Polymer-liquid systems

A method of manufacturing rubber articles by pouring a compounded latex into an absorbent hollow mould the skin of rubber thus formed is removed, dried and vulcanised. The term is also apphed to the pouring into moulds of liquid polymer systems based on silicone or polyurethane elastomers. 

The results presented in Fig. 6.9 for a solid polymer electrolyte follow the same trend as that obtained for electrolytes based on low molecular weight liquid polymers. Fig. 6.10 (MacCallum, Tomlin and Vincent, 1986 Cameron, Ingram and Sorrie, 1987). The liquid polymer systems are very similar to conventional non-aqueous electrolytes which also show a... 

Fabricated silicone rubber parts are traditionally made from high consistency silicone gum stock. Because of the stiffness of the gum stock, the material must be worked with rubber masticating equipment and preformed before fabrication. A new fabricating process using a low consistency liquid silicone rubber was introduced by Dow Corning Corporation recently (1, 3). This process is called liquid polymer system (LPS). 

Extrusion Coating - The use of liquid silicone rubber in coating application requires less energy than conventional dispersion coating processes. Solventless material, rapid cure time, absence of by-products and the elimination of multiple passes all contribute to the reduced energy demand of the liquid polymer system. 

Good physical properties, including low viscosity provides superior handling in liquid polymer system. 

The addition of a second liquid to a binary liquid-polymer system to produce a ternary system is used widely for a variety of purposes. If the seeond liquid is a poor solvent, or a pre-eipitant for the polymer, the dissolving potential of the liquid medium can be reduced and eventually phase separation may even occur. This does not neeessarily take place in every case and sometimes mixtures of two relatively poor solvents can even produce an enhancement of the solvent power. The mixed solvent is then said to exhibit a synergistic ef feet. ... 

Volatile Liquids. These are chilled and mixed into the liquid polymer system at room temperature. They provide temporary plasticization. Then, the heat of processing volatilizes them, plasticization ceases, and the expanding gas bubbles produce the foam. 

The Phaser experiments reveal a surprising thermodynamic principle of polymer-solvent-carbon dioxide mixtures. Whereas most polymers have very low solubility (often below 1%) in supercritical carbon dioxide, supercritical carbon dioxide can have appreciable solubility in many types of polymers. Carbon dioxide solubilities ranging from 20 to 60% have been measured for several pure liquid polymer systems having no organic solvent. In these systems, the thermodynamic concepts of solvent and solute are reversed the carbon dioxide is the solute and the polymer is the solvent. 

Recently, a liquid polymer system (ATRIGEL ) has been developed which has both the simplicity and control of solid biodegradable implants... 

In the previous chapter, we discussed liquid polymer systems. These exist in specific states selected by the laws of equilibrium thermodynamics. The rules which control structure formation during crystallization are different and this is a most important point to be noticed Structure formation here is governed by kinetical criteria rather than by equilibrium thermodynamics. What does this mean Indeed, we encounter here a new criterion The structure which develops at a given temperature is that with the maximum growth rate rather than that with the lowest free energy. As a consequence, treatment of the crystallization behavior of polymers requires kinetical considerations. 

Liquid Crystalline Systems. Conventional photoconductive polymers are amphorous or systems withlow order. In the case of PVK, the hole moves by hoppiag between the pendent carba2ole groups. The hole mobilities are usuaUylow, cm /Vs, due to a trap-dominated hoppiag... 

FIG. 22-85 Phase diagram for a PEG/Dextran, hiphasic, aqueous-polymer system used in liquid-liquid extraction operations for protein separations. Alheiisson, Partition of Cell Particles and Macromolecules, 3d ed., Copyright 1986. Reprintedhy petTTUssion of John Wiley Sons, Inc.)... 

In 1975 Wacker-Chemie introduced silicones under the name of m-polymers. These are also room temperature curing liquid polymers which give rubbery materials on cross-linking and are available both as one- and two-component systems. Their particular feature is that they contain dispersions of copolymers such as those of styrene and n-butyl acrylate in the shape of rods or rice grains in the fluid silicone polymer. A small amount of the organic copolymer is also grafted onto the silicone backbone. 

