Microscopic high temperatures

Intervention of localized microscopic high temperatures is possible [8, 14, 24], as advocated in sonochemistry to justify the sonochemical effect. There is an inevitable lack of experimental evidence, because we can necessarily have access to macroscopic temperature only. It has been suggested [6, 19] that, in some examples, MW activation could originate from hot spots generated by dielectric relaxation on a molecular scale. 

Steel alloyed with 1% A1 is more resistant to oxidation at high temperatures. The macro- and microscopic homogeneity of the distribution of all elements is better for powder metallurgical, hot isostatically pressed steels. Combining these advantages should result in better performance of high-speed steels. 

The solidity of gel electrolytes results from chain entanglements. At high temperatures they flow like liquids, but on cooling they show a small increase in the shear modulus at temperatures well above T. This is the liquid-to-rubber transition. The values of shear modulus and viscosity for rubbery solids are considerably lower than those for glass forming liquids at an equivalent structural relaxation time. The local or microscopic viscosity relaxation time of the rubbery material, which is reflected in the 7], obeys a VTF equation with a pre-exponential factor equivalent to that for small-molecule liquids. Above the liquid-to-rubber transition, the VTF equation is also obeyed but the pre-exponential term for viscosity is much larger than is typical for small-molecule liquids and is dependent on the polymer molecular weight. 

In the high-temperature limit microscopic calculation [186] led to a formula quadratic in scattering phases ... 

FTIR instrumentation is mature. A typical routine mid-IR spectrometer has KBr optics, best resolution of around 1cm-1, and a room temperature DTGS detector. Noise levels below 0.1 % T peak-to-peak can be achieved in a few seconds. The sample compartment will accommodate a variety of sampling accessories such as those for ATR (attenuated total reflection) and diffuse reflection. At present, IR spectra can be obtained with fast and very fast FTIR interferometers with microscopes, in reflection and microreflection, in diffusion, at very low or very high temperatures, in dilute solutions, etc. Hyphenated IR techniques such as PyFTIR, TG-FTIR, GC-FTIR, HPLC-FTIR and SEC-FTIR (Chapter 7) can simplify many problems and streamline the selection process by doing multiple analyses with one sampling. Solvent absorbance limits flow-through IR spectroscopy cells so as to make them impractical for polymer analysis. Advanced FTIR... 

The question arises of the extent to which, in polycrystalline films reactant gas has access to the substrate. It is clear that in high-temperature films the total absence of intercrystal gaps means that such access of gas is completely absent. In the case of films deposited at 0°C, one may estimate from the measured roughness factor and from transmission electron microscopic evidence that, of the total substrate area, more than 90% is in direct contact with metal in any case, the substrate at the base of a gap is almost certainly covered with a thin layer of metal. Thus, even in this case the gas cannot have more than trivial access to the substrate. 

In the paramagnetic regime, the evolution of the EPR line width and g value show the presence of two transitions, observed at 142 and 61 K in the Mo salt, and at 222 and 46 K in the W salt. Based on detailed X-ray diffraction experiments performed on the Mo salt, the high temperature transition has been attributed to a structural second-order phase transition to a triclinic unit cell with apparition of a superstructure with a modulation vector q = (0,1/2, 1/2). Because of a twinning of the crystals at this transition, it has not been possible to determine the microscopic features of the transition, which is probably associated to an ordering of the anions, which are disordered at room temperature, an original feature for such centrosymmetric anions. This superstructure remains present down to the Neel... 

The VLS mechanism was confirmed at the nanometer scale by direct, in situ observation of nano-wire growth in a transmission electron microscope at high temperatures. Wu, Y. Yang, P. J. Am. Chem. Soc. 2001, 123, 3165. 

There has also been work with hydrogen storage in buckyballs or carbon nanotubes. These are microscopic structures fashioned out of carbon. This research indicates a potential storage technique using a combination of chemical and physical containment at very high temperature... 

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