Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Continuity break

The enthalpy of the copolymerization of trioxane is such that bulk polymerization is feasible. For production, molten trioxane, initiator, and comonomer are fed to the reactor a chain-transfer agent is in eluded if desired. Polymerization proceeds in bulk with precipitation of polymer and the reactor must supply enough shearing to continually break up the polymer bed, reduce particle size, and provide good heat transfer. The mixing requirements for the bulk polymerization of trioxane have been reviewed (22). Raw copolymer is obtained as fine emmb or flake containing imbibed formaldehyde and trioxane which are substantially removed in subsequent treatments which may be combined with removal of unstable end groups. [Pg.58]

An effective hquid-liquid reactor may be designed to obtain drops that continuously break up and coalesce, or it may be designed to obtain very small drops that have very efficient mass transfer and follow the continuous phase with a low rate of coalescence. The former will require a much larger reactor, but the separation of the phases after reaction is simpler. [Pg.351]

Whereas the dipoles themselves are permanent, van der Waals interactions are not. They are sufficiently weak that they continually break and re-form as part of a dynamic process. [Pg.44]

In recent years, tremendous progress has been achieved in the analysis of the isotope composition of important trace compounds in the atmosphere. The major elements - nitrogen, oxygen, carbon - continually break apart and recombine in a multitude of photochemical reactions, which have the potential to produce isotope fractionations (Kaye 1987). Isotope analysis is increasingly employed in studies of the cycles of atmospheric trace gases e.g., CH4 and N2O, which can give insights into sources and sinks and transport processes of these compounds. The rationale is that various sources have characteristic isotope ratios and that sink processes are accompanied by isotope fractionation. [Pg.164]

Hydrogen bonds are continually breaking and reforming by thermal agitation and, according to the association model, there exist instantaneous distributions of free monomers Bj, hydrogen-bonded dimers B2 and multimers Bj, which obey the reaction scheme ... [Pg.146]

Was this your answer As Table 8.1 shows, the specific heats of ice and water vapor are about half that of liquid water. Only liquid water has a remarkable specific heat. This is because the liquid phase is the only phase in which hydrogen bonds are continually breaking and re-forming. [Pg.276]

Despite all the alleged poisons in the food, stomach cancer is declining sons and daughters are growing taller than their parents and athletes continually break world s records. The DDT in the fat of the athletes must be responsible for the new records ... [Pg.117]

At this time, it is instructive to note that Eqs. (34) and (42) predict that the large drops will continuously break down to a size flniax> where the breakage function g(fl ) approaches some arbitrary low value close to zero. At this point, the exponential term dominates the behavior of the breakage rate expression and a relation for Oniax is obtained similar to the one given by Eq. (18), which was derived on the basis of maximum stable drop theory. [Pg.212]

As an example of an application of the splitter, the continuous breaking of an emulsion used in the liquid-membrane-permeation technology is shown in Figure 17. [Pg.396]

Because of the interaction of the two complicated and not well-understood fields, turbulent flow and non-Newtonian fluids, understanding of DR mechanism(s) is still quite limited. Cates and coworkers (for example, Refs. " ) and a number of other investigators have done theoretical studies of the dynamics of self-assemblies of worm-like micelles. Because these so-called living polymers are subject to reversible scission and recombination, their relaxation behavior differs from reptating polymer chains. An additional form of stress relaxation is provided by continuous breaking and repair of the micellar chains. Thus, stress relaxation in micellar networks occurs through a combination of reptation and breaking. For rapid scission kinetics, linear viscoelastic (Maxwell) behavior is predicted and is observed for some surfactant systems at low frequencies. In many cationic surfactant systems, however, the observed behavior in Cole-Cole plots does not fit the Maxwell model. [Pg.779]

Please note that there must not be any continuity breaks in the copper surface. This does not mean no blemishes or imperfections, but does mean that if you put a multimeter probe on one side of a copper trace there should be a continuity beep when the probe is placed on the other side of the copper trace. Take your time with this step. Keep ironing until... [Pg.202]

Some gels do have properties (such as an ability to heal ) that suggest that their junctions are continually breaking and re-forming,... [Pg.304]

Hence, the conclusions provided by NMR observations agree with our results (Figs. 14 and 16) concerning the continuity break of various parameters. [Pg.393]


See other pages where Continuity break is mentioned: [Pg.524]    [Pg.49]    [Pg.495]    [Pg.334]    [Pg.149]    [Pg.245]    [Pg.498]    [Pg.375]    [Pg.49]    [Pg.371]    [Pg.657]    [Pg.116]    [Pg.4]    [Pg.321]    [Pg.746]    [Pg.198]    [Pg.90]    [Pg.1]    [Pg.107]    [Pg.49]    [Pg.55]    [Pg.201]    [Pg.140]    [Pg.285]    [Pg.73]    [Pg.71]    [Pg.363]    [Pg.304]    [Pg.515]    [Pg.69]    [Pg.394]    [Pg.43]    [Pg.105]   
See also in sourсe #XX -- [ Pg.87 ]




SEARCH



Continuous emulsion breaking

Continuous phase breaking efficiency

© 2024 chempedia.info