In systems of LP the dynamic response to a temperature quench is characterized by a different mechanism, namely monomer-mediated equilibrium polymerization (MMEP) in which only single monomers may participate in the mass exchange. For this no analytic solution, even in terms of MFA, seems to exist yet [70]. Monomer-mediated equilibrium polymerization (MMEP) is typical of systems like poly(a-methylstyrene) [5-7] in which a reaction proceeds by the addition or removal of a single monomer at the active end of a polymer chain after a radical initiator has been added to the system so as to start the polymerization. The attachment/detachment of single monomers at chain ends is believed to be the mechanism of equilibrium polymerization also for certain liquid sulphur systems [8] as well as for self-assembled aggregates of certain dyes [9] where chain ends are thermally activated radicals with no initiators needed. 

As the main disadvantage of liquid membrane systems is the instability over a longer period of time, another approach would be to perform separation through a solid membrane [22]. Enantioselective polymer membranes typically consist of a nonse-lective porous support coated with a thin layer of an enantioselective polymer. This... 

Optimization requires that a-rtjl have some reasonably high value so that the wall temperature has a significant influence on reactor performance. There is no requirement that 3>AtlR be large. Thus, the method can be used for polymer systems that have thermal diffusivities typical of organic liquids but low molecular diffusivities. The calculations needed to solve the optimization are much longer than those needed to solve the ODEs of Chapter 6, but they are still feasible on small computers. 

The liquid-liquid partition systems discussed above are in fact very similar to various membrane-type interfaces and may serve as a model for them. A good example is, for instance, the distribution of a dissociated salt between aqueous solution and a permeable organic polymer [60]. 

Whereas SEC is the dominant technique for the characterisation of polymers, various nonexclusion liquid chromatographic (NELC) methods, such as GPEC and LACCC offer equally valid possibilities for deformulation of complex polymer systems. In fact, molecular characterisation of polymers in the precip-itation/adsorption mode (gradient HPLC) enables differences in chemical structure and composition to be... 

Polymer-modified asphalt is a cold-applied liquid waterproofing system. As with the Sonneborn system mentioned above, the quality of the installation depends on the applicator (it is difficult to achieve an even coating on a vertical surface). High-grade polymer-modified asphalt is superior to coal tar-modified polyurethane in elasticity, crack-spanning ability, and resealability, but inferior in its resistance to chemicals. 

Holland, F.A. Scale-Up of Liquid Mixing Systems, Chemical Engineering, Sept. 17, 1962, p. 179. Chen, S.J., MacDonald, A.R. Motionless Mixers for Viscous Polymers, Chemical Engineering, Mar. 19, 1973, p. 105. 

Step growth polymerization can also yield highly crosslinked polymer systems via a prepolymer process. In this process, we create a prepolymer through a step growth reaction mechanism on two of the sites of a trifunctional monomer. The third site, which is chemically different, can then react with another monomer that is added to the liquid prepolymer to create the crosslinked species. We often use heat to initiate the second reaction. We can use this method to directly create finished items by injecting a mixture of the liquid prepolymer and additional monomer into a mold where they polymerize to create the desired, final shape. Cultured marble countertops and some automotive body panels are created in this manner. 

The macroscopic long-time behavior of dense polymer liquids exhibits drastic changes if permanent cross-links are introduced in the system [75-77], Due to the presence of junctions the flow properties are suppressed and the viscoelastic liquid is transformed into a viscoelastic solid. This is contrary to the short-time behavior, which appears very similar in non-cross-linked and crosslinked polymer systems. 

Many common polymers, polymeric additives and lubricants oxidise so rapidly after impact in liquid oxygen that they are hazardous. Of those tested, only acrylonitrile-butadiene, poly(cyanoethylsiloxane), poly(dimethylsiloxane) and polystyrene exploded after impact of 6.8-95 J intensity (5-70 ft.lbf). All plasticisers (except dibutyl sebacate) and antioxidants examined were very reactive. A theoretical treatment of rates of energy absorption and transfer is included [1], Previously, many resins and lubricants had been examined similarly, and 35 were found acceptable in liquid oxygen systems [2],... 

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