Material polycrystalline boron nitride

Machining Ferrous Materials with Polycrystalline Boron Nitride... 

Fig. 4-26. Temperature dependency of the microhardness (Knoop) of sintered and composite dense polycrystalline boron nitride materials from 300 to 1500 K (in GPa) [2].

A wide range of cutting-tool materials is available. Properties, performance capabilities, and cost vary widely (2,7). Various steels (see Steel) cast cobalt alloys (see Cobalt and cobalt alloys) cemented, cast, and coated carbides (qv) ceramics (qv), sintered polycrystalline cubic boron nitride (cBN) (see Boron compounds) and sintered polycrystalline diamond tbin diamond coatings on cemented carbides and ceramics and single-crystal natural diamond (see Carbon) are all used as tool materials. Most tool materials used in the 1990s were developed during the twentieth century. The tool materials of the 1990s... 

Cubic Phase of Boron Nitride c-BN. The cubic phase of boron nitride (c-BN) is one of the hardest materials, second only to diamond and with similar crystal structure. It is the first example of a new material theoretically predicted and then synthesized in laboratory. From automated synthesis a microcrystalline phase of cubic boron nitride is recovered at ambient conditions in a metastable state, providing the basic material for a wide range of cutting and grinding applications. Synthetic polycrystalline diamonds and nitrides are principally used as abrasives but in spite of the greater hardness of diamond, its employment as a superabrasive is limited by a relatively low chemical and thermal stability. Cubic boron nitride, on the contrary, has only half the hardness of diamond but an extremely high thermal stability and inertness. 

Conductivity of (BN) iSO F and comparison with Cg SO F. In our early studies (12), a four-probe technique was employed, in which four platinum wires were used for electrical contact, and the samples were prepared by pressing powdered polycrystalline material into pellets. Because the platinum wires and the pellet surface are not ideally flat, a uniform intimate contact could not be assured between the wires and the pellet. The boundary effects due to the polycrystalline nature of the pellet sample also render such conductivity measurements unreliable. Attempts to use a contactless radio frequency inductive technique described by Zeller et al. (22) failed because this technique is not sensitive to low conductivities. A four-point probe measurement (21) on an intercalated highly oriented boron nitride sample was used in the present set of conductivity measurements. The <7295k 1.5Scm . The specific conductivity increased with decreasing temperature (see Fig. 1), it having nearly twice the room temperature value at 77 K. This indicates metallic behavior. 

Until recently, there were no tool materials that would stand up to the high stresses and temperatures necessary for FSW of materials with higher melting points, such as steels, stainless steels, and nickel-base alloys. In 1998, tungsten alloys and polycrystalline cubic boron nitride (PCBN) were developed to create FSW tools for use in steel, stainless steel, titanium alloys, and nickel-base alloys. Properties of the resultant welds have been shown to be outstanding. Although some issues remain (primarily limited tool life with tungsten-base tools), FSW has been demonstrated as a technically and eco-... 

Reviews on the synthesis of sinter materials consisting of p-BN and/or y-BN and their use as machining tools are numerous and have been cited with the respective applications. Variable intergrain bonding additives are contained in polycrystalline hard boron nitride sinters, and it is difficult to decide if a material should be classified as a polycrystalline hard boron nitride sinter, as a sintered boron nitride base ceramic, or as hard metal-bonded dense boron nitride. 

P-BN tools work satisfactorily in hardened steel up to contact temperatures of 1000°C, since there is no chemical reaction between boron nitride and iron. This, however, also depends on the binding phase of the polycrystalline materials and can lead to adhesive wear [24, 25]. In hard steel, the main wear mechanism on the tool is abrasion by hard alloy carbide particles [26]. In the case of Co-based super alloy (Vitallium), the results on hard-BN tool wear are somewhat incongruous [27, 28], while Inconel 718 can be machined under proper selection of the cutting conditions [29]. Apparently, austenitic steels containing a high percentage of Co are difficult to cut by hard-BN tools, due to the formation of cobalt nitrides which leads to high tool wear [8]. 

Polycrystalline cubic boron nitride (CBN) is a material with excellent hot hardness and can be used at very high cutting speeds. It also has good toughness and resistance to thermal shock. CBN consists of boron nitride with ceramic or titanium nitride binder and is brazed onto a cemented carbide carrier to form an insert. CBN grades are largely used for finish turning hardened steel... 

FIGURE 9.10 Polycrystalline cubic boron nitride (rcHN) blanks and workpiece materials. 

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