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Organonitrogen-lithium compounds

Structures of Organonitrogen-Lithium Compounds Recent Patterns and Perspectives in Organolithium Chemistry... [Pg.511]

STRUCTURES OF ORGANONITROGEN-LITHIUM COMPOUNDS RECENT PATTERNS AND PERSPECTIVES IN ORGANOLITHIUM CHEMISTRY... [Pg.47]

Organonitrogen-lithium compounds, and particularly lithium amides (R2NLi), are widely used both in organic and in organometallic syntheses. For the former, these strong bases are employed as proton abstractors (5-8), to generate new organolithiums. These can then be derivatized with so-called electrophiles, e.g., alkyl and acyl halides (E+ = R+ and R—C+=0) and trimethylsilylchloride (E+ = MeaSi+) [Eq. (1)]. [Pg.48]

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Organonitrogen

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