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Metal oxide-loaded

Historically, the isomerization catalysts have included amorphous siUca-aluminas, zeoHtes, and metal-loaded oxides. AH of the catalysts contain acidity, which isomerizes the xylenes and if strong enough can also crack the EB and xylenes to benzene and toluene. Dual functional catalysts additionally contain a metal that is capable of converting EB to xylenes. [Pg.421]

Various pairs of inorganic ions such as lOsVr, Fe /Fe, and Ce /Ce have been used as redox mediators to facilitate electron-hole separation in metal loaded oxide semiconductor photocatalysts [105-107], Two different photocatalysts, Pt-Ti02 (anatase) and Ti02 (rutile), suspended in an aqueous solution of Nal were employed to produce H2 and O2 under, respectively, the mediation of 1 (electron donor) and IOs (electron acceptor) [105]. The following steps are involved in a one-cell reaction in the presence of UV light. [Pg.392]

Each precious metal or base metal oxide has unique characteristics, and the correct metal or combination of metals must be selected for each exhaust control appHcation. The metal loading of the supported metal oxide catalysts is typically much greater than for nobel metals, because of the lower inherent activity pet exposed atom of catalyst. This higher overall metal loading, however, can make the system more tolerant of catalyst poisons. Some compounds can quickly poison the limited sites available on the noble metal catalysts (19). [Pg.503]

Calculating the Maximum Quantity of Lead and Lead Compounds. To calculate the maximum amount of lead and lead compounds present at your facility at any one time, you must consider types of metallic load and M types of lead compounds present at your facility, Including stockpiled raw materials, lead and lead oxide present in process equipment, the metallic lead and lead peroxide contained in finished batteries stored on-site, and stockpiled lead scrap. Since the reporting form is being prepared for lead compounds, the maximum amount reported is the total of the inventories of these materials. The maximum amount of metallic lead (2,305,000 pounds), lead oxide (205,000 pounds), and lead peroxide (625,000 pounds) present at your facility is 3,135,000 pounds, which is between 1,000,000 and 9,999,999 pounds. You would therefore report range 06 on Part III, Section 4, of the reporting form. [Pg.83]

Transport in solution or aqueous suspension is the major mechanism for metal movement from the land to the oceans and ultimately to burial in ocean sediments. In solution, the hydrated metal ion and inorganic and organic complexes can all account for major portions of the total metal load. Relatively pure metal ores exist in many places, and metals from these ores may enter an aquatic system as a result of weathering. For most metals a more common sequence is for a small amount of the ore to dissolve, for the metal ions to adsorb onto other particulate matter suspended in flowing water, and for the metal to be carried as part of the particulate load of a stream in this fashion. The very insoluble oxides of Fe, Si, and A1 (including clays), and particulate organic matter, are the most important solid adsorbents on which metals are "carried."... [Pg.415]

Bimetallic Co-Mo oxide specimens were prepared via co-impregnation of calculated amounts of cobalt nitrate and ammonia heptamolybdate on y-alumina to achieve a total metal loading of 20wt% with an equimolar Co Mo ratio. Nitridation of catalysts was carried in a fixed bed... [Pg.245]

The catalyst was prepared by impregnating porous alumina particles with a solution of nickel and lanthanum nitrates. The metal loading was 20 w1% for nickel and 10 wt% for lanthanum oxide. The catalyst particles were A group particles [8], whereas they were not classified as the AA oup [9]. The average particle diameter was 120 pm, and the bed density was 1.09 kg m . The minimum fluidization velocity was 9.6 mm s. The settled bed height was around 400 mm. The superficial gas velocity was 40-60 mm s. The reaction rate was controlled by changing the reaction temperature. [Pg.498]

Figure 11. Tafel plots for methanol oxidation on (a) an E-Tek Pt-C electrode and (b) an E-Tek PtojRuoj-C electrode (1 M CH3OH in 0.5 M HQO4, 50 C, metal loading 0.1 mg cm" ). Figure 11. Tafel plots for methanol oxidation on (a) an E-Tek Pt-C electrode and (b) an E-Tek PtojRuoj-C electrode (1 M CH3OH in 0.5 M HQO4, 50 C, metal loading 0.1 mg cm" ).
Precious metal loaded ln/H-ZSM-5 for reduction of nitric oxide with methane in the presence of water vapor... [Pg.671]

The BET surface of ACC, oxidized ACC and Pt/ACC were 1300, 680, and 580 m2g" respectively. Surprisingly, the distribution of pore radius in the three samples exhibited 4 sharp peaks centered at the same position at 0.37, 0.55, 0.75, 0.95 nm, respectively (Table 1). Therefore, neither the NaOCl oxidizing treatment, nor the metal loading modified the micropore size. However, the peak heights decreased in the series ACC ACC(oxidized) > Pt/ACC resulting in a decrease of the differential volumes dV/dr given in Table 1. Therefore, the... [Pg.53]

Chromium zeolites are recognised to possess, at least at the laboratory scale, notable catalytic properties like in ethylene polymerization, oxidation of hydrocarbons, cracking of cumene, disproportionation of n-heptane, and thermolysis of H20 [ 1 ]. Several factors may have an effect on the catalytic activity of the chromium catalysts, such as the oxidation state, the structure (amorphous or crystalline, mono/di-chromate or polychromates, oxides, etc.) and the interaction of the chromium species with the support which depends essentially on the catalysts preparation method. They are ruled principally by several parameters such as the metal loading, the support characteristics, and the nature of the post-treatment (calcination, reduction, etc.). The nature of metal precursor is a parameter which can affect the predominance of chromium species in zeolite. In the case of solid-state exchange, the exchange process initially takes place at the solid- solid interface between the precursor salt and zeolite grains, and the success of the exchange depends on the type of interactions developed [2]. The aim of this work is to study the effect of the chromium precursor on the physicochemical properties of chromium loaded ZSM-5 catalysts and their catalytic performance in ethylene ammoxidation to acetonitrile. [Pg.345]


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Loading metal

Metal Loaded Oxide Semiconductors

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