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Major elemental ratios

I) that these are called the ordinary chondrites these constitute 35%, 38% and 8%, respectively, i.e. >80% of all falls Obviously, chondrite compositions with elements apportioned by chemical form are not continuous but, rather, quantized. Elsewhere (/) I list major element ratios diagnostic of specific chondritic groups. The total iron in some enstatite (E) chondrites - i.e. those in which the ferromagnesian silicate pyroxene (and the other low-Ca one, olivine) is Fe- and Ca-free MgSiOs - exceeds that in the H group of ordinary chondrites, denoting them as EH chondrites the EL chondrite designation is self-evident. [Pg.169]

The elements Na, K, Cl, SO, Br, B, and F are the most conservative major elements. No significant variations in the ratios of these elements to chlorine have been demonstrated. Strontium has a small (< 0.5%) depletion in the euphotic zone (Brass and Turekian, 1974) possibly due to the plankton Acantharia, which makes its shell from SrS04 (celestite). Calcium has been known since the 19th century to be about 0.5% enriched in the deep sea relative to surface waters. Alkalinity (HCOf") also shows a deep enrichment. These elements are controlled by the formation... [Pg.259]

Negrel Ph, Allegre CJ, Dupre B, Lewin E (1993) Erosion sources determined by inversion of major and trace element ratios and strontium isotopic ratios in river water the Congo Basin case. Earth Planet Sci Lett 120 59-76... [Pg.118]

Table 3 describes the main parts of an environmental risk assessment (ERA) that are based on the two major elements characterisation of exposure and characterisation of effects [27, 51]. ERA uses a combination of exposure and effects data as a basis for assessing the likelihood and severity of adverse effects (risks) and feeds this into the decision-making process for managing risks. The process of assessing risk ranges from the simple calculation of hazard ratios to complex utilisation of probabilistic methods based on models and/or measured data sets. Setting of thresholds such as EQS and quality norms (QN) [27] relies primarily on... [Pg.406]

Table 4 shows the flux of main heavy metals and nutritious elements for 32 rivers (R-Flux) and Chinese continent (T-Flux) flowing into the sea. Furthermore, it shows the average ratio of SPM and dissolved forms (SPM-rate and Water-rate) when rivers reach to shallow sea. From it, variation of flux is very large among different elements, flux of major elements like as Ca, Fe, K, Mg, Na can get to a few or decades million tons, while trace elements including Cd and Hg have only decades to one hundred tons. In the same boat, transport forms of different elements vary largely too. Ratio of dissolved form for Ca, K, Mg and Na when river water migrates to sea takes up over 90%, while for Fe and Pb SPM form takes up domination. [Pg.72]

If we are dealing with major elements, partition coefficients Dt may be expected to vary with many parameters, including temperature or liquid chemistry. For some elemental pairs and particularly for isotopes for which activity coefficients are correlated, there is a better chance, however, that the ratio of two partition coefficients Dn and Di2 shows lesser variations. We therefore subtract the distillation equation (1.5.3) for element or isotope il from that for i2 as... [Pg.36]

Leaching of chemicals from complex materials or matrices is a complicated phenomenon in which many factors may influence the release of the specific organic compounds and inorganic ions. Important factors include major element chemistry, pH, redox, complexation, liquid to solid ratio, contact time, and biological activity. To describe fully the leaching of SWMs/COMs under field conditions, a battery of leaching tests was specifically designed to simulate various physical and chemical release mechanisms. [Pg.221]

Several difficulties arise from the use of TBP in the Thorex pro-cess.Thorium (IV) is the major element present, and the loading capacity of a 30% TBP-dodecane solution is considerably lower for the tetravalent actinides than it is for U(VI) thus, a larger organic/aqueous phase ratio... [Pg.529]

In recent years, tremendous progress has been achieved in the analysis of the isotope composition of important trace compounds in the atmosphere. The major elements - nitrogen, oxygen, carbon - continually break apart and recombine in a multitude of photochemical reactions, which have the potential to produce isotope fractionations (Kaye 1987). Isotope analysis is increasingly employed in studies of the cycles of atmospheric trace gases e.g., CH4 and N2O, which can give insights into sources and sinks and transport processes of these compounds. The rationale is that various sources have characteristic isotope ratios and that sink processes are accompanied by isotope fractionation. [Pg.164]

A second example is shown in excerpt 13Q. Harpp s proposed work initially involves the collection of held data in two sampling campaigns. Following collection, the samples will be analyzed for trace and major element concentrations and isotopic ratios. In her case, the order in which she conducts these analyses is less important than how she will use the data to answer questions about plume-ridge interaction mechanisms. Thus, she organizes her proposed work (titled Proposed Plan ) not by the tests she will perform, but rather by the types of information the analyzed data will provide (i.e., information about formation mechanisms, melting dynamics, and spatial distributions). [Pg.463]

