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4- Lithium compounds

A book on the chemistry of the alkali metals (lithium to francium) has been publishedand the chemistry of the typical elements has been reviewed.  [Pg.25]

The equilibrium pressures (0.5—760Torr) of hydrogen existing above mixtures of lithium with lithium hydride (0.5—99 mol% LiH) sealed in iron capsules have been measured from 983 to 1176 K. The isotherms confirm the phase diagram to consist of two immiscible liquid phases with boundaries 25.2 and 98.4 mol% LiH at 983 K and 45.4 and 85.8 mol% LiH at 1176 K. For dilute solutions of lithium hydride in liquid lithium, the relationship between the mole fraction in solution, Xi.iH, and the equilibrium pressure, (phj)S at T(K) is given by [Pg.25]

The standard free energy of formation (kcalmoF ) of liquid lithium hydride is given by (13.47 x lO T -16.55). The thermodynamic properties of the Li-LiH system have been determined by a mass spectrometric Knudsen effusion method in the plateau region from 973 to 1146 K. The enthalpy, AHitjs, of the reaction [Pg.25]

Gilbert, G. Mamantov, and G. M. Begun, Inorg. Nuclear Chem. Letters, 1974, 10, 1123. [Pg.25]

Habibi, B. Ducourant, R. Fourcade, and G. Mascherpa, Bull. Soc. chim. France, 1974, 2320. [Pg.25]

The worldwide production capacity of lithium and lithium compounds in 1995 was 14 10 t (as lithium), of which 40% is in the USA. The current capacity in the USA is ca. 8 10 t/a and it is still increasing. It supplies 60% of the world market. The capacity in the second largest producer country, Chile, is 3 10 t/a and that in the former States of the USSR is 1 10 t/a. [Pg.214]

The proportion of elemental lithium in the total production of lithium and lithium compounds worldwide is ca. 10%. It is exclusively manufactured by melt electrolysis of a mixture of lithium chloride (45 to 55%) and potassium chloride at 400 to 460°C in steel cells with a graphite anode and a steel cathode. The cell voltage is 6.0 to 6.5 V. The metallic lithium formed collects on the surface of the molten salt electrolyte. [Pg.214]

Most important lithium compounds LijCO, LiOH, LiH, LiCl [Pg.214]

Lithium carbonate Lithium carbonate is industrially the most important lithium compound and the starting material for most of the other lithium salts. It is formed in the processing of lithium minerals and brines. Enriched and calcined lithium ore (spodumene) is digested e.g. with [Pg.214]

Lithium carbonate is utilized as a starting material for the manufacture of all other lithium compounds and in large quantities in the manufacture of aluminum by melt electrolysis (ca. 25% of the total lithium consumption). Lithium carbonate is also used as a flux in the glass, enamel and ceramic industries, which accounts for a further ca. 25% of lithium consumption. Glasses with high lithium content (on the basis of lithium aluminosilicate) are as a result of their low thermal expansion coefficients virtually fireproof. In psychiatry high purity lithium carbonate is utilized for the treatment of manic-depressive complaints. [Pg.215]

Inorganic Chemistry of the Main-group Elements 8 Lithium Compounds [Pg.42]

Petrov, V. V. Fomichev, G. V. Zimina, and V. E. Plyushchev, Khim. Khim. Tekhnol., Tr. Yubileinoi Konf., Posvyashch. 70-Letiyu Inst., ed. A. N. Bashkirov, (Mosk. Inst. Tonkoi Khim. Tekhnol.), 1970, (Publ. 1972), p. 349. [Pg.42]

Cade and W. Huo, Atomic Data Nuclear Data Tables, 1973, 12, 415. [Pg.42]

Maraine-Giroux, R. Bouaziz, and G. Perez, Rev. Chim. minerale, 1972, 9, 779. [Pg.43]

The reactions of atoms and small molecules as studied by u.v., vacuum-U.V., and visible spectroscopy are discussed in a review which covers rate constants for addition and recombination reactions of molecules and atoms (includes Na, K, and Rb) collisional cross-sections rate constants for reactions and energy transfers of recently observed diatomic molecules and radicals (includes Lig).  [Pg.42]

Ikrami, A. S. Paramzin, and Kh. Sh. Dzhuraev. Izvest. Akad. Nauk Tadzh. S.S.R., Otdel. Fiz-Mat. Geol.-Khim. Nauk, 1972, 42. [Pg.42]

d(calc) = 3.107. The AljBr - anion consists of two AlBr4 tetrahedra sharing one corner. K surrounded by nine Br at 3.3— [Pg.43]

