanoparticle by physically mixing two kinds of already-prepared monometallic nanoparticles with or without after-treatments. Bimetallic nanoparticle alloys are prepared usually by the simultaneous reduction while bimetallic nanoparticles with core/shell structures are prepared usually by the successive reduction. In the preparation of bimetallic nanoparticles, one of the most interesting aspects is a core/shell structure. The surface element plays an important role in the functions of metal nanoparticles like catal5dic and optical properties, but these properties can be tuned by addition of the second element which may be located on the surface or in the center of the particles adjacent to the surface element. So, we would like to use following marks to inscribe the bimetallic nanoparticles composed of metal 1, Mi and metal 2, M2. 

In summary, two kinds of monometallic nanoparticles with smaller particle sizes easily form bimetallic nanoparticles by the physical mixing. The monometallic nanoparticles with stronger interaction also have a trend to form the bimetallic nanoparticles by the mixing. This kind of chemistry between nanoparticles is now becoming open to human beings. 

We investigated on structure of CuPd (2 1) bimetallic nanoparticles by XRD [71]. Since the XRD peaks of the PVP-protected CuPd nanoparticles appeared between the corresponding diffraction lines of Cu and Pd nanoparticles, as shown in Figru e 11, the bimetallic alloy phase was clearly formd to be formed in CuPd (2 1) bimetallic nanoparticles. We also characterized Ag-core/Rh-shell bimetallic nanoparticles, which formed during simple physical mixing of the corresponding monometallic ones, by XRD coupled with TEM [148]. 

Effect of Ruthenium Loading Two ruthenium concentrations (0.5% and 1.5%) were used to study the effect of ruthenium loading on syngas conversion over physically mixed Ru/Al-O-//ZSM-5 catalysts. The results are shown in Table II. The formation of C +C2 was greatly reduced from 40% w th 1.5% Ru to 25% with 0. % Ru. On the other hand, the higher ruthenium loading gave a coproduct of reduced end point (Ex. 2A and 2B). As expected, no difference in aromatics production was observed. 

Reynolds, C. S. (1994). The long, the short and the stalled - on the attributes of phytoplankton selected by physical mixing in lakes and rivers, Hydrobiologia, 289, 9-21. 

The CVD catalyst exhibits good catalytic performance for the selective oxidation/ammoxida-tion of propene as shown in Table 8.5. Propene is converted selectively to acrolein (major) and acrylonitrile (minor) in the presence of NH3, whereas cracking to CxHy and complete oxidation to C02 proceeds under the propene+02 reaction conditions without NH3. The difference is obvious. HZ has no catalytic activity for the selective oxidation. A conventional impregnation Re/HZ catalyst and a physically mixed Re/HZ catalyst are not selective for the reaction (Table 8.5). Note that NH3 opened a reaction path to convert propene to acrolein. Catalysts prepared by impregnation and physical mixing methods also catalyzed the reaction but the selectivity was much lower than that for the CVD catalyst. Other zeolites are much less effective as supports for ReOx species in the selective oxidation because active Re clusters cannot be produced effectively in the pores of those zeolites, probably owing to its inappropriate pore structure and acidity. 

Table 8.5 Performance of ReOx/Zeolite Catalysts in Selective Oxidation/Ammoxidation of Propene on a CVD HZcvd Catalyst, an Impregnated HZimp Catalyst, and a Physically Mixed HZphys Catalyst at 673 K...

Carpenter, M. D., Gierke, J. S., et al., 1993, Vapor Phase Transport in Physically-Mixed Clay Soils In Proceedings of the 1993 Petroleum Hydrocarbons and Organic Chemicals in Ground Water Prevention, Detection and Restoration. American Petroleum Institute and National Ground Water Association, November 10-12, pp. 479-489. 

Mixtures These materials are characterized by introducing nanoscale size materials into the polymeric matrix only by physical mixing. Here the nanomaterials are usually in a state of agglomeration. In this case, the nanomaterials are in a weight content less than 10 %. 

Bioturbation The physical mixing of sediments caused by the burrowing and feeding activities of benthic organisms. 

Table 10.6 shows the catalytic performances of the selective benzene oxidation on the zeolite-supported Re catalysts under steady-state reaction conditions [107]. Catalyhc activity and selectivity largely depended on the types of zeolites and the preparation methods. The Re catalysts prepared by CVD of MTO exhibited higher catalyhc achvity and phenol selechvity than those prepared by the convenhonal impregnation method as supports (Table 10.6). Physical mixing of MTO with the supports provided poor phenol synthesis.

---