1-linalool

Linalool (3.17) occurs even more widely than geraniol. The richest source is Ho leaf oil which can contain over 95% linalool. Rosewood contains 80-85% and freesia about 80% linalool. It also occurs at levels around 50% in lavender and in herbs such as coriander and basil. Citrus leaves and flowers also contain significant amounts of linalool. However, it takes its name from the oil of linaloe wood, of which it accounts for about 30%. 

We might therefore expect total scrambling of regiochemistry and stereochemistry to occur in such carbocation reactions. However, things 

Chemoenzymatic synthesis of cis-and trans-linalool oxide using bacterial EH. 

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Sensory perception is both quaUtative and quantitative. The taste of sucrose and the smell of linalool are two different kinds of sensory perceptions and each of these sensations can have different intensities. Sweet, bitter, salty, fmity, floral, etc, are different flavor quaUties produced by different chemical compounds the intensity of a particular sensory quaUty is deterrnined by the amount of the stimulus present. The saltiness of a sodium chloride solution becomes more intense if more of the salt is added, but its quaUty does not change. However, if hydrochloric acid is substituted for sodium chloride, the flavor quahty is sour not salty. For this reason, quaUty is substitutive, and quantity, intensity, or magnitude is additive (13). The sensory properties of food are generally compHcated, consisting of many different flavor quaUties at different intensities. The first task of sensory analysis is to identify the component quahties and then to determine their various intensities. 

Materials for flavoring may be divided into several groups. The most common groupings are either natural or artificial flavorings. Natural materials include spices and herbs essential oils and thek extracts, concentrates, and isolates fmit, fmit juices, and fmit essence animal and vegetable materials and thek extracts and aromatic chemicals isolated by physical means from natural products, eg, citral from lemongrass and linalool from hois de rose. 

Basil (Sweet Basil). Basil consists of the brown, dried leaves and tender stems of Ocimum basilicum L. (Labiatae), an aimual native to India, Africa, and Asia, and cultivated in Egypt, southern Erance, Morocco, the Mediteranean countries, and the United States. Basil is one of the oldest known herbs, and it is reported that there are perhaps 50—60 poorly defined Ocimum species which can only be identified according to their chemical components. The flavor of the basihcum type is warm, sweet, somewhat pungent, and pecuhar, ie, methyl chavicol and linalool. It is used with meats, fish, certain cheeses, and tomato-based salads. The fresh leaves are ground and known as pesto with pastas. It is the main component of the Hqueur Chartreuse. 

Aroma chemicals are isolates, or chemically treated oils or components of oils. Some components are removed physically, others chemically. In most cases, they are further purified by distillation. For example, Bois de Rose (rosewood) oil may be distilled to isolate linalool, which may be then further treated chemically to yield derivatives such as linalyl acetate, an important fragrance ingredient and a primary component in its own right of lavender and lavandin oils. Vetiver oil Haiti, although containing only 70% alcohols, is treated with acetic anhydride, then carefully distilled to include valuable odor components in the distillate, even though they may not be esters. 

Of the 10 constituents which represent nearly half the oil of neroH, only linalool (10) can be said to contribute direcdy to the characteristic aroma of orange flower oil. In 1977, IFF chemists performed an in-depth analysis of this oil and identified three simple terpenic compounds, each present at less than 0.01%, a-terpenyl methyl ether [1457-68-0] (31), geranyl methyl ether [2565-82-4] (32), andhnalyl methyl ether [60763-44-2] (33) (11). The latter two compounds possess green floral-citms aromas and have been known to perfumery for some time a-terpenyl methyl ether (31) has been called the orange flower ether by IFF chemists owing to its characteristic odor. 

Bois de Rose. Bois de rose oil is obtained by steam distillation of wood chips from South American rosewood trees, Aniba rosaeodora. The tree, a wild evergreen, grows mainly in the Amazon basin. The oil is used as obtained in perfumery for its sweet, woody-floral odor and as a source of linalool [78-70-6] (3), which it contains to the extent of 70%. Linalool distilled from bois de rose oil is also used directly in perfumery and for conversion to esters, eg, the acetate (1). 

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