Cubic close-packed Cl ions with octahedral interstices occupied by (K + Al) ions half of tetrahedral interstices occupied by 0 ions. [Pg.43]

Grannec, J. C. Champamaud-Mesjard, J. P. Costy, J. C. Cousseins, and B. Gaud-reau. Rev. Chim. minirale, 1972, 9, 569. [Pg.43]


If the organolithium derivative of 2.4-dimethylthiazole or 2-methyl-4-phenylthiazole (prepared at -78°C) is allowed to warm to room temperature, the 2-lithium compound reacts with the nonmetallated thiazole (Scheme 5) (225). [Pg.379]

Unlike elimination and nucleophilic substitution reactions foimation of oigano lithium compounds does not require that the halogen be bonded to sp hybndized carbon Compounds such as vinyl halides and aiyl halides m which the halogen is bonded to sp hybndized carbon react m the same way as alkyl halides but at somewhat slowei rates... [Pg.590]

COLORANTSFORFOOD,DRUGS,COSTffiTICSANDTffiDICALDEVICES] (Void) -for lithium fires THIUM AND LITHIUM COMPOUNDS] (Vol 15)... [Pg.251]


See other pages where 4- Lithium compounds is mentioned: [Pg.241]    [Pg.241]    [Pg.289]    [Pg.9]    [Pg.17]    [Pg.22]    [Pg.24]    [Pg.30]    [Pg.30]    [Pg.33]    [Pg.36]    [Pg.39]    [Pg.54]    [Pg.61]    [Pg.64]    [Pg.86]    [Pg.92]    [Pg.101]    [Pg.129]    [Pg.142]    [Pg.143]    [Pg.143]    [Pg.143]    [Pg.155]    [Pg.156]    [Pg.164]    [Pg.165]    [Pg.170]    [Pg.173]    [Pg.191]    [Pg.226]    [Pg.229]    [Pg.246]    [Pg.248]    [Pg.254]    [Pg.275]    [Pg.287]    [Pg.298]    [Pg.309]    [Pg.326]    [Pg.361]    [Pg.373]    [Pg.385]    [Pg.400]    [Pg.402]    [Pg.406]   
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See also in sourсe #XX -- [ Pg.126 , Pg.127 , Pg.128 , Pg.129 , Pg.130 , Pg.131 , Pg.132 ]

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Acyl compounds reaction with lithium aluminum hydride

