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Materials and Experimental Techniques

Dupuis A-C (2011) Proton exchange membranes for fuel cells operated at medium temperatures materials and experimental techniques. Prog Mater Sci 56 289-327... [Pg.293]

Aspects of bonding and structure/dynamics in selected carbonium ions were presented and discussed. These representative studies demonstrate the power of structural theory in the development of concepts that could lead to new and efficient processes, especially in the area of hydrocarbon chemistry and catalysis. There is no doubt that as newer theoretical and experimental techniques and models are introduced, they will be applied to the study of carbonium ions. A deeper understanding of structure/dynamics of hypervalent non-classical carbonium ions will not only deepen our knowledge of structural theory in chemistry, but could also help in the development of new processes and materials useful in our daily life. [Pg.337]

As with the first two editions, the book is organized into two parts I. Theory and Experimental Techniques and II. Experiments. Part I introduces students to theoretical and background material for the experiments. This part may also serve as a supplement for instructors who use their own experiments. In Part II there are 15 experiments that represent all areas of biochemistry, including working with proteins and nucleic acid isolation and characterization. The number of experiments has been reduced from earlier editions at the request of instructors and students who believed the book had more experiments than needed for a typical one-semester course. There are, however, still sufficient experiments for a two-semester course sequence. The reduction in the number of experiments has also been achieved by combining some experiments. [Pg.483]

This statement refers directly to the concept of the potential energy function describing interaction energy as a function of the distance sufficient to model various properties of matter that are directly or indirectly related to the intermolecular forces. Recent progress in computational and experimental techniques opens the perspective for rational de novo design of new materials with desired properties being governed by specific interactions. [Pg.603]

Catalytic applications of ceria and ceria-based mixed oxides depend primarily upon the nature and concentration of the defects present in the material. Although experimental techniques are available for the study of these defects, the characterization of their physical properties at the atomic level is often very difficult. The most important point defects in ceria are oxygen vacancies, reduced Ce centers and dopant impurities. The formation energy of such defects and the energetics of their mutual interactions within the bulk oxide have been the subject of several computational studies. [Pg.278]

The role of computer modelling in the science of complex solids including microporous materials was surveyed in Faraday Discussion 106 held in 1997. These techniques have now an increasingly predictive role. They can, for example, predict new microporous structures, design templates for their synthesis and model the static and dynamical behaviour of sorbed molecules within their pores,a topic of enduring importance and one of particular interest to Barrer. Computer modelling methods are, of course, most effective when used in a complementary manner with other physical techniques. Ref. 6 nicely illustrates this theme. Here EXAFS and quantum mechanical methods are used in a concerted manner to elucidate the structure of the active site in microporous titanosilicate catalysts. Articles in Faraday Discussions, vol. 106 again illustrate the complementarity of computational and experimental techniques. [Pg.340]

In order to obtain optimum line narrowing and improved sensitivity in a solid-state NMR spectrum of a zeolitic material, the experimental techniques discussed in this chapter may be applied in combination, as, e.g., CP/MAS, DD/MAS, CP/DOR or CRAMPS (Combined rotation and multiple pulse spectroscopy). The rotor synchronization technique provides... [Pg.149]

The practice of catalysis involves an extensive knowledge of the procedures and experimental techniques used in the preparation of solid catalysts. Chemical composition is not a sufficient guide. In many cases, the physical characteristics such as surface area, pore volume, pore size, particle size and crystal structure modify or control the catalytic properties of the material. [Pg.220]

Such differences can be attributed to differences in starting material and experimental conditions and techniques. Further it should be born in mind that thermal decomposition processes occur along complex mechanisms that cannot adequately be described by a simple rate law. This explains why apparent energies of activation or reaction orders can vary almost continuously with experimental conditions. [Pg.397]

In reviewing a vast quantity of literature on the subject, it is possible to encounter some studies which are of little value because insufficient attention has been given to the control of important physical factors, to the potentiality of the experimental technique, or to the limitations of particular theoretical approaches. Therefore, Section 2 is exclusively devoted to description of the materials and experimental methods used in measuring the adsorption of ionic surfactant onto mineral substrates. Some experimental problems, encountered in the everyday laboratory practice, will be pointed out. Among different experimental methods, the adsorption calorimetry particularly deserves to be noted. [Pg.800]

TECHNIQUES FOR MATERIALS CHARACTERIZATION Experimental Techniques Used to Determine the Composition, Structure, and Energy States... [Pg.1967]

The coupling of ab initio and experimental techniques provides a powerful tool for the understanding of proton conductivity and the development of new materials for fuel cells. [Pg.450]


See other pages where Materials and Experimental Techniques is mentioned: [Pg.356]    [Pg.52]    [Pg.798]    [Pg.212]    [Pg.231]    [Pg.49]    [Pg.356]    [Pg.233]    [Pg.292]    [Pg.295]    [Pg.30]    [Pg.31]    [Pg.33]    [Pg.37]    [Pg.39]    [Pg.41]    [Pg.45]    [Pg.47]    [Pg.356]    [Pg.52]    [Pg.798]    [Pg.212]    [Pg.231]    [Pg.49]    [Pg.356]    [Pg.233]    [Pg.292]    [Pg.295]    [Pg.30]    [Pg.31]    [Pg.33]    [Pg.37]    [Pg.39]    [Pg.41]    [Pg.45]    [Pg.47]    [Pg.20]    [Pg.404]    [Pg.260]    [Pg.451]    [Pg.420]    [Pg.391]    [Pg.215]    [Pg.746]    [Pg.74]    [Pg.31]    [Pg.3]    [Pg.8]    [Pg.451]   


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