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Micellar techniques

Applicability of CZE to the Edman phenylthiohydantion derivatives of amino acids (140) is limited because the neutral amino acids cannot be resolved by this method and by the reduced thickness of the sample requiring relatively high concentrations of the fluorescent material for detection. These limitations may be overcome by a micellar technique that confers mobility to neutral 140 species and by application of thermotropic detection that allows one to detect a few tens of fmol of the derivative, obtained after injecting ca 0.5 nL, at a concentration of ca 1 p-M330. [Pg.1096]

The successful implementation of the biphasic oxo process as the prototype of a homogeneous aqueous catalyst system will have different consequences for hydro-formylation reactions as described in Chapter 3 (development of new ligands) and Chapter 4 (solvents, co-solvents, micellar techniques) and Section 6.1.3.2. [Pg.359]

The interfacial technique differs from the micellar technique in that the dispersed phase is much larger and has a much greater capacity for holding the reactant(s). Coalescence of the dispersed phase occurs spontaneously on standing, making phase separation and catalyst recovery easier. [Pg.175]

Due to its petrophysical characteristics, the Chateaurenard field is well adapted to the chemical recovery techniques. Four pilot tests have been run in this field, two micellar-polymer tests (1, 2) and two straight polymer tests (3, 4, 5). All pilots were technical successes but it appeared that large scale straight polymer injection may be economical whereas the micellar technique is too costly (7). [Pg.318]

The polymer polymerized by the micellar technique (surfactant polymer) contained 0.25 mole% APS, while the solution polymerized (solution polymer, DMF/H2O 57 43 volume fraction) polymer contained 0.35mole%. Steady-state emission spectra of the two polymers, shown in Fig. 2.13, indicated that at constant polymer concentration, Ie/Im was higher for the surfactant polymer even though it contained less of the pyrene-sulfonamide label. This was indicative of a higher local label concentration in the surfactant polymer and thus a blocky copolymer microstructure. [Pg.26]

On the other hand, zirconia is an interesting material to be used as catalyst support due to its thermal stability in different atmospheres. The most common methods that can be used to obtain zirconia are the sol-gel method, the micellar technique or the mechanochemical synthesis [3]. Zirconia is frequently prepared by micellar method, while the sol-gel method from an alkoxide is less used [4]. Its acid properties can be modified by addition of cationic or anionic substances, such as sulfate or tungstate [5]. [Pg.405]

The potentiometric titration with n-bntylamine indicated that the catalysts present very strong acid sites with potential between 100 and 700 mV. Ei valnes were in the range 700-650 mV, nearly independent of Nth, and the number of acid sites decreased with the thermal treatment temperature in an almost linear relation with the Nt decrease. The acidity of the supports is higher than that of a zirconia obtained by micellar technique from zirconium oxychloride and ammonia [8], which present very weak sites. [Pg.408]

The pur pose of work is to develop the technique of separ ation of purine bases (caffeine, theophylline, theobromine) and the technique of detection of purine bases in biological fluid by TLC using micellar mobile phases containing of different surfactants. [Pg.350]

Electrodriven Separation Techniques encompass a wide range of analytical procedures based on several distinct physical and chemical principles, usually acting together to perform the requh ed separation. Example of electrophoretic-based techniques includes capillary zone electrophoresis (CZE), capillary isotachophoresis (CITP), and capillary gel electrophoresis (CGE) (45-47). Some other electrodriven separation techniques are based not only on electrophoretic principles but rather on chromatographic principles as well. Examples of the latter are micellar... [Pg.143]

Ultrafiltration of micellar solutions combines the high permeate flows commonly found in ultrafiltration systems with the possibility of removing molecules independent of their size, since micelles can specifically solubilize or bind low molecular weight components. Characteristics of this separation technique, known as micellar-enhanced ultrafiltration (MEUF), are that micelles bind specific compounds and subsequent ultrafiltration separates the surrounding aqueous phase from the micelles [70]. The pore size of the UF membrane must be chosen such, that the micelles are retained but the unbound components can pass the membrane freely. Alternatively, proteins such as BSA have been used in stead of micelles to obtain similar enan-tioselective aggregates [71]. [Pg.145]