Aliphatic nitro compounds, reductions, lithium aluminum

Alkenyl lithium compounds

Alkyl lithium compounds

Alkyl lithium compounds anionic polymerization

Alkyl lithium compounds initiators

Alkyllithium compounds lithium alkoxide

Alkynyl-lithium compound

Allylic compounds Lithium-Ethylamine

Allylic compounds reductions, lithium aluminum hydride

Allylic compounds, lithium aluminum hydride

Allylic lithium compounds

Antipsychotics Lithium compounds

Aromatic compounds lithium batteries

Benzylic compounds reductions, lithium aluminum hydride

Benzylic compounds, lithium aluminum hydride

Carbonyl compounds lithium diisopropylamide

Carbonyl compounds lithium enolates

Chlorpromazine Lithium compounds

Cluster compounds lithium alkyls

Configuration lithium compounds, organo

Copper Compounds Lithium dimethylcuprate

Cyclopropyl compounds, 1-bromosynthesis via lithium-halogen exchange

Deprotonation of Carbonyl Compounds by Lithium Dialkylamides

Electrophilic reactions lithium compounds

Fluoroaromatic lithium compounds

Graphites lithium-graphite intercalation compounds

Halogen-lithium exchange reactions functionalized compounds

Heterocyclic compounds Lithium diisopropylamide

Hormonal) Lithium compounds

Hydrogen-lithium exchange with aromatic compounds

Hydroxy carbonyl compounds Lithium borohydride

Imidazolones lithium compounds

Insertion compounds, lithium

Intercalation compounds lithium insertion

Lithium Compounds Benzyllithium

Lithium Compounds Butyllithium

Lithium Compounds Ethyllithium

Lithium Compounds Methyllithium

Lithium Compounds Organolithium reagents

Lithium Compounds Phenyllithium

Lithium aluminum hydride aliphatic nitro compounds

Lithium aluminum hydride carbonyl compounds

Lithium aluminum hydride reduction, alcohols from, with carbonyl compounds

Lithium aluminum hydride unsaturated carbonyl compounds

Lithium and its Compounds

Lithium bis copper compounds

Lithium borohydride unsaturated carbonyl compounds

Lithium bridged electron-deficient compounds

Lithium carbonyl compound reduction

Lithium carbonyl compounds

Lithium complexes compounds

Lithium compounds Alcohol

Lithium compounds Aluminium hydroxide

Lithium compounds Amphetamines

Lithium compounds Antibiotics

Lithium compounds Benzodiazepines

Lithium compounds LiCoO

Lithium compounds Michael additions

Lithium compounds aldol reactions

Lithium compounds alkali metal ionic liquids

Lithium compounds alkyl or aryl

Lithium compounds aluminum hydride

Lithium compounds amides

Lithium compounds amination

Lithium compounds benzoate

Lithium compounds combination

Lithium compounds deprotonation with

Lithium compounds diazoalkane cycloaddition reactions

Lithium compounds electrodeposition

Lithium compounds future applications

Lithium compounds levels

Lithium compounds metalation

Lithium compounds organic media

Lithium compounds organometallics, synthesis

Lithium compounds oxidation

Lithium compounds phase effects

Lithium compounds with oxygen

Lithium compounds, organolithium acetylide

Lithium compounds, organo— as reagents

Lithium compounds, reactions

Lithium compounds, structure

Lithium derivatives vinyl compounds

Lithium dialkylcuprates reactions with carbonyl compounds

Lithium dialkylcuprates, addition compounds

Lithium diorganocopper compounds

Lithium graphite compounds

Lithium hexamethyldisilylamide carbonyl compounds

Lithium hydride carbonyl compounds

Lithium intercalation compounds

Lithium organolithium compounds

Lithium organometallic compounds

Lithium organometallic compounds reactions

Lithium sodium compounds, organo

Lithium sulfide intermediate compounds

Lithium triethylborohydride unsaturated carbonyl compounds

Lithium unsaturated carbonyl compounds

Lithium with organometallic compounds

Lithium, 1-phenylseleno-l-thioalkylreactivity reactions with carbonyl compounds

Lithium, 1-seleno-1-silylalkylreactivity reactions with carbonyl compounds

Lithium, a-selenoalkylacyl anion equivalents reactions with carbonyl compounds

Lithium, a-selenoalkylnucleophilicity reactions with carbonyl compounds

Lithium, a-selenoallylambident reactivity reactions with carbonyl compounds

Lithium, a-selenocyclopropylreactivity reactions with carbonyl compounds

Lithium, alkoxyallylalkoxyallylaluminum compounds from

Lithium, organic compounds

Lithium, organo- compounds

Lithium, organo- compounds alkenyl

Lithium, organo- compounds alkylation

Lithium, organo- compounds by lithiation

Lithium, organo- compounds examples

Lithium, organo- compounds preparation

Lithium, organo- compounds reactions with

Lithium, organo- compounds structure

Lithium, organo- compounds synthesis using

Lithium, organo-, compounds basicity

Lithium, organo-, reagents carbonyl compounds

Lithium, trialkylstannylmethylreactions with carbonyl compounds

Lithium, trialkylstannylmethylreactions with carbonyl compounds methylenation

Lithium, triarylstannylmethylreactions with carbonyl compounds

Lithium, triarylstannylmethylreactions with carbonyl compounds methylenation

Lithium-acetylene compounds

Lithium-ethylene compounds

Lithium-graphite intercalation compounds

Look up the names of both individual drugs and their drug groups to access full information Lithium compounds

Medicines) Lithium compounds

Moclobemide Lithium compounds

Nitrogen compounds reductions, lithium aluminum hydride

Organic lithium compounds (other than

Organo-lithium compounds, addition

Organo-lithium compounds, addition ketones

Organocopper compounds. See Lithium diorganocuprates

Organolithium compounds with lithium carboxylates

Organometallic compounds of lithium

Organonitrogen-lithium compounds

Poly lithium compounds

Potassium iodide Lithium compounds

Reduction by lithium aluminum hydride or similar compounds

Salicylates Lithium compounds

Secondary benzylic lithium compounds

Sodium bicarbonate Lithium compounds

Sodium chloride Lithium compounds

Sodium salicylate Lithium compounds

Sulfur compounds lithium aluminum hydride

Sulfur, reaction with organo-lithium compounds

THIUM AND LITHIUM COMPOUNDS

Tertiary benzylic lithium compounds

Tertiary silyl lithium compounds

Unsaturated carbonyl compounds Lithium-Ammonia

Vinyl lithium compounds

Vinylic lithium compounds

With Organo Lithium Compounds

With lithium, reduction aromatic compounds

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