Year Three Complete analysis of trace elements by ICP-MS at Lawrence University analysis of major elements by XRF at Macalester College (up to 100 samples) determination of Sr, Nd, and Pb isotopic ratios of a selection of Wolf and Darwin samples by TIMS at Cornell (up to 30 samples). Interpretation of geochemical data, modeling of melting parameters. Presentation of results at Fall AGU meeting by undergraduate student(s). Preparation for fieldwork. [Pg.481]

Major-element compositions (weight ratios of Mg/Si and Al/Si) for mantle rocks (peridotites) and estimates of the primitive mantle composition of the Earth compared with various groups of chondrites and the Sun. No mixture of chondrite types provides an exact match to the primitive mantle composition, although some carbonaceous chondrites provide the closest match. Modified from Righter et al. (2006). [Pg.501]

And the answer is yes if we emphasize the way the new findings enable us to revise Freud s necessarily speculative dream theory and replace it with one that gives a detailed alternative account of dream phenomenology and eliminates the very dubious disguise-censorship idea, but still retains the crucial concept of emotional salience as a major element in dream content elaboration. The model does not now specify regional shifts in neuronal activity and/or blood flow, but if both derive from the neuromodulatory ratio shift, then factor M would predict the enhancement of emotion in dreaming and its central role in shaping dream plots. [Pg.130]

Although we attributed artifacts to each of the four major western Mediterranean sources, our focus here is on artifacts attributed to Monti Arci, Sardinia. Figure 2 illustrates the use of elemental ratios to discriminate the major island obsidian groups by INAA. By projecting these data as logged ratios of samarium/barium on the X-axis and iron/cesium on the Y-axis, we have maximized the differences between the various Sardinian subgroups in a manner... [Pg.279]

Figure l. Comparison ofINAA elemental ratios for the four major western Mediterranean Island obsidian sources. Only geologic source samples are... [Pg.280]

Elemental analysis is a common tool used for the characterization and differentiation of HS isolated from organic amendments and unamended and amended soils. It provides information on the distribution of major elements, typically C, H, N, S, and O, in HS, thus setting limits for HS possible molecular composition. The atomic ratios C/N, C/H, and O/C are also useful in identifying types of HS, monitoring their structural changes, and devising HS structural formulas (Stevenson, 1994 Senesi and Loffredo, 1999). [Pg.152]

The dominant elements in marine DOM are expected to be C, H, and O, with lesser quantities of N, S, and R Concentrations of organic C, N, and P can be measured directly on seawater without isolating DOM, using methods that were described in Section 11.1.2, and those concentrations can be used to calculate molar ratios of C/N, C/P, and N/P Concentrations of organic C, N, and P cannot be converted into conventional mass-based elemental compositions (%C, %N, and %P), because the total mass of DOM cannot itself be measured directly in seawater. To be able to calculate the mass percentages of all major elements in marine DOM, samples must be isolated and purified to yield dry, low-ash materials. [Pg.430]

As stated by Van der Sloot (1998), several factors can influence the release of contaminants from both granular and monolithic materials. These include major element chemistry, pH, redox status of the system, presence of complexants, humic substances or other dissolved organic compounds, liquid to solid ratio, and biological activity. [Pg.357]

Major element compositions for the Colle Fabbri rocks are extremely variable for such a small outcrop (e.g. Si02 = 43-64 wt % CaO = 4 to 37 wt %). Rare-earth elements (REE) are moderately enriched and fractionated, and contain an important negative Eu anomaly. 87Sr/86Sr ratios range from 0.7077 to 0.7119 and 143Nd/144Nd ratios vary from 0.71115 to 0.71192 (Melluso et al. 2003). [Pg.60]

Variation diagrams of major and trace elements vs. MgO at Colli Albani (Fig. 4.19) show a positive correlation for CaO, TiC>2, FeOtotai and ferro-magnesian trace elements (Cr, Ni, Co, etc.), negative correlations for Na20, K2O, AI2O3 and incompatible elements (Th, La, Ta, etc.), and a bell shaped trend for P2O5. Incompatible elements show smooth inter-element positive trends (Fig. 4.19g). The pre-caldera lavas seem to define different trends on some major and trace element variation diagrams, especially on plots of incompatible element vs. incompatible element ratios (Fig. 4.19h). REE and incompatible element patterns have shapes that are similar to those for other ultrapotassic rocks from the Roman Province (Fig. 4.20). [Pg.94]


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