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Methyl aniline

Mit Lithiumalanat/Aluminiumchlorid gelingen die Hydrogenolysen unter sehr milden Bedingungen so erhalt man z. B. aus 2-Amino-benzoesaure in Diathylather 50% d.Th. 2-Methyl-anilin (weiteres s. S. 220, 287f.)2. [Pg.171]

Fuchs K, A Schreiner, F Lingens (1991) Degradation of 2-methylaniline and chlorinated isomers of 2-methyl-aniline by Rhodococcus rhodochrous strain CTM. J Gen Microbiol 137 2033-2039. [Pg.491]

Das relative Oxidationsvermogen aromatischer Persauren gegenuber 2-Methyl-anilin wur-de eingehend untersucht2. [Pg.67]

NOi fV " Ha/lrnns-Pd(py)2Cl2/C2HsOH Normaldruck 30 6 h 2-Methyl-anilin (+ Bis- 2-methyl-phenyQ-diazen) 90 [+3,5] 8... [Pg.826]

H2/Amberlite-gebundencr 2-(Benzyl-amino benzoesaure-PdClj-Kom- plex /C2U5OH 4200 kPa 100° 4 h 2-Methyl-anilin (88) 10... [Pg.826]

HsC6-CH2-OH (Uberschull)/Kon 1. Zugabe bci 170° Wasser wird ab-destilliert 2. RiickfluB bei 250° 90 min N-Benzyl-2-methyl-anilin 51 6... [Pg.827]

Paraffin (Sdp. 360-400°) Edukt langsam zum siedenden Paraffin geben Produkt + HzO abdestillieren. lOmin 2-Methyl-anilin [ + 2-Amino-benza dehyd 87 [+8] 7... [Pg.827]

Unter gleichen Bedingungen entstehen aus N-Allyl-2-methyl- bzw. N-Allyl-N-methyl-ani-lin jeweils als Hauptprodukte 2-Allyl-6-methyl-anilin (R = H 56%) bzw. 2-Allyl-N-methyl-anilin (r = CH3 68%) und entsprechend aus N-(2-Butenyl)-2-methyl-anilin 6-Methyl-2-(l-methyl-allyl)-anilin (45%)3 ... [Pg.1157]

VNH 0 fJ XCH3 + [groGer ttberschuB an Oxiran] H20 20-25% 20 h 4-Fluor-N,N-bis-[2-hydroxy-ethyl -2-methyl-anilin 82 5... [Pg.1212]

Benzenesulfonyl 2,5 tolylenediazoimide [ called N-Benzol-sulfonyl-4-diazo-2-methyl-anilin or Toluchinon-benzolsulfonylimid-(l) diazid (4) in Ger], CeH5.SOa.N (CH3)CgH3 N2 or C6Hs-S02 ... [Pg.62]

Refs l)Beil 12, [401,402] 2)W.G Macmillan T.H.Reade, JCS 1929, 2866 Dinitrobromomethylaniline, C7HgN304Br mw 276.06 N 15.22%. Three N-methyl derive, (02N)2CgH2Br.NH.CH3, are described in the lieerature 2,4-Dinit.ro-5-bromo-N-methylaniline, yel crysts(from ale), mp l49-l50° 2,4-Dinitro-6 -bromo-N-methylaniline, yel crysts(from AcOH), mp 147° and 2,6-Dinitro-4-bromo-N-metbylaniline, om ndls or yel crysts(from ale or petr eth), mp 104-6°(Ref 1). Two aminotoluene or methylaniline derivs, (OzN)2C6H(Br)NH2.CH3, are described in the literature 4,6-Dinitro-3-bromo-2-methyl-aniline, yel crysts, mp 200°-, and 3,5-Dinitro-2 -bromo-4-methylaniline, It yel ndls or prisms (from ale), mp 170-4°(Ref 2). Other props methods of prepn are given in the Refs Refs l)Beil 12, 761 [417, 418] 2)Beil 12, (397, 445) [540]... [Pg.313]

V-(4-chloro-2-methylphenyl)benzamide. A mixture of 4-chloro-2-methyl-aniline (14.2 g, 0.10 mol), benzoyl chloride (14.1 g, 0.10 mol) and triethylamine (10.1 g, 0.10 mol) in anhydrous toluene (150 ml) is stirred and refluxed for 3 hours and then allowed to stand for c. 16 hours at room temperature. The resulting solids (mixture of product and salts) are filtered off and stirred at room temperature for c. 1.5 hours with water (150.ml). The solid product is filtered off and recrystallised from dichloromethane-toluene (yield 87%, m.p. 170-171 °C). [Pg.1159]


See other pages where Methyl aniline is mentioned: [Pg.208]    [Pg.208]    [Pg.208]    [Pg.220]    [Pg.409]    [Pg.1314]    [Pg.2382]    [Pg.122]    [Pg.146]    [Pg.146]    [Pg.146]    [Pg.686]    [Pg.284]    [Pg.826]    [Pg.826]    [Pg.826]    [Pg.826]    [Pg.826]    [Pg.827]    [Pg.827]    [Pg.827]    [Pg.827]    [Pg.868]    [Pg.971]    [Pg.983]    [Pg.1138]    [Pg.377]    [Pg.136]    [Pg.160]    [Pg.160]    [Pg.160]    [Pg.287]    [Pg.1314]    [Pg.2382]    [Pg.1083]    [Pg.208]   
See also in sourсe #XX -- [ Pg.686 ]




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2 methyl 5 ethyl aniline

2 methyl 5 ethyl aniline hydrogenation

2 methyl 5 ethyl aniline imine

Amines aromatic aniline methylation

Amino di methyl aniline

Aniline A -methyl

Aniline N- [ methyl

Aniline, methylation

Aniline, methylation

Anilines methylated

Anilines methylated

Maleic acid Methyl-aniline

Methyl aniline, ionization

Methyl, alcohol anilines

Mono methyl aniline

Nitroso amines methyl aniline

Quinolines 2-methyl-, from aniline

Reaction of Substituted Anilines with Methyl Iodide

Reduction reactions aromatic aniline methylation

Transition states aniline methylation

V-methyl aniline

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