2-Methyl-p-anisidine

METHYLANILINE HYDROCHLORIDE see TGS500 2-METHYL-p-ANISIDINE see MG0500... 

Goto et al. (2004) measured the reaction kinetics of one-electron oxidation of A -methyl-p-anisidine in AN. In the electrode process, oxidation was performed at the platinum disk-shaped anode, in the chemical process, by means of the tris(p-bromophenyl)amine cation-radical. In both the cases, after one-electron oxidation, dimerization took place leading to the formation of the dye variamine blue. According to the kinetic data, the mechanism of this dye formation is different in the electrode and chemical processes (see Scheme 2.34). Namely, in the electrode oxidation, the cation-radical appears to be surrounded by a huge amount of the initial (nonoxidized) A-methyl-p-anisidine... 

N, JV-Dimethyl-2-nitro-p -toluidine N, JV-Dimethyl-2-nitro-p -anisidine A,jV-E>iethyl-3-nitroaniline A -Dimethyl-d-nitrosoaniline A -Dimethyl-d-nitroaniline A,A-I)iethyl-4-nitroaniline N, A-Diethyl-3-methyl-4-nitro aniline N,N, 3,5-Tetramethyl-4-nitroaniline 4-N,N -Dimethylaminobenzophenone Ethyl 4-Ar,iV-dimethylaminobenzoate 4-(Ar,Ar-Dimethylamino)-/S-nitrostyrene 4-(jV,jV-Dimethylamino)benzaldehyde... 

Methylaminoacetaldehyde dimethyl acetal, d508 a-(l-Methylaminoethyl)benzyl alcohol, e2 Methylanilines, tl80 thru tl82 Methyl oanisate, m304 Methyl p-anisate, m305 2-Methyl-/ -anisidine, m80... 

Amresco acryl-40, see Acrylamide AMS, see a-Methylstyrene n-Amyl acetate, see Amyl acetate Amyl acetic ester, see Amyl acetate Amyl acetic ether, see Amyl acetate Amylene, see 1-Pentene a-n-Amylene, see 1-Pentene p-n-Amylene, see cis-2-Pentene cis-p-Amylene, see cis-2-Pentene frans-p-Amylene, see trans-2-Venlene sec-Amyl ethanoate, see Amyl acetate Amyl ethyl ketone, see 5-Methyl-3-heptanone Amyl hydride, see Pentane Amyl methyl ketone, see 2-Heptanone n-Amyl methyl ketone, see 2-Heptanone AN, see Acrylonitrile Anaesthetic ether, see Ethyl ether Anamenth, see Trichloroethylene Anduron, see Diuron Anesthenyl, see Methylal Anesthesia ether, see Ethyl ether Anesthetic ether, see Ethyl ether Anhydrous ammonia, see Ammonia Aniline oil, see Aniline Anilinobenzene, see 4-Aminobiphenyl Anilinomethane, see Methylaniline 2-Anidine, see o-Anisidine 4-Anisidine, see p-Anisidine 2-Anisylamine, see o-Anisidine... 

Methoxyaniline, see o-Anisidine p-Methoxyaniline, see p-Anisidine 2-Methoxybenzenamine, see o-Anisidine 4-Methoxybenzenamine, see p-Anisidine p-Methoxybenzenamine, see p-Anisidine Methoxycarbonylethene, see Methyl acrylate Methoxycarbonylethylene, see Methyl acrylate 2-Methoxycarbonyl-l-methylvinyl dimethyl phosphate, see... 

Methoxyethanol, see Methyl cellosolve 2-Methoxyethanol acetate, see Methyl cellosolve acetate 2-Methoxyethyl acetate, see Methyl cellosolve acetate 2-Methoxyethyl alcohol, see Methyl cellosolve 2-Methoxyethyl ethanoate, see Methyl cellosolve acetate Methoxyhydroxyethane, see Methyl cellosolve Methoxymethyl methyl ether, see Methylal 4-Methoxyphenylamine, see p-Anisidine... 

Methoxyphenylamine, see o-Anisidine p-Methoxyphenylamine, see p-Anisidine Methyl acetone, see 2-Butanone Methyl acetylene, see Propyne p-Methylacrolein, see Crotonaldehyde Methyl alcohol, see Methanol... 

Many amides have been prepared from pyrazinecarboxylic acid chlorides some are listed below with the relevant amines and references 2-chlorocarbonyl [MeNHj/ EtOAc (138) Me NH/EtOAc (138) BujNH etc/EtOAc (138) aniline/EtOAc (138, 1335) other aromatic and heterocyclic amines/EtOAc (138) sulfanilamide/ pyridine (1336) p-(2 -aminoethyl)benzenesulfonamide (1385) p-anisidine/benzene (1334) 4-hydroxypiperidine/benzene chloroform (1386) morpholine/DMF/20° (1387) 2-aminopyrimidine/benzene (1388) glycine/NaOH/ether (1201, cf. 1333, 1360)] 2-chlorocarbonyl-5-methyl [MeNHj/benzene (1337) MejNH/benzene (1337) 4-phenylpiperazine or diethanolamine/benzene-chloroform (1386) 2-chlorocarbonyl-3-phenyl (6-aminopenicillanic acid) (1024) 2-chloro-3-chloro-carbonyl (morpholine/benzene) (838) 2-chloro-5-chlorocarbonyl (NH4OH) (839) 2-chloro-6-chlorocarbonyl (Et2NH/benzene) (870, 1389) 2-chlorocarbonyl-5-hydroxy (aniline/benzene) (1055) 2-chlorocarbonyl-3-methoxy (morpholine/ benzene) (867) 2-chlorocarbonyl-5-methoxy (morpholine/benzene-chloroform) (1386) and 2-(l -chlorocarbonylethyI) (morpholine/benzene) (364). 

FIGURE 11.16 Electrophorogram for a standard solution of aromatic amines. Peaks 1, pyridine 2, /7-phenylenediamine 3, benzidine 4, o-toluidine 5, aniline 6, A/,A -dimethylaniline 7, p-anisidine 8, /7-chloroaniline 9, m-chloroaniline 10, ethylaniline 11, a-naphthylamine 12, diethyl-aniline 13, A -(l-naphthyl)ethylenediamine 14, 4-aminophenazone 15, o-chloroaniline 16, 3,4-dichloroani-line 17, 3,3 -dichlorobenzidine 18, 2-methyl-3-nitroaniline 19, 2,4-dichloroaniline 20, 2,3-dichloroaniline 21, 2,5-dichloroaniline. (From Cavallaro, A., Piangerelli, V., Nerini, F., Cavalli, S., and Reschiotto, C., J. Chromatogr., 709, 361-366, 1995.)... 

Methyl-o-anisidine (2-methoxy-5-methyl benzenamine, p-cresidine, 2-methoxy-5-methylaniline, 3 - amino -4-methoxy toluene) [120-71-8]... 

Anisic acid, methyl ester [Benzoic acid, 4-methoxy-, methyl ester], 55,40,41 o-Anisidine (Benzenamine, 2-raethoxy-], p-bromination of, 55,23 [10]ANNULENE,[11-Oxabicyclo[4.4.1]-undeca-l,3,5,7,9-pentaene], 55, 86 Anthranilic acid [Benzoic acid, 2-amino-], p-bromination of, 55, 23 Apparatus, distillation of benzocyclopro-pene for, 55,13... 

The same author [63] reported the synthesis of 1 (3-methylcarbapenem intermediates such as 111 (Scheme 16), employing chiral imines prepared from (S)-methyl 3-hydroxy-2-methylpropionaldehyde and p-anisidine or DAM-NH2. The reaction of diketene 98 with these imines in the presence of imidazole produced a diastereomeric mixture of P-lactams 107 and 108 in a variable ratio. These authors found that the best results in terms of chemical yield and stereoselectivity could be obtained when the [2 + 2] cycloaddition reaction was performed on imines derived from DAM-NH2 toluene as solvent and using 4-methylimidazole instead of imidazole. Under these conditions the P-lactam 108b was obtained in 49% yield and the ratio of isomers 107b/108b was 1 15. 

Cl 37100. See 2-Methyl-4-nitroaniline Cl 37105. See 2-Methyl-5-nitroaniline Cl 37107. See p-Toluidine Cl 37110. See 3-Nitro-p-toluidine Cl 37115. See o-Anisidine hydrochloride Cl 37130. See 2-Methoxy-5-nitroaniline Cl 37225. See Benzidine Cl 37230. See o-Tolidine Cl 37235. See Dianisidine Cl 37240. See N-Phenyl-p-phenylenediamine Cl 37500. See P-Naphthol Cl 40000. See Direct yellow 11 Cl 40002 Cl 40003. See 4,4 -Diaminostilbene-2,2 -disulfonic acid Cl 40645. See Sodium-2-(4-styrvl-3-sulfophenyl)-2H-naphtho-(1,2-d)-triazole Cl 40800... 

N-(Methoxy (methylthio) phosphinoyl) acetamide. SeeAcephate 2-Methoxynaphthalene P-Methoxynaphthalene. See P-Naphthyl methyl ether 2-Methoxy-5-nitroaniline CAS 99-59-2 EINECS/ELINCS 202-770-5 Synonyms 2-Amino-1-methoxy-4-nitrobenzene 3-Amino-4-methoxynitrobenzene 2-Amino-4-nitroanisole Aniline, 2-methoxy-5-nitro- o-Anisidine nitrate... 

Methyl-o-anisidine. See p-Cresidine 2-Methylanisole. See o-Methylanisole 4-Methylanisole. See p-Methylanisole o-Methylanisole... 

The acidic periodate oxidations of p-anisidine to 4-methoxy-l,2-benzoquinone, A,Al-diethyl-m-toluidine to methyl-1,4-benzoquinone, Mn(II)-catalysed oxidation of Al-methyl aniline to p-benzoquinone, and 3-chloro-2-methylaniline to 2-chloro-3-methyl-l,4-benzoquinone were studied in acetone/water medium. The reactions were first order in 104 and substrates, the rates increased with increasing ionic strength and dielectric constant, and the plot of 1/ 2 versus [H+] passed through a minimum. 

The reducing methylated sugars are detected by the same reagents used for paper chromatograms such as aniline phthalate (No. 10), p-anisidine phthalate (No. 12), 2,3,5-triphenyltetrazolium chloride (No. 255), alkaline silver nitrate (No. 234) and, in addition, the sulfuric acid sprays and iodine vapor. Brief exposure to iodine vapor does not cause a detectable destruction of the methyl ethers of the sugars [83] and is therefore a convenient method for visualizing the components on preparative plates [73] or for quantitative analysis. 

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