The effects of pH on electrokinetic velocities in micellar electrokinetic chromatography was studied by using sodium dodecyl sulfate solutions [179]. Micellar electrokinetic capillary chromatography with a sodium dodecyl sulfate pseudostationary phase has been used to determine the partition constants for nitrophenols, thiazolylazo dyes, and metal chelate compounds [180]. A similar technique was used to separate hydroquinone and some of its ether derivatives. This analysis is suitable for the determination of hydroquinone in skin-toning creams [181]. The ingredients of antipyretic analgesic preparations have also been determined by this technique [182], The addition of sodium dodecyl sulfate improves the peak shapes and resolution in chiral separations by micellar electrokinetic chromatography [183]. [Pg.274]

Flocculation values achieved from turbidity measurements using the light scattering technique showed improvement with nonylphenol ether carboxylic acid (4 mol EO) in particular. The oil solubilization rate has been found to be proportional to the surfactant micellar size [190]. [Pg.343]

By flourescence techniques, it was observed that the fluorescence yield and lifetime of 1,8-anilinonaphthalenesulfonate decrease with an increase in the aqueous core of AOT-reversed micelles, while the position of the emission maximum shifts to longer wavelengths [64], These changes in the electronic properties were attributed to the peculiar effective polarity and viscosity of the micellar core and to their evolution with R. [Pg.487]

CE was recently used for anthocyanin analysis because of its excellent resolution. This technique has different modes capillary zone electrophoresis (CZE), capillary gel electrophoresis (CGE), micellar electrokinetic chromatography (MEKC), capillary electrochromatography (CEC), capillary isoelectric focusing (CIEE), and capillary isotachophoresis (CITP)."° CZE is the most popular method for anthocyanin... [Pg.489]

Recently a new method was developed for the complete liquid chromatographic separation and diode array detection of standard mixtures of the 14 most frequently used synthetic colorants. Protocols for RP-HPLC - " and IP-HPLC techniques have been extensively described and the techniques were compared with micellar electrokinetic capillary chromatography, - which has been shown to be suitable for the analysis of synthetic colorants. [Pg.542]

With the development of new instrumental techniques, much new information on the size and shape of aqueous micelles has become available. The inceptive description of the micelle as a spherical agglomerate of 20-100 monomers, 12-30 in radius (JJ, with a liquid hydrocarbon interior, has been considerably refined in recent years by spectroscopic (e.g. nmr, fluorescence decay, quasielastic light-scattering), hydrodynamic (e.g. viscometry, centrifugation) and classical light-scattering and osmometry studies. From these investigations have developed plausible descriptions of the thermodynamic and kinetic states of micellar micro-environments, as well as an appreciation of the plurality of micelle size and shape. [Pg.225]

MEKC is a CE mode based on the partitioning of compounds between an aqueous and a micellar phase. This analytical technique combines CE as well as LC features and enables the separation of neutral compounds. The buffer solution consists of an aqueous solution containing micelles as a pseudo-stationary phase. The composition and nature of the pseudo-stationary phase can be adjusted but sodium dodecyl sulfate (SDS) remains the most widely used surfactant. [Pg.348]


See other pages where Micellar techniques is mentioned: [Pg.1096]    [Pg.426]    [Pg.169]    [Pg.174]    [Pg.83]    [Pg.1096]    [Pg.426]    [Pg.169]    [Pg.174]    [Pg.83]    [Pg.126]    [Pg.134]    [Pg.145]    [Pg.145]    [Pg.350]    [Pg.411]    [Pg.259]    [Pg.119]    [Pg.316]    [Pg.147]    [Pg.463]    [Pg.543]    [Pg.226]    [Pg.50]    [Pg.109]    [Pg.744]    [Pg.484]    [Pg.386]    [Pg.274]    [Pg.274]    [Pg.677]    [Pg.706]   
See also in sourсe #XX -- [ Pg.1096 , Pg.1097 ]




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