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Liquid inorganic materials

PhenoHc-based resins have almost disappeared. A few other resin types are available commercially but have not made a significant impact. Inorganic materials retain importance in a number of areas where synthetic organic ion-exchange resins are not normally used. Only the latter are discussed here. This article places emphasis on the styrenic and acryHc resins that are made as small beads. Other forms of synthetic ion-exchange materials such as membranes, papers, fibers (qv), foams (qv), and Hquid extractants are not included (see Extraction, liquid-liquid Membrane technology Paper.). [Pg.371]

As with organic solvents, proteins are not soluble in most of the ionic liquids when they are used as pure solvent. As a result, the enzyme is either applied in immobilized form, coupled to a support, or as a suspension in its native form. For production processes, the majority of enzymes are used as immobilized catalysts in order to facilitate handling and to improve their operational stability [24—26]. As support, either inorganic materials such as porous glass or different organic polymers are used [27]. These heterogeneous catalyst particles are subject to internal and external... [Pg.338]

An inspection of Tables 1 and 2 shows that appropriate solvents for lithium batteries mainly belong to classes 6 and 7 and include cyclic (EC, PC) and open-chain (DMC, MEC, DEC, MPC) esters and ethers (DIOX, DME, THF) as well as inorganic sulfur compounds (S02, SOCl2). These sulfur compounds are mainly used as liquid cathode materials, simultaneously serving as solvents (S02C12, SOCl2) or cosolvents (S02) in primary or secondary lithium batteries. Recent developments of solvents include... [Pg.459]

The use of ordered supramolecular assemblies, such as micelles, monolayers, vesicles, inverted micelles, and lyotropic liquid crystalline systems, allows for the controlled nucleation of inorganic materials on molecular templates with well-defined structure and surface chemistry. Poly(propyleneimine) dendrimers modified with long aliphatic chains are a new class of amphiphiles which display a variety of aggregation states due to their conformational flexibility [38]. In the presence of octadecylamine, poly(propyleneimine) dendrimers modified with long alkyl chains self-assemble to form remarkably rigid and well-defined aggregates. When the aggregate dispersion was injected into a supersaturated... [Pg.153]

Principles and Characteristics Combustion analysis is used primarily to determine C, H, N, O, S, P, and halogens in a variety of organic and inorganic materials (gas, liquid or solid) at trace to per cent level, e.g. for the determination of organic-bound halogens in epoxy moulding resins, halogenated hydrocarbons, brominated resins, phosphorous in flame-retardant materials, etc. Sample quantities are dependent upon the concentration level of the analyte. A precise assay can usually be obtained with a few mg of material. Combustions are performed under controlled conditions, usually in the presence of catalysts. Oxidative combustions are most common. The element of interest is converted into a reaction product, which is then determined by techniques such as GC, IC, ion-selective electrode, titrime-try, or colorimetric measurement. Various combustion techniques are commonly used. [Pg.595]

Significant progress has been made in the application of ionic liquids (ILs) as alternative solvents to C02 capture because of their unique properties such as very low vapour pressure, a broad range of liquid temperatures, excellent thermal and chemical stabilities and selective dissolution of certain organic and inorganic materials. ILs are liquid organic salts at ambient conditions with a cationic part and an anionic part. [Pg.91]

The liquid-phase hydrogenation of various terminal and internal alkynes under mild conditions was largely described with metal nanoparticles deposited/in-corporated in inorganic materials [83, 84], although several examples of selective reduction achieved by stabilized palladium, platinum or rhodium colloids have been reported in the literature. [Pg.238]

The main focus of the following considerations is on catalysis using inorganic materials. Similar considerations come into play for catalysis with molecular compounds as catalytic components of course, issues related to diffusion in porous systems are not applicable there as molecular catalysts, unless bound or attached to a solid material or contained in a polymeric entity, lack a porous system which could restrict mass transport to the active center. It is evident that the basic considerations for mass transport-related phenomena are also valid for liquid and liquid-gas-phase catalysis with inorganic materials. [Pg.391]

The temperature of the liquid is now raised, first quickly to 70° and then slowly to 85° this causes precipitation of the dye. After a quarter of an hour the mixture is cooled to 50° precipitated inorganic material is dissolved by adding 15 c.c. of concentrated sulphuric acid and, when the mixture has been cooled completely, the crude dye is filtered as dry as possible at the pump. The product is at once dissolved in 200-300 c.c. of boiling water the solution is filtered and left to crystallise over night after 20 g. of concentrated zinc chloride solution (1 1) and 40 g. of finely powdered common salt have been added. The beautiful crystals, which have a red lustre,... [Pg.323]

Stationary phase materials are synthesized from different raw materials. Those stationary phase materials synthesized from inorganic materials, such as silica and alumina, are physically strong but chemically unstable. Conversely, stationary phase materials synthesized from organic materials, such as polystyrene or poly(vinyl alcohol), are chemically stable but physically weaker. Improvements in the chemical stability of inorganic stationary phase materials and in the physical strength of organic stationary phase materials are required the marketed products do not have both and have to be used under restricted conditions in liquid chromatography. [Pg.31]

The advantage of this technique is the rapidity of monitoring for many compounds simultaneously, including some of the liquid and solid inorganic materials—such as sulfuric acid, ammonium sulfate, and ammonium nitrate—that may be the final products of the primary pollutants nitric oxide and sulfur dioxide. Also, monitoring the many par-... [Pg.37]

They serve as both separator and electrolyte. These are generally inorganic materials that are impervious barriers to gases and liquids. They allow one or more kinds of ions to migrate through their lattice when a potential gradient or a chemical gradient is present. These types of separators are beyond the scope of this article. [Pg.184]


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