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Polymer-metal composites, research

Wizel later extended her study and included another metallic nanopartide, cobalt, and an additional polymer, poly(methylmethacrylate), in her metal-polymer composite research [58]. A significant difference in the solubility of the iron-poly(methylacrylate) and cobalt-poly(methylacrylate) in various solvents was observed. While the iron-poly(methylacrylate) composite (FePMA) and iron-poly(methylmethacrylate) composite (FePMMA) dissolved in chloroform, acetone, and toluene at room temperature, the corresponding cobalt-poly(methylacrylate) composite (CoPMA) was insoluble in these solvents at room temperature. At elevated temperatures (45 °C), dissolution of CoPMA in these solvents was observed. This difference is accounted for by the stronger interaction existing between the cobalt and the surrounding polymer. For iron-poly(methylacrylate) this interaction is weakened due to the formation of an iron complex. The Mw of the various polymers and composites as a function of the metal-to-monomer weight ratio was measured and reported. [Pg.126]

A pioneering and comprehensive study of the effect of copper on the thermal oxidative degradation of polyolefins has been made by a Bell Laboratories research group (1-6). They found that surface reactions at the interface between metal and polymer are important factors in many applications including metal-polymer composites, polyolefin-insulated... [Pg.164]

Recently, ultrafine metai particles have attracted much interest because of their unique properties which differ from those of buiK metals, e.g., quantum size effect, such as low melting point, plasmon resonance absorption and so an It is well known that ultrafine metal particles are quite active because of their large surface area and that they are liable to aggregate and grow in size. Thus, it is necessary to maintain them in stable form in a matrix for size control and tor narrow size distribution. Ultrafine metal partides-polymer composites, which are prepared by embedding ntetal particles in a polymer, can be used as electrical, magnetic, optical or chemically useful materials. The techniques to prepare ultrafine metal partides-polymer composites have been explored end reported by many researchers. Many of these involve co-evaporation or co-sputtering of a metal and polymer . In the case of thesb methods, however, metal-polymer composites have to be prepared at a rate below ca. 10 nm/min so that ultrafine metal particles will not... [Pg.95]

The contributors of the chapters in this book have various areas of expertise. Therefore, this book is interdisciplinary and is written for readers with a background in physical science. I believe that this book will be of interest to university students, lecturers and researchers who are interested in the fields of materials science, engineering and technology and, specifically, in advanced ceramic materials, metal, polymer composite, nanomaterials, bio-materials and optical materials. As it deals with many basic concepts that are of concern in the relevant fields, this book can also be used as a primer for studies in materials science and engineering. [Pg.333]

Plueddemann, E.P. (1988). Present status and research needs in silane coupling. In Proc. ICCI-II, Interfaces in Polymer, Ceramic and Metal Matrix Composites. (H. Ishida ed.), Elsevier Sci. Pub. New York. pp. 17-33. [Pg.40]

A more recent trend in polymer materials research is the hybridization of cellulosic polysaccharides with inorganic compounds natural and synthetic layered clays, silica, zeolites, metal oxides, and apatites are employable as nanoscale components. In addition, if mesoscopic assemblies such as liquid-crystalline ordering are used in the construction of new compositional systems, the variety of functionalized cellulosic materials will be further expanded. [Pg.101]

Unless materials are chemically stable in service environments, their otherwise useful properties (strength, ductility, magnetic and electronic behavior, etc.) may be lost. This section describes research opportunities and needs associated with metastable metallic alloys, metal-matrix composites, electroactive polymers, and high-performance ceramics. [Pg.134]

Laboratory of Chemical Technology of Polymeric Composite Materials, V.A. Belyi Metal-Polymer Research Institute of National Academy of Sciences of Belarus, 32a Kiroc Street, 246050 Gomel, Belarus. [Pg.269]

Dr. B.R. Ambedkar National Institute of Technology -Jalandhar. Seven students have completed their Ph.D. degree under his supervision. He has a wide experience in the field of natural products, polymers composites, hydrogels, removal of toxic heavy metal ions from waste water, removal of colloidal particles, sustained drug delivery, controlled release of insecticides/pesticides, etc. He has more than 80 research papers in various reputed international journals. He has more than 60 research papers in the proceedings of the international conferences and... [Pg.721]

In the area of membranes, DOE research strategies include studies of hydrophilic additives, non-aqueous proton conductors, and phase segregation control - both in polymers and two-polymer composites. The DOE s catalysts strategies include lowering platinum group metals (PGM) content, developing affordable platinum-based alloys, and developing non-platinum catalysts. [Pg.108]


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