Metal classification scheme

A classification by chemical type is given ia Table 1. It does not attempt to be either rigorous or complete. Clearly, some materials could appear ia more than one of these classifications, eg, polyethylene waxes [9002-88 ] can be classified ia both synthetic waxes and polyolefins, and fiuorosihcones ia sihcones and fiuoropolymers. The broad classes of release materials available are given ia the chemical class column, the principal types ia the chemical subdivision column, and one or two important selections ia the specific examples column. Many commercial products are difficult to place ia any classification scheme. Some are of proprietary composition and many are mixtures. For example, metallic soaps are often used ia combination with hydrocarbon waxes to produce finely dispersed suspensions. Many products also contain formulating aids such as solvents, emulsifiers, and biocides. 

Nonferrous metallurgy is as varied as the ores and finished products. Almost every thermal, chemical, and physical process known to engineers is in use. The general classification scheme that follows gives an understanding of the emissions and control systems aluminum (primary and secondary), beryllium, copper (primary and secondary), lead (primary and secondary), mercury, zinc, alloys of nonferrous metals (primary and secondary), and other nonferrous metals. 

As a slight departure from the present classification scheme, oxide-based cermets can be either oxide particles in a metal matrix or metal particles in an oxide matrix. Such cermets are used in tool making and high-temperature applications where erosion resistance is needed. 

When we study a solid that does not have the characteristic lustrous appearance of a metal, we find that the conductivity is extremely low. This includes the solids we have called ionic solids sodium chloride, sodium nitrate, silver nitrate, and silver chloride. It includes, as well, the molecular crystals, such as ice. This solid, shown in Figure 5-3, is made up of molecules (such as exist in the gas phase) regularly packed in an orderly array. These poor conductors differ widely from the metals in almost every property. Thus electrical conductivity furnishes the key to one of the most fundamental classification schemes for substances. 

A distinction between a solid and liquid is often made in terms of the presence of a crystalline or noncrystalline state. Crystals have definite lines of cleavage and an orderly geometric structure. Thus, diamond is crystalline and solid, while glass is not. The hardness of the substance does not determine the physical state. Soft crystals such as sodium metal, naphthalene, and ice are solid while supercooled glycerine or supercooled quartz are not crystalline and are better considered to be supercooled liquids. Intermediate between the solid and liquid are liquid crystals, which have orderly structures in one or two dimensions,4 but not all three. These demonstrate that science is never as simple as we try to make it through our classification schemes. We will see that thermodynamics handles such exceptions with ease. 

There are many ways to classify composites, including schemes based upon (1) materials combinations, such as metal-matrix, or glass-fiber-reinforced composites (2) bulk-form characteristics, such as laminar composites or matrix composites (3) distribution of constituents, such as continuous or discontinuous or (4) function, like structural or electrical composites. Scheme (2) is the most general, so we will utilize it here. We will see that other classification schemes will be useful in later sections of this chapter. 

Some related processes are difficult to classify. One example is the formation of blisters and pits in metals which sometimes accompanies treatment of metals, either simultaneously or sequentially, with hydrogen and oxygen (embrittlement). Limitations of the classification scheme with respect to some reconstruction processes are discussed below. 

We see that for the (alkali metal + oxygen macrocycle) complexes, charge and relative size of the ion play an important part in determining the stability of the complex. However, for the (transition metal + aza- or thia-substituted macrocycle) complexes, the nature of the bonding seems to be the important effect. Sten Ahrland16 has used a classification scheme for metal ion acceptors that helps us understand this difference. He designates the metal ion as either hard or soft. The characteristics that determine the assignment are as follows. 

Like the other systems above, the W-S system can be treated according to Kullerud s classification scheme for binary sulfides141. Two regions of liquid immiscibility should occur at high temperatures under equilibrium pressure in both the metal-rich and the sulfur-rich portions of the W—S system. This is incorporated in the schematic diagram shown in Fig. 9. 

The corrosivity of soils also depends upon the oxidation-reduction potential as classified by Booth et al.15 The classification scheme of the corrosivity of soils is given in Table 4.4b. Macrogalvanic cells are formed in underground pipelines due to foreign structure the combination of new and old pipe dissimilar metals (stainless steel and carbon steel) differential aeration dissimilar soils and stray currents. All these lead to localized corrosion of underground pipelines. 

The U.N. classification scheme defines water-reactive substances as substances which are liable to become spontaneously flammable or to give off flammable gases in dangerous quantities by interaction with water. Water-reactive substances include, among others, alkaline metals (Na, K, Li, etc.), hydrogenates, and organometallic compounds. 

This review is intended to focus on ceramic matrix composite materials. However, the creep models which exist and which will be discussed are generic in the sense that they can apply to materials with polymer, metal or ceramic matrices. Only a case-by-case distinction between linear and nonlinear behavior separates the materials into classes of response. The temperature-dependent issue of whether the fibers creep or do not creep permits further classification. Therefore, in the review of the models, it is more attractive to use a classification scheme which accords with the nature of the material response rather than one which identifies the materials per se. Thus, this review could apply to polymer, metal or ceramic matrix materials equally well. 

The periodic table is a classification scheme for elements that is tremendously useful in learning the properties of the elements. It consists of seven periods and 16 classical groups, or families (18 in a more modem but less useful version). Several of the groups have names, which beginning students need to leam. The elements are separated into metals and nonmetals on the periodic table. They are also subdivided into main group elements, transition elements, and inner transition elements. (Section 1.5)